Bubble growth and transient heat transfer at the onset of boiling

An experimental study was conducted to investigate transient local heat transfer around a bubble at onset of boiling on a thin glass heating plate immersed in saturated n-hexane at low pressure. Eight rapid response Cu-Ni thermocouples consisting of a vacuum deposited thin film were used to measure the temperature change of the heating surface. Simultaneous high-speed video photographs were also obtained. The surface temperatures near a nucleation site decreased rapidly owing to the evaporation of a thin layer (microlayer) of liquid formed beneath the bubble in the early period and the rate of bubble growth increased with increasing incipient boiling superheat (ΔT_IB). The thickness of the microlayer decreased markedly with increasing ΔT_IB. © 1998 Scripta Technica, Heat Trans Jpn Res, 26(7): 484–492, 1997     

Forced convective boiling of subcooled water at high velocity

This paper deals with heat transfer and critical heat flux (CHF) in subcooled flow boiling offering a fundamental study aimed at high heat flux cooling. Experiments with water at 0.12 MPa were conducted in a mass velocity range from 500 kg/m²s to 15,000 kg/m²s (velocity from 0.5 m/s to 15 m/s) and subcooling from 20 K to 60 K. A sheet of stainless steel (80 mm in heated length, 10 mm wide, and 0.2 mm thick) was mounted flush with a sidewall of a vertical rectangular channel (cross-section 20 mm by 30 mm) and heated directly using direct current. It was found that mass velocity and subcooling strongly affect CHF and heat transfer in non-boiling convection and partial nucleate boiling regimes. These two parameters have no appreciable influence in the fully developed nucleate boiling regime. In the parameter range used, CHF reached 15 MW/m². Boiling bubble behavior just prior to reaching CHF was found to vary depending on mass velocity and subcooling. 1998 Scripta Technica, Heat Trans Jpn Res, 27(5): 376–389, 1998     

Synthesis and properties of novel sulfonated polyimides bearing sulfophenyl pendant groups for polymer electrolyte fuel cell application

A novel sulfonated diamine bearing sulfophenyl pendant groups of 2,2′-(4-sulfophenyl) benzidine (BSPhB) was synthesized. Sulfonated polyimides (SPIs) derived from 1,4,5,8-naphthalene tetracarboxylic dianhydride, BSPhB and other non-sulfonated diamines were successfully synthesized. The SPIs with ion exchange capacity (IEC) of 1.5-2.8 meq g⁻¹ showed high reduced viscosity of 3-10 dL g⁻¹ and high desulfonation temperature of 320 °C. The SPI membranes were tough and flexible, having high stress at break of more than 80 MPa and elongation of 80-100%. They showed highly anisotropic membrane swelling in water with larger swelling in thickness direction than in plane direction. They showed fairly high proton conductivity (σ). For example, the membrane with IEC of 1.77 meq g⁻¹ exhibited σ values of 120 and 260 mS cm⁻¹ at 60 and 120 °C, respectively, in water. They also showed fairly high water stability.     

Verifying a signature architecture: a comparative case study

We report on a case study in applying different formal methods to model and verify an architecture for administrating digital signatures. The architecture comprises several concurrently executing systems that authenticate users and generate and store digital signatures by passing security relevant data through a tightly controlled interface. The architecture is interesting from a formal-methods perspective as it involves complex operations on data as well as process coordination and hence is a candidate for both data-oriented and process-oriented formal methods. We have built and verified two models of the signature architecture using two representative formal methods. In the first, we specify a data model of the architecture in Z that we extend to a trace model and interactively verify by theorem proving. In the second, we model the architecture as a system of communicating processes that we verify by finite-state model checking. We provide a detailed comparison of these two different approaches to formalization (infinite state with rich data types versus finite state) and verification (theorem proving versus model checking). Contrary to common belief, our case study suggests that Z is well suited for temporal reasoning about process models with complex operations on data. Moreover, our comparison highlights the advantages of proving theorems about such models and provides evidence that, in the hands of an experienced user, theorem proving may be neither substantially more time-consuming nor more complex than model checking.     

Analysis of the addition products of α-tocopherol with phosphatidylcholine-peroxyl radicals by high-performance liquid chromatography with chemiluminescent detection

A chemiluminescence-based high-performance liquid chromatographic method was developed for the analysis of the addition products of α-tocopherol with phosphatidylcholine-peroxyl radicals (TOO-PC). The TOO-PC eluted from a reversed-phase column was reacted with a chemiluminescent reagent consisting of a Cypridina luciferin analog and a lipid-soluble iron chelate in acidic methanol at 50°C, and the generated chemiluminescence was monitored. The detection limit for TOO-PC by this method was about 1 pmol. This method was applied to the detection of TOO-PC in the peroxidized membranes prepared from rabbit erythrocyte ghosts. When the erythrocyte ghosts were peroxidized by the addition of a water-soluble free radical initiator, a peak corresponding to TOO-PC was detected on the chromatogram with chemiluminescent detection. The amount of TOO-PC in the erythrocyte membranes increased with the depletion of endogenous α-tocopherol. The results indicate that this method proved useful for the detection of the TOO-PC formed by the peroxyl-radical scavenging reactions of α-tocopherol in biological systems.     

SEM and TEM characterization of magnesium hydride catalyzed with Ni nano-particle or Nb2O5

The microstructures of MgH₂ catalyzed with Ni nano-particle or Nb₂O₅ mesoporous powders are examined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations. For MgH₂ catalyzed with Ni, the Ni particles with the diameter smaller than 1 μm were detected on the MgH₂ particles with the diameter smaller than 5 μm by the back scattering electron (BSE) microscopy. In details, the TEM micrograph indicates that the Ni particles distribute 20 nm in diameter on MgH₂ uniformly, which was the same size as the additive doped in MgH₂ before milling. On the other hand, for MgH₂ catalyzed with Nb₂O₅, the additive particles could not be found anywhere in the BSE image. Even in the TEM micrograph by much larger magnification than the SEM micrograph, the particles corresponding to the additive cannot be observed at all. Furthermore, an energy dispersive X-ray (EDX) analysis in spots with a diameter of 20 nm indicated that the existing ratio of Mg to Nb was evaluated to 98:2, being the same as the starting ratio before milling. Therefore, the metal oxide Nb₂O₅ becomes extremely small particle that could not be observed by the present work after milling compared to metal Ni^nano.     

Determination of vedaprofen in livestock products and seafoods by liquid chromatography-tandem mass spectrometry

A novel liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for the trace residue determination of vedaprofen (VPF) in livestock products and seafoods. VPF was extracted from each sample with acidified acetone, and the crude extract was re-extracted with ethyl acetate and NaCl solution. Clean-up was performed using a weak anion exchange cartridge (Bond Elut DEA). The LC separation was performed on a C18 column using acetonitrile-0.0025 mol/L formic acid (3 : 2) as the mobile phase and MS was run in the negative ion electrospray ionization mode. The calibration curve was linear in the range of 0.001-0.1 μg/mL VPF. The mean recoveries from equine muscle, cattle muscle, cattle liver, cattle fat, salmon, eel, corbicula, milk, egg and buckwheat honey were 72-94%, and the relative standard deviations (RSDs) were 1.1-2.0%. Limits of quantitation (LOQs) ranged from 0.001 to 0.007 μg/g.     

Recent progress of Cat-CVD research in Japan—bridging between the first and second Cat-CVD conferences

We review the recent progress of Cat-CVD research in Japan since the 1st Cat-CVD conference in Kanazawa in 2000. Some groups, including ours, succeeded in realizing large-area deposition of amorphous silicon (a-Si) of approximately 1 m size, and thin film transistors (TFTs) with a mobility over several 10s of cm² V⁻¹ s⁻¹ are fabricated using Cat-CVD polycrystalline silicon (poly-Si) films. Extensive studies of in situ cleaning methods revealed that a high rate of chamber cleaning is possible in Cat-CVD systems. Solar cell research is now carried out within the New Energy and Industrial Technology Development Organization (NEDO) project, and the study of Cat-CVD Si₃N₄ films prepared at lower than 100 °C is now a Japan Science and Technology Corporation (JST) project to use them as coatings on organic devices. The feasibility of Cat-CVD for various applications has been widely demonstrated, along with further understanding of the fundamental mechanism of the Cat-CVD process.