福美双分光光度法快速测定微量铜

在碱性条件下, Ｃｕ ? 与福美双（ Ｎ Ｃ Ｈ３ Ｃ Ｈ３ Ｃ Ｓ Ｓ Ｓ Ｃ Ｓ Ｃ Ｈ３ Ｃ Ｈ３ ） 形成稳定的桔红色配合物,配合物的λｍ ａｘ ＝ ４５２ ｎ ｍ , 表观摩尔吸光系数ε＝ １ ．２ ×１０ ４ 。铜含量在０ ～１０ μｇ／ ｍ Ｌ 范围内符合比耳定律。     

Factors controlling diel patterns of methane emission via rice

Methane emissions from flooded rice grown under greenhouse conditions were monitored using a closed chamber technique. The three rice cultivars showed similar diel emission patterns though the amplitudes differed. Variation in emissions (maximum emission rate) from the different cultivars ranged from 0.164–0.241 mg/pot/h at tillering stage, 0.714–2.334 mg/pot/h at heading stage, 0.399–1.393 mg/pot/h at ripening stage. The methane emissions increased in the morning at accelerating rates, reached a maximum in the early afternoon, then decreased rapidly to constant rates during the night. The diel emission pattern was modeled using a Gaussian equation for daytime, and a constant for nocturnal emissions. Applying an Arrhenius equation, more than 90% of the diel variation of methane emissions could be predicted from soil temperature fluctuations. The predictions improved by using a diffusion model based on soil temperature and dissolved methane concentrations in soil solution. Soil temperature and methane concentration in soil solution are the two major factors controlling diel methane emissions.     

Michael addition of ethyl acrylate and acetone over solid bases

The catalytic behaviour of the superbases Na/NaOH/-Al₂O₃ and Cs_xO/-Al₂O₃ as well as of the basic zeolites Na/NaX and Cs_xO/CsX were investigated in the Michael addition of ethyl acrylate and acetone. The reactions were carried out in the liquid phase at catalyst loadings varying from 0.05 to 0.1 mol ester/g catalyst.     

Security of Water Supply and Electricity Production: Aspects of Integrated Management

The share of renewable resources in electricity generation, e.g. in Germany, is increasing. The power sector is thus becoming more dependent on climate/weather parameters. During the summer months of the last decade, numerous thermal power plants in Europe had to be throttled due to water shortages and high water temperatures. At the same time, Europe was confronted with a reduction in hydropower production. One method of securing a future electricity supply is to increase the reliability of the water supply for power plants. In this paper, scenarios are presented for future electricity production by hydropower and thermal power plants in the Elbe river basin. Electricity production in hydropower plants will decline by approximately 13 % by 2050. This decline is due to climate change and it could be compensated for by optimizing and modernizing existing hydropower plants. Due to higher efficiencies and the conversion of plant cooling systems, no water shortages are expected in most thermal power plants. However, water shortages are expected to affect the plants in the city of Berlin. Inter- and intra-basin water transfers constitute a possible adaptation option. While the transfer of water from the river Oder would be the most cost-efficient solution from Berlin’s perspective, the transfer of water from the river Elbe would have additional positive effects in the upstream Spree river sub-basin.     

Downstream Migration of the European Eel (Anguilla Anguilla) in the Elbe River,Germany: Movement Patterns and the Potential Impact of Environmental Factors

Recruitment of European eels (Anguilla anguilla) has declined to the extent that they have been added to the IUCN Red List of Threatened Species. Therefore, it is critical to ensure that eels complete their outward river migration in order to contribute to the available spawning stock. We conducted a 4‐year (2007–2011) telemetry study to understand the migratory behaviour and potential impact of environmental factors on the eel during this critical life stage. Out of 399 female eels tagged with acoustic transmitters, only 28% demonstrated clear downstream migratory behaviour. Fifty‐five percent were detected exhibiting no downstream migration behaviour and 17% were not detected at any monitoring station. Movement patterns of downstream‐migrating (silver) eels were characterized by nocturnal activity and seasonal migration, with distinct peaks in autumn and spring. Migration was often discontinuous and exhibited phases of active locomotion and expanded stopovers. The most important determinants of movement activity were water temperature, cumulative precipitation and moonlight, although the significance varied by season and location in the river basin. Our results evidence a discontinuous, stepwise migration over an extended period. Furthermore, our findings indicate that migration success depends on holding duration prior to tagging and environmental predictors with varying importance depending on the season, as well as the locations of capture, tagging and release. Copyright © 2015 John Wiley & Sons, Ltd.     

A meta-analysis study of the effect of chilling on prevalence of Salmonella on pig carcasses

In the field of food safety, meta-analysis can be used to combine results of prevalence studies of pathogens at critical stages within the food processing chain so that policy makers can access reliable and concise information on the effectiveness of interventions for controlling and preventing foodborne illnesses in humans. The objective of this work was to demonstrate the applicability of a parametric approach of meta-analysis to the specific case of determining the overall effect of chilling on Salmonella prevalence on pig carcasses. A meta-analysis was performed on each of two parameters measuring effect size for binary outcomes (relative risk and risk difference). Both meta-analyses confirmed that the chilling operation has a significant beneficial effect (P < 0.001) on the reduction of Salmonella prevalence on pig carcasses. Because risk difference is a parameter sensitive to the differences across studies in carcass swab areas and Salmonella detection methods, its meta-analysis highly reflected this heterogeneity (P < 0.001). However, parameterization of relative risk, not being biased by the above sources of variability, did not give rise to heterogeneity among studies and produced a fixed-effects meta-analysis solution, which is deemed more suitable for compilations based on a small number of individual studies (n = 9). Because of the systematic approach of meta-analysis (i.e., individual studies are weighed according to precision) and its reliance for actual data, the output distribution of the relative risk effect size (approximately eN(-0.868,0.166)) merits consideration for inclusion in the chilling stage of quantitative risk assessments modeling the prevalence of this pathogen along the pork production chain.     

Engineering aspects of radio-wave heating for soil remediation and compatibility with biodegradation

Dielectric heating of soil using radio waves (RW) can be applied to support various remediation techniques, namely biodegradation and soil vapor extraction, under in situ, on site or ex situ conditions. To improve the spatial resolution of energy dissipation, the design of rod electrodes was modified with an air gap around the electrode allowing thermal treatment focused to the desired soil volume. A combination of low- and high-frequency electrical energy was successfully applied to homogeneously heat the capillary fringe, the boundary region of saturated and unsaturated zones. The energetic efficiency of the method was evaluated showing that an efficient transformation of RW energy to heat in the target volume can be achieved. By comparing biodegradation and soil respiration under conventional and electric (low-frequency resistive and dielectric RW) heating, the compatibility of the electric heating methods with bioremediation processes could be proven. Therefore, RW-supported microbial degradation of pollutants is a real option for accelerated soil remediation.     

Study of solar radiation stability of modern polymer materials on a large solar furnace

The testing of modern polymer insulators designed for transmission facilities for light stability under the action of solar radiation is considered. The technique of accelerated testing including irradiation of the samples with ultraviolet radiation using a large solar furnace has been proposed.     

Silicon-organic pigment material hybrids for photovoltaic application

Hybrid materials of silicon and organic dyes have been investigated for possible application as photovoltaic material in thin film solar cells. High conversion efficiency is expected from the combination of the advantages of organic dyes for light absorption and those of silicon for charge carrier separation and transport. Low temperature remote hot wire chemical vapor deposition (HWCVD) was developed for microcrystalline silicon (μc-Si) deposition using SiH₄/H₂ mixtures. As model dyes zinc phthalocyanines have been evaporated from Knudsen type sources. Layers of dye on μc-Si and μc-Si on dye films, and composites of simultaneously and sequentially deposited Si and dye have been prepared and characterized. Raman, absorption, and photoemission spectroscopy prove the stability of the organic molecules against the rough HWCVD-Si process. Transient microwave conductivity (TRMC) indicates good electronic quality of the μc-Si matrix. Energy transfer from dye to Si is indicated indirectly by luminescence and directly by photoconductivity measurements. F_xZnPc pigments with x=0,4,8,16 have been synthesized, purified and adsorbed onto H-terminated Si(1 1 1) for electronic state line up determination by photoelectron spectroscopy. For x=4 and 8 the dye frontier orbitals line up symmetrically versus the Si energy gap offering similar energetic driving forces for electron and hole injection, which is considered optimum for bulk sensitization and indicates a direction to improve the optoelectronic coupling of the organic dyes to silicon.     

Modelling a PEM fuel cell stack with a nonlinear equivalent circuit

A nonlinear circuit model of a polymer electrolyte membrane (PEM) fuel cell stack is presented. The model allows the simulation of both steady-state and dynamic behaviour of the stack on condition that the values of some of its parameters are changed in the two operating conditions. The circuit parameters can be obtained by means of simple experimental tests and calculations. A commercial PEM fuel cell stack is modelled as seen from the power conditioning system side, without requiring parameters necessary for complex mathematical models and not easily obtainable by the majority of users. A procedure of parameter determination is developed and a comparison between the simulated and experimental results for both steady-state and dynamic behaviour of the PEM stack is shown.