纳米级无机粒子对聚乙烯的增强与增韧

对μｍ级ＣａＣＯ３、ＴｉＯ２和ｎｍ级ＳｉＣ／Ｓｉ３Ｎ４粒子填充ＬＤＰＥ的性能进行了研究。实验证明，μｍ级粒子对ＬＤＰＥ虽无明显的增强增韧作用，但也未使基体的机械性能大幅度下降。ｎｍ级ＳｉＣ／Ｓｉ３Ｎ４对ＬＤＰＥ有较大的增强增韧作用，在５％质量分数时冲击强度出现最大值，缺口冲击强度达５５．７ｋＪ／ｍ２为纯ＬＤＰＥ的２０３％；伸长率到６２５％时仍未断裂，为纯ＬＤＰＥ的５００％，但熔体流动速率急剧下降，仅为纯ＬＤＰＥ的２６％，当含量在３％和１５％质量分数时，熔体流动速率分别为纯ＬＤＰＥ的３３７％和１５１％。     

A surrogate-based optimization method with RBF neural network enhanced by linear interpolation and hybrid infill strategy

In engineering, it is computationally prohibitive to directly employ costly models in optimization. Therefore, surrogate-based optimization is developed to replace the accurate models with cheap surrogates during optimization for efficiency. The two key issues of surrogate-based optimization are how to improve the surrogate accuracy by making the most of the available training samples, and how to sequentially augment the training set with certain infill strategy so as to gradually improve the surrogate accuracy and guarantee the convergence to the real global optimum of the accurate model. To address these two issues, a radial basis function neural network (RBFNN) based optimization method is proposed in this paper. First, a linear interpolation (LI) based RBFNN modelling method, LI-RBFNN, is developed, which can enhance the RBFNN accuracy by enforcing the gradient match between the surrogate and the trend observed from the training samples. Second, a hybrid infill strategy is proposed, which uses the surrogate prediction error based surrogate lower bound as the optimization objective to locate the promising region and meanwhile employs a linear interpolation-based sequential sampling approach to improve the surrogate accuracy globally. Finally, extensive tests are investigated and the effectiveness and efficiency of the proposed methods are demonstrated.     

Preparation and characterization of a series of polyamides with long alkylene segments: Nylons 12 20, 10 20,s 20,6 20, 4 20 and 2 20

Summary A series of nylons with long alkylene segments between amide groups were newly prepared by step-heating melt-polycondensation of 1,lS-octadecanedicarboxylic acid with various diamines. The prepared polyamides were characterized carefully. The results show that many properties of the prepared nylons change regularly with the length of methylene segments in diamines. In addition, nylon 2 20 has a relatively low molecular weight and much different melting and thermal decomposition behaviors in comparison with other nylons. Received: 21 June 2OO2/Revised version: 18 September 2002/ Accepted: 18 September 2002 Correspondence to Deyue Yan E-mail: dyyan@mail.sjtu.edu.cn Tel: 0086-21-54742863 Fax: 0086-21-54741297     

喷码机平台WinCE5.0系统的BSP开发

基于以S3C2440A处理器为核心的喷码机硬件开发平台,研究了嵌入式WinCE5.0操作系统板级支持包BSP的开发。分析了喷码机平台的硬件组成和BSP的框架结构,利用源代码重用的思想,完成了Bootloader、OAL、驱动程序、配置文件的开发工作并在BINFS文件系统的基础上实现Multi-bin成功将内核分块。实践表明该BSP在喷码机台上运行稳定,可靠性高,能有效提升系统的开机速度,并使平台拥有了运行大型喷印软件的能力。     

省级网站安全监控平台建设的几点建议

针对网站日益增多的安全问题,提出在监管方面重要的技术手段--省级网站安全监控平台,并针对平台实现功能、平台建设、运维等方面提出几点建议.     

注塑参数对聚碳酸酯成型收缩率的影响研究

研究了注塑参数对聚碳酸酯(PC)成型收缩率的影响，从理论上探讨了注塑参数—制品结构—收缩率之间的关系。试验结果表明，对PC成型收缩率影响最大的注塑参数是料温，其次是模具温度、注塑压力和注射速率，而保压时间、冷却时间、预塑速率在实验范围内对PC成型收缩率影响较小。     

高铁早强矿渣硅酸盐水泥的研制

湖北某水泥厂在８．３万Ｔ立窑水泥生产线上，成功地开发高铁早强矿渣水泥，并通过了国家建材局水泥专家参加的省级鉴定。该水泥具有早强高，硬化快，抗硫酸盐侵蚀和胶凝性能好等性。     

高支化度酯类增塑剂的结构鉴定

利用AV50 0核磁共振波谱仪鉴定了一种从聚氨酯材料中分离出的增塑剂。这是一种新型的性能优良的耐迁移性脂肪族增塑剂。使用的手段有红外光谱 ,1 H NMR ,1 3C NMR ,1 3C 1 HCOSY ,1 H 1 HCOSY以及DEPT等技术。     

Fast online acquisition and analysis for parison swell and sag in blow molding

It is critical to quantitatively and reliably characterize the effects of swell and sag phenomena on the final parison dimensions in extrusion blow molding. To achieve this goal, an online image acquisition and analysis technique was developed. The successive images of parison were automatically taken using the online acquisition apparatus. These images were then analyzed by the combined use of the conventional digital image processing method and the new one developed by the authors. So the development of parison diameter and thickness swells with the extrusion time could be determined online. On the basis of the online obtained actual swell values, the pure swell and sag components were quantitatively determined. The developed technique was tested through a series of experiments using several resins under different processing parameters and die types. Shown in the present article were the results for a converging die under three different die gaps and a high‐density polyethylene. Some new phenomena were observed using the proposed technique. The results showed that the technique yields fast and accurate determination of the evolution of diameter, thickness, and length of parison during its extrusion. The technique can be employed as a part of the closed loop control for blow molded part thickness. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2399–2406, 2006     

Chemical and experiential basis for rejection ofTropaeolum majus byPieris rapae larvae

Rejection of nasturtium,Tropaeolum majus, by cabbage-reared larvae ofPieris rapae has been explained by the presence of feeding deterrents in the nastrutium foliage. Sensitivity to the deterrents develops as neonate larvae feed on cabbage. The most prominent deterrent compound, which is present in nasturtium at a concentration of 40 mg/100 g fresh leaves, was identified as chlorogenic acid. When neonate larvae were fed on a cabbage leaf treated with high concentrations of deterrent-containing extracts of nasturtium foliage, they remained insensitive to the deterrents, so they accepted nasturtium when transferred as second instars. When neonate larvae were reared on a cabbage leaf treated with 0.1 mg chlorogenic acid, ca. 35% of the second instars accepted nasturtium. Similar dietary exposure of neonates to the subunits of chlorogenic acid, caffeic acid and quinic, acid resulted in much less or no effect on the rejection behavior of second instars. The results suggest that the combined effects of specific chemical constituents of nasturtium can explain the rejection of this plant by larvae ofP. rapae, but if larvae are continuously exposed to these compounds immediately after hatching, they apparently become habituated to the feeding deterrents. The lack of activity of the subunits of chlorogenic acid suggests that specific structural features are necessary for a dietary constituent to cause such habituation or suppression of sensitivity development.