MDY一1炸药猛度测试仪的研制

为使炸药猛度的测试达到现代先进水平，研制了ＭＤＹ一１测试仪。论述了研制此仪的重要意义，仪器电路工作原理及测试原理，以及对电路和炸药进行检测的结果。     

最大Lyapunov指数实现局域网流量的预测

由于网络中存在复杂的非线性动力学特性,基于混沌理论,采用最大Lyapunov指数对局域网络流量序列进行预测分析,能够实现较早地预测出网络流量的突变特性.首先,采用相空间重构理论,并结合C-C算法将实际测试的流量时间序列投影到重构的相空间中.然后,计算其最大Lyapunov指数并对最大可预测时间进行了分析,同时对预测算法进行了研究.最后,对实际测试的局域网流量序列分别采用点预测和区间预测方法进行了分析.仿真结果显示,采用点预测方法对流量突变可以进行有效预测,突变越剧烈预测越准确;而采用区间预测可以有效预测流量的变化趋势,但不适用于广域网环境.进一步表明此方法能有效地利用所有数据信息进行预测,预测效果准确、可靠,可广泛的用于网络拥塞和网络攻击中.     

Preparation and electrochemical characterization of activated carbons by chemical-physical activation

A process was proposed based on the combination of chemical and physical activation for the production of activated carbons used as the electrode material for electric double layer capacitor (EDLC). By material characterization and electrochemical methods, the influences of the activitation process on the specific surface area, pore structure and electrochemical properties of the activated carbons were investigated. The results show that specific surface area, the mesopore volume, and the specific capacitance increase with the increase of the mass ratio of KOH to char (m(KOH)/m(char)) and the activation time, respectively. When m(KOH)/m(char) is 4.0, the specific surface area and the mesopore volume reach the maximum values, i.e. 1 960 m²/g and 0.308 4 cm³/g, and the specific capacitance is 120.7 F/g synchronously. Compared with the chemical activation, the activated carbons prepared by chemical-physical activation show a larger mesopore volume, a higher ratio of mesopore and a larger specific capacitance. Foundation item: Project(2007BAE12B01) supported by the National Key Technology Research and Development Program of China     

自复位装配式混凝土框架结构抗震性能试验研究

提出了一种采用新型连接节点构造的自复位装配式混凝土框架结构。设计并制作了两榀单层单跨框架结构试件,包括一榀现浇混凝土框架和一榀新型装配式混凝土框架。其中,对装配式混凝土框架结构进行了两次拟静力试验,第二次试验是在第一次试验完成后并更换结构的耗能钢筋进行的。试验结果表明：新型装配式混凝土框架结构的承载能力和耗能能力略低于现浇混凝土框架结构,但延性较现浇框架有较大提高,层间位移角超过1/50时,承载力仍无下降趋势;另外,装配式混凝土框架结构在第一次试验后的残余变形约为现浇框架结构的15%,构件损伤轻微,结构可以实现自主复位;装配式框架结构在第二次试验中的承载力较第一次试验略有下降,残余变形有所增大,仍然具有一定的自主复位能力,结构损伤仍较轻微,说明其经过简单地更换耗能钢筋就可以实现抗震能力的基本恢复。     

超细粉体粒度测试方法浅析

介绍了超细粉体粒度测试的几种主要方法(激光衍射散射法、离心沉降法、颗粒图像处理仪和库尔特颗粒计数器)的测试原理及性能特点，并进行了比较。讨论了粒度测试中应注意的几个问题，重点分析了测试条件不同对粒度测定的影响，得出分散介质、分散剂、超声功率及超声时间等是影响粒度测定的最主要的因素；指出了重复性、真实性、易操作性、量程和动态范围是评价粒度仪测试性能的几个重要指标。     

Biodegradable Polycaprolactone-Titania Nanocomposites: Preparation,Characterization and Antimicrobial Properties

Nanocomposites obtained from the incorporation of synthesized TiO₂ nanoparticles (≈10 nm average primary particle size) in different amounts, ranging from 0.5 to 5 wt.%, into a biodegradable polycaprolactone matrix are achieved via a straightforward and commercial melting processing. The resulting nanocomposites have been structurally and thermally characterized by transmission electron microscopy (TEM), wide/small angle X-ray diffraction (WAXS/SAXS, respectively) and differential scanning calorimetry (DSC). TEM evaluation provides evidence of an excellent nanometric dispersion of the oxide component in the polymeric matrix, with aggregates having an average size well below 100 nm. Presence of these TiO₂ nanoparticles induces a nucleant effect during polymer crystallization. Moreover, the antimicrobial activity of nanocomposites has been tested using both UV and visible light against Gram-negative Escherichia coli bacteria and Gram-positive Staphylococcus aureus. The bactericidal behavior has been explained through the analysis of the material optical properties, with a key role played by the creation of new electronic states within the polymer-based nanocomposites.     

Ag2O–Al2O3–ZrO2 Trimetallic Nanocatalyst for High Performance Photodegradation of Nicosulfuron Herbicide

Topics in Catalysis - In the present study, Ag2O–Al2O3–ZrO2 based trimetallic oxide nanocatalyst was designed using simple microwave assisted reduction method. It was characterized...     

反应降解聚丙烯的高速挤出流动稳定性

采用双毛细管流变仪研究了反应降解聚丙烯试样的挤出稳定性。结果表明:基础树脂聚丙烯PP-2401的挤出压力随剪切速率增高呈阶梯状稳定增高,而降解聚丙烯的挤出压力随剪切速率增高出现不规则波动;低相对分子质量降解聚丙烯的压力波动主要发生在口模入口区;发生波动的原因与聚丙烯分子链结构特征有关,同时与熔体在口模区的Weissenberg准数和Reynolds准数较大有关。     

Copolymerizations of ethylene with α-olefin-ω-ols by highly active vanadium(III) catalysts bearing [N,O] bidentate chelated ligands

The copolymerizations of ethylene with polar hydroxyl monomers such as 10-undecen-1-ol, 5-hexen-1-ol and 3-buten-1-ol were investigated by the vanadium(III) catalysts bearing bidentate [N,O] ligands (1, [PhNC(CH₃)CHC(Ph)O]VCl₂(THF)₂; 2, [PhNCHC₆H₄O]VCl₂(THF)₂; 3, [PhNCHC(Ph)CHO]VCl₂(THF)₂). The polar monomers were pretreated by alkylaluminum before the polymerization. High catalytic activities and efficient comonomer incorporations can be easily obtained by changing monomer masking reagents and polymerization conditions in the presence of diethylaluminium chloride as a cocatalyst. The longer the spacer group, the higher the incorporation of the monomer. Under the mild conditions, the incorporation level of 10-undecen-1-ol reached 13.9 mol% in the resultant copolymers was obtained. The reactivity ratios of copolymerization (r₁ = 41.4, r₂ = 0.02, r₁r₂ = 0.83) were evaluated by Fineman–Ross method. According to ¹³C NMR spectra, polar units were located both on the main chain and at the chain end. The end-hydroxylated polymers were probably obtained due to the formation of dormant species after the insertion of the comonomer followed by the chain transfer to alkylaluminum. In addition, the signals derived from polar monomer inverse insertion were detected for the first time.