金刚石形状对成形砂轮修整精度的影响及其消除的方法

在用金刚石修整成形砂轮时,金刚石的形状对砂轮的成形修整精度有不容忽视的影响。为了提高修整精度,可以分别或综合采取下列措施：1）减小金刚石的形状误差,如挑选金刚石的形状或加以修整;2）减小修整机构的修整压力角v D;3）按金刚石的形状修磨修整机构的仿形触指。     

Structural load mitigation control for wind turbines: A new performance measure

Structural loads of wind turbines are becoming critical because of the growing size of wind turbines in combination with the required dynamic output demands. Wind turbine tower and blades are therefore affected by structural loads. To mitigate the loads while maintaining other desired conditions such as the optimization of power generated or the regulation of rotor speed, advanced control schemes have been developed during the last decade. However, conflict and trade‐off between structural load reduction capacity of the controllers and other goals arise; when trying to reduce the structural loads, the power production or regulation performance may be also reduced. Suitable measures are needed when designing controllers to evaluate the control performance with respect to the conflicting control goals. Existing measures for structural loads only consider the loads without referring to the relationship between loads and other control performance aspects. In this contribution, the conflicts are clearly defined and expressed to evaluate the effectiveness of control methods by introducing novel measures. New measures considering structural loads, power production, and regulation to prove the control performance and to formulate criteria for controller design are proposed. The proposed measures allow graphical illustration and numerical criteria describing conflicting control goals and the relationship between goals. Two control approaches for wind turbines, PI and observer‐based state feedback, are defined and used to illustrate and to compare the newly introduced measures. The results are obtained by simulation using Fatigue, Aerodynamics, Structures, and Turbulence (FAST) tool, developed by the National Renewable Energy Laboratory (NREL), USA.     

Study on Thermal Decomposition of Composite Propellants containing PCP polymer or PCP-HTPB copolymer as a binder

A modified manometric vacuum stability test (MVST) apparatus as well as a differential thermal analyzer (DTA) and a thermogravimetric analyzer (TGA) were used to study thermal decomposition of a series of propellants. The solid propellants contained polycaprolactone (PCP) prepolymer or PCP-HTPB copolymer as binder, ammonium perchlorate (AP) and a nitramine (RDX or HMX) as oxidants, aluminum as fuel, and bis(2,2-dinitropropyl)acetal/formal (BDNPA/F) as plasticizer. The mixtures were cured with an isocyanate (Desmodur N-100). It is found from MVST examinations that propellants containing PCP polymer are more stable than ones containing PCP-HTPB copolymer. The PCP propellants were still stable after 40 hours heating at 135°C. The thermal decomposition reactions of prepared propellants during dynamic heating were indicated by two major stages of weight loss in the TGA traces.     

Production of GST–SOD fusion protein by recombinant E coli XL1 Blue

A recombinant plasmid was constructed by inserting a DNA fragment with the coding region of Cu/Zn–superoxide dismutase (Cu/Zn–SOD) cDNA from sweet potato, Ipomoea batatas (l) Lam cv Tainong 57, into the 3′ end of the open reading frame of the glutathione S‐transferase (GST) gene in an expression vector, pGEX‐2T. The constructed plasmid was transformed into E coli XL1 Blue. Fusion proteins of Cu/Zn–SOD and GST (GST–SOD) were produced from the recombinant E coli. About 6 mg of GST–SOD fusion proteins could be obtained from 1 dm³ of cultural broth after induction with 0.075 mmol dm⁻³ Isopropyl‐β‐D ‐thiogalactoside (IPTG). Lactose was not an efficient inducer. High cell density culture was performed by fed‐batch fermentation using a glucose analyzer to control glucose concentration at 1 g dm⁻³. The cell density of the fed‐batch culture reached an OD₆₀₀ of 30, the total amount of GST–SOD fusion protein was 100 mg dm⁻³ which is about 14 times more than that of the batch culture. Most of the fusion proteins were shown to be in an active monomeric form, and the molecular weight was estimated to be 45 kDa by SDS–PAGE and 47 kDa by gel filtration. The specific activity of the purified fusion proteins was about 1200 mg⁻¹ and equal to 3200 unit per mg of SOD domain only. © 2000 Society of Chemical Industry     

Highly concentrated aqueous SiC slurry containing fine SiC powder: A new approach for ultra-dense green body

SiC slurry with ultra-high concentration up to 70 vol% was prepared using oxidized fine and coarse SiC powder mixture, and dense SiC green body with a relative density of 76% was fabricated by drying the slurry at ambient condition. Three approaches were performed to prepare highly concentrated SiC slurry; preparation of SiC powder having good dispersion behavior, optimization of the oxidation condition, and optimization of bi-modal particle size distribution. An aqueous slurry with the solid loading up to 62 vol% could be prepared using fine (150 nm) SiC powder prepared by the mechanical alloying of Si and carbon. The surface property of the fine and coarse (10 μm) SiC powders was optimized using an oxidation treatment. The maximum solid loading of the fine SiC slurry prepared using oxidized powder was 66 vol%. By optimizing the mixing ratio of the oxidized fine and coarse SiC powder to 75:25, the solid loading of the SiC slurry could increase up to 70 vol%. The relative densities of the green bodies after drying 66, 68, and 70 vol% slurries were 69, 75.7, and 76.1%, respectively, which values were higher than those (58%) prepared by cold isostatic pressing under 200 MPa.     

Characteristics of fractionated flours from whole buckwheat grain using a gradual milling system and their application for noodle making

BACKGROUND: Recently, the quality of buckwheat (Fagopyrum esculentum, Moench) flour was improved by using a gradual milling method in which whole buckwheat grains were milled into various fractions. In this study, 16 fractions milled from whole buckwheat grains from the outer to inner parts are characterised and used for noodle making. RESULTS: Protein and ash contents of flours increased in the order from the inner to the outer fractions. Each fraction contained nine main fatty acids in which the concentration of palmitic, stearic, linoleic and linolenic acids tended to decrease from the inner to outer parts of the grain, whereas the concentration of oleic acid in the middle parts of grain was higher than in the other parts. The peak viscosity was different among the fractions and the middle fractions had significantly higher peak viscosity than the other fractions. The optimum cooking time and whiteness of uncooked and cooked noodles substituted with 40% of the fractions decreased from the inner to outer fractions, whereas noodles made from the inner fractions were harder and less elastic than those from the outer fractions. CONCLUSION: The different buckwheat fractions contributed to different quality of soba noodles. However, the appropriate fractions could be used for noodle making to improve the quality of noodles depending on nutritional demands. Copyright © 2007 Society of Chemical Industry     

Risk Assessment of Human Exposure to Bioaccessible Phthalate Esters via Indoor Dust around the Pearl River Delta

There is limited information on the bioaccessible fractions of phthalate esters in indoor dust in order to estimate human exposure. In the present study, workplace dust and settled house dust samples from Hong Kong, Shenzhen, and Guangzhou, the three major cities scattered around the Pearl River Delta (PRD) were collected. Chemical analyses showed that the phthalates in workplace dust ranged from 144 to 1810 μg/g, with dust from shopping malls containing the highest level, and in home dust ranged from 181 to 9240 μg/g. The most abundant phthalate ester found was bis(2-ethylhexyl) phthalate (DEHP) in both workplace dust and home dust, followed by di-n-butyl phthalate (DBP) and di-iso-butyl phthalate (DIBP). Principal Components Analysis (PCA) indicated that indoor dust around PRD showed similar phthalate esters patterns of composition. A significant correlation was observed between total phthalate esters concentrations in home dust and the number of year of house construction (p < 0.05). The oral bioaccessibility of phthalate esters in indoor dust ranged from 10.2% (DEHP) to 32% (DMP). Risk assessment indicated that the dominant exposure routes varied in different phthalate esters exposure profiles and the dermal contact exposure pathway was identified as an important route for indoor DEHP exposure.     

Replacement of carcinogenic alkylating agent ethylene oxide in the synthesis of (Z)-3-dodecen-1-YL (E)-2-butenoate,sex pheromone of sweet-potato weevil,Cylas formicarius elegantulus (summers) andCylas formicarius formicarius (F.)

An alternative synthesis of (Z)-3-dodecen-1-y1 (E)-2-butenoate without use of carcinogenic ethylene oxide and HMPA is described. By coupling of the tetrahydropyranyl (THP) ether of 3-butyn-1-ol with 1-bromooctane with sodamide in liquid ammonia, 12-(2-tetrahydropyranyloxy)-9-dodecyne was obtained; subsequent hydrolysis and semihydrogenation afforded (Z)-3-dodecen-1-ol. The alcohol was then reacted with crotonyl chloride to give the desired crotonate with a total yield of 29.8%. Males of sweet-potato weevil,Cylas formicarius were strongly attracted to the synthetic sex pheromone. The attraction from the dispenser of polyethylene tube was better than the attraction from the dispenser of rubber septum in the field.     

Intermolecular and intramolecular hydrogen bonding of poly(dimethylsiloxane)urethane‐graft–poly(methyl methacrylate) copolymers based on 2,4‐TDI and m‐XDI

In this study, poly(dimethylsiloxane)urethane–graft–poly(methyl methacrylate) (PDMS urethane–g–PMMA) copolymers with low crosslinking density were synthesized. Glass transition temperatures of the copolymers were investigated by dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC). Results confirm that PDMS urethane–g–PMMA is miscible in the 2,4‐TDI (2,4‐ toluene diisocyanate) system, whereas it is partially miscible in the m‐XDI (m‐xylene diisocyanate) system. Free, intra‐ (urethane–urethane), and inter‐ (urethane–ester) association hydrogen bonding exist in the urethane group of copolymers. The inter‐association hydrogen bonding can improve the compatibility of the copolymer components. The relationship between the frequency shift and enthalpy confirm the distribution of hydrogen bonding in the macromonomer and copolymer. Ninety percent of the hydrogen bonding is by interassociation in the 2,4‐TDI system. The intra‐association hydrogen bonding in the m‐XDI system is higher than that in the 2,4‐TDI system. Consequently, aggregation may occur easily in the siloxane‐grafted chain in the m‐XDI system. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 962–972, 2002     

Lamellar morphologies and crystal stability of syndiotactic polystyrene in α-crystalline form

Syndiotactic polystyrene (sPS) samples melt-crystallized into neat α″ hexagonal modifications were prepared at various temperatures thoroughly for the extensive morphological studies. Lamellar morphologies of the as-prepared sPS samples were investigated using small-angle X-ray scattering (SAXS) and transmission electron microscopy (TEM). Absence of a discernible scattering peak was found for SAXS conducted at room temperature, resulting from a negligible difference in the electron density between the lamellar and amorphous layers. To enhance the scattering contrast and strength, SAXS was carried out at 180 °C to obtain more reliable morphological parameters. Due to the broad thickness distribution of morphological features as revealed from the TEM observations, a pronounced variation is found for the long periods derived from the Bragg's law, one-dimensional correlation function, and interface distribution function of the SAXS data. In addition, relatively irregular packing of lamellar stacks with short lateral dimensions was detected in the as-prepared α″-form sPS, leading to the absence of spherulitic birefringence under polarized optical microscopy. Based on the interface distribution function analysis of the SAXS intensity profiles, the lamellar thicknesses were estimated. Using the Gibbs-Thomson relation, the ratio of fold surface free energy (σ_e) to the fusion enthalpy for α″-form sPS was successfully deduced to be ca. 0.057 nm, which is lower than that of β′-form sPS, ca. 0.12 nm. On this basis, a comparison of critical lamellar thicknesses for α″- and β′-form sPS at various crystallization temperatures is provided and the crystal stability associated with the lamellar thickness is discussed as well.