PEGDA/NIPAM共聚物水凝胶的溶胀性能及体积相变研究

以IRGACURE2959为光引发剂,聚乙二醇双丙烯酸酯(PEGAD)和N-异丙基丙烯酰胺(NIPAM)为单体,通过紫外光引发光聚合合成了PEGDA/NIPAM共聚物水凝胶.研究了不同单体质量比凝胶材料在不同温度和pH值下的溶胀性能,测试凝胶在不同温度水中的体积相变.研究结果表明,水凝胶的平衡溶胀率随着NIPAM质量浓度增大而增大,随着环境温度的升高而减小,随着环境pH的增大而增大;NIPAM引入后,随着温度升高达到凝胶低临界溶解温度(LCST)时,凝胶平衡溶胀率及溶胀比减小明显加快,发生体积相变;随着NIPAM质量浓度的增大,凝胶溶胀饱和率减小,凝胶具备良好的延缓溶胀性能.     

ZnO一维纳米结构在金属基底上的原位生长和表征

以Cu—Zn合金片为基底并提供Zn源,在含氧气氛中通过调控反应温度和氧偏压,采用热氧化法直接在Cu-Zn合金片上大面积可控地合成了多种形貌的ZnO一雏纳米材料薄膜（包括纳米带、纳米片、纳米梳和纳米线等）,采用多种分析方法对产物的形貌、结构进行了详细的表征,并对其相应的生长模型进行了讨论。结果表明,反应温度和氧偏压对ZnO纳米结构的生长至关重要,随着反应温度升高或氧含量的减少,气相Zn／O物种的偏压比增加,ZnO纳米结构尺寸变小。     

Properties and pervaporation separation of hydroxyl‐terminated polybutadiene‐based polyurethane/poly(methyl metharcylate) interpenetrating networks membranes

Hydroxyl‐terminated polybutadiene (HTPB), 4,4′‐dicyclohexyl methane diiscyanate (H₁₂MDI), and 1,4‐butane diol are used to synthesize polyurethane (PU) solutions by two‐stage process. Interpenetrating networks (IPNs) of HTPB‐based PU and poly(methyl methacrylate) (PMMA) with HTPB/MMA (wt/wt % ratio) = 2.0, 1.5, 1.0, 1.5, 0.8, and 0.6, which are designated as IPN1 to IPN5, respectively, are synthesized by sequential polymerization technique. Thermal properties, tensile strength, and contact angle of membranes increase with the increase of MMA content, while the elongation of membranes show the reverse trend. Characterization of membranes are investigated by C?C/C?O absorption ratio and infrared absorption frequency shiftment. These PU and IPN membranes are used for the separation of ethanol/water and isopropanol/water solution by pervaporation test. IPN3 membrane possesses the largest pervaporation permeability and the separation factor. The pervaporation results of ethanol/water feed has the same trend as that of isopropyl alcohol (IPA)/water solution. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Synthesis and characterization of a positive‐working,aqueous‐base‐developable photosensitive polyimide precursor

A positive‐working, aqueous‐base‐developable photosensitive polyimide precursor based on poly(amic ester)‐bearing phenolic hydroxyl groups and a diazonaphthoquinone photosensitive compound was developed. The poly(amic ester) was prepared from a direct polymerization of 2,2′‐bis‐(3‐amino‐4‐hydroxyphenyl)hexafluoropropane and bis(n‐butyl)ester of pyromellitic acid in the presence of phenylphosphonic dichloride as an activator. Subsequently, the thermal imidization of the poly(amic ester) precursor at 300°C produced the corresponding polyimide. The inherent viscosity of the precursor polymer was 0.23 dL/g. The cyclized polyimide showed a glass‐transition temperature at 356°C and a 5% weight loss at 474°C in nitrogen. The structures of the precursor polymer and the fully cyclized polymer were characterized by Fourier transform infrared spectroscopy and ¹H‐NMR. The photosensitive polyimide precursor containing 25 wt % diazonaphthoquinone photoactive compound showed a sensitivity of 150 mJ/cm² and a contrast of 1.65 in a 3 μm film with 1.25 wt % tetramethylammonium hydroxide developer. A pattern with a resolution of 10 μm was obtained from this composition. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 352–358, 2002     

基于集成压控振荡器的调频电路仿真分析

LM566是一种积分-施密特触发电路型的单片集成 VCO 芯片,在调频电路的教学中作为调制器和解调器,通过对其芯片的仿真,可以在软件平台形象的展示其工作特点,便于定量分析。由于Multisim元件库里没有LM566所需模型,为实现LM566在Multisim12仿真环境中的建模,首先,运用Multisim元件库中现有的基本元件模型,构建LM566芯片内部结构;然后,对外围调频电路的静态工作方式和动态工作方式的分析;最后,实验结果表明,给出的芯片模型能够客观的描述LM566的基本特性,为运用该芯片完成包括调频电路在内的各种功能电路的仿真分析奠定了基础,有效扩展了Multisim仿真软件的使用范围,具有一定的借鉴意义。     

Relationship of structure to properties of surfactants. 16. Linear decyldiphenylether sulfonates

The properties of some well-characterized sodium linear decyldiphenylether (C₁₀DPE)sulfonates have been studied. Among the properties investigated are dynamic and equilibrium surface tension, critical micelle concentration (CMC), area per molecule at the aqueous solution/air interface, wetting time by the Draves technique, foaming by the Ross-Miles method, solubilization, and hydrotropy. The decyldiphenylether moiety appears to be equivalent to a terminally substituted straight alkyl chain of 16 carbon atoms. The trialkyl- and dialkyl-mono-sulfonates have solubilities of < 0.01 g/dm³ in water, but are readily soluble in hexane. The didecyldiphenyl ether disulfonate (DADS) has a very low CMC value (1.0 × 10⁻⁵ mol dm⁻³) in aqueous 0.1 N Na⁺ solution (NaCl), characteristic of surfactants with two hydrophilic and two hydrophobic groups. It also has a much larger area per molecule at the aqueous solution/air interface than the monodecyldiphenyl-ether monosulfonate (MAMS) and a much higher surface tension at the CMC. MAMS has a much lower surface tension at a surface age of 1 second (γ_1s) than either DADS or the monodecyldiphenylether disulfonate (MADS). In agreement with γ_1s and γ_eq values, wetting times increase in the order: MAMS < DADS < MADS and initial foam heights decrease in the order: MAMS > DADS > MADS. Solubilization for three water-insoluble surfactants decreases in the order: DADS > MAMS > MADS, while hydrotropy is most pronounced with the disulfonates.     

光纤通信中自相位调制与四波混频影响因素仿真

为了解决在高速率传输过程中,光纤介质的非线性效应及其在波分复用(WDM)系统中光信号造成的严重衰减问题,围绕自相位调制和四波混频两种非线性效应进行分析,采用Opti System模拟软件分析了造成SPM和FWM效应的主要变量因素.结果表明,输入功率、信道间隔以及色散是造成自相位调制和四波混频性能变化的主要原因,通过调整这些参数可以提高光纤传输性能,为进一步优化奠定了基础.     

既有建筑节能改造保温材料的NSGA-Ⅱ协同设计

保温措施是既有建筑节能改造中最有效的节能措施之一。在墙体节能改造设计中,保温材料种类及其厚度的确定是至关重要的,受到多个目标参数的制约和影响。基于反问题的研究方法,建立数值计算方法与多目标遗传算法NSGA-Ⅱ相结合的优化模型,以单位面积墙体全年总能耗和保温材料成本为目标参数,对成都地区某既有建筑墙体节能改造的保温材料种类与厚度进行了协同设计。结果表明,采用常规的保温厚度,常用的8种保温材料中有6种都不是最优解,但是可以通过改变保温材料的厚度或单价等方法使解向Pareto前沿逼近,以实现单位面积墙体年总能耗最小和改造成本最小之间的平衡。     

一种高效的虚拟桌面可信保证机制

虚拟桌面系统与传统PC桌面系统结构的不同,导致其在保证安全机制自身可信的同时,也会带来“语义差别”和效率降低等问题。本文提出了一种安全虚拟机完整性监控机制SVMIM（Security Virtual Machine Integrity Monitor）。SVMIM采用混杂模式的安全结构,基于可信计算技术对虚拟桌面系统的代码加载过程进行监视和控制,有效克服“语义差别”问题,并保证安全机制自身的可信;同时,SVMIM基于虚拟桌面网络引导机制,在网络存储端使用存储克隆技术,最大程度地降低安全机制对系统性能的影响。系统性能分析和基于SVMIM原型系统进行的实验表明该技术是可行的,并且相对于传统的虚拟桌面安全保障方案具有较大的性能优势。     

基于表面反应和扩散迁移控制的灰岩单裂隙渗流—溶解模型及其数值模拟

针对碳酸盐类可溶岩地区水电站坝址流场、化学场以及固相介质属性等随时间发生改变,从而对工程安全运行造成不利影响等问题,研究了灰岩地区地下水运移过程中各物理场间的相互作用,分析了影响灰岩溶解速率的两个因素,即表面反应控制和扩散迁移控制。在此基础上,建立了单裂隙中的渗流—溶解耦合模型,并进行数值求解。模拟结果表明,在垂直裂隙延伸方向,其溶蚀锋面为非齐整平面,而是呈似“虫洞”状非均一变化,而沿裂隙延伸方向即自上游侧向下游方向溶蚀程度逐渐减轻;而通过裂隙的流量呈现随时间逐渐增大的趋势,但变幅不大;根据流量求得的等效水力隙宽,其增幅和增长速率均小于实际平均隙宽;同时,化学场中Ca2+浓度的分布与裂隙开度变化具有相似性,不同时刻下上游侧反应速率R均大于下游侧。就反应机制而言,在初期均受表面反应控制,而随反应进行,位于上游补给区部位转为受扩散迁移控制,但在下游位置仍受表面反应控制。