Portable Infrared Spectrometer to Characterize and Differentiate Between Organic and Conventional Bovine Butter

The performance of a portable infrared system combined with pattern recognition to discriminate between organically and conventionally produced bovine butter samples as well as to predict the levels of conjugated linoleic acid (CLA) were evaluated. Sixty butter (27 organic and 33 conventional) samples were used in this study. Bovine butter–fat were applied onto an attenuated total reflectance infrared (ATR‐IR) accessory equipped with a five‐bounce ZnSe crystal set at 65 °C for spectral collection. In addition, ATR‐IR spectra of bovine butter were directly collected at room temperature to avoid phase separation. The fatty acid profile and the levels of CLA were determined using reference FAME‐GC‐FID analysis. SIMCA models showed well separated clusters that discriminated between organic and conventional bovine butters due to C=C trans bending out of the plane vibration modes band at 967 cm^?1. Additionally, strong PLSR models were developed to predict CLA levels using butter–fat and bovine butter spectra with SEP of 0.05 % and RPD of 4.7, indicating that the models are suitable for quality control applications. Portable IR technology offers the ability for “in situ” analysis of butters that is much less time consuming than current analytical practices for authentication and quality control efforts by the industry.     

Highly crystalline and oriented high‐strength poly(ethylene terephthalate) fibers by using low molecular weight polymer

High‐strength poly(ethylene terephthalate) (PET) fibers were obtained using low molecular weight (LMW) polymervia horizontal isothermal bath (hIB), followed by postdrawing process. We investigated the unique formations of different precursors, which differentiated in its molecular orientation and crystalline structures from traditional high‐speed spinning PET fibers. Sharp increase in crystallinity was observed after drawing process even though the fibers showed almost no any crystallinity before the drawing. Properties of as‐spun and drawn hIB and control filaments at different process conditions were compared. As would be expected, performances of resulted treated undrawn and drawn fibers have dramatically improved with developing unique morphologies. Tenacities more than 8 g/d for as‐spun and 10 g/d for drawn treated fibers after just drawn at 1.279 draw ratio were observed. These performances are considerably higher than that of control fibers. An explanation of structural development of high‐strength fibers using LMW polymer spun with hIB is proposed. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42747.     

Enhanced production of isoamyl acetate from beet molasses with addition of fusel oil by Williopsis saturnus var. saturnus

Fusel oil which contains high level of amyl alcohols (approximately 45–55%) is a by-product obtained from the distillation of alcohol made by fermentation of molasses. Williopsis saturnus is a yeast which is able to convert isoamyl alcohol into isoamyl acetate. The aim of this study was to increase the formation of isoamyl acetate by the addition of fusel oil at the ratios of 1%, 2% and 3% (v/v) to molasses based fermentation medium using W. saturnus. It was found out that bioconversion of added fusel oil into isoamyl acetate was possible and an addition of 1% fusel oil led to an increase in isoamyl acetate concentration from 118 to 354 mg/L.     

The effect of magnetic field on the impurity binding energy of shallow donor impurities in a Ga1?xInxNyAs1?y/GaAs quantum well

Using a variational approach, we have investigated the effects of the magnetic field, the impurity position, and the nitrogen and indium concentrations on impurity binding energy in a Ga_1−xIn_xN_yAs_1−y/GaAs quantum well. Our calculations have revealed the dependence of impurity binding on the applied magnetic field, the impurity position, and the nitrogen and indium concentrations.     

Synthesis of Various Calix[4]arene Derivatives with Mercaptoalkyl Chains and Their Application in Removing Cr(VI) from Aqueous Solution

Four different mercaptoalkyl-substituted calixarene derivatives (5,11,17,23-tetra-tert-butyl-25,27-bis(3-mercaptopropoxyl)-26,28-dihydroxycalix[4]arene, 25,27-bis(3-mercaptopropoxyl)-26,28-dihydroxycalix[4]arene, 25,27-bis(5-mercaptopentanoxyl)-26,28-dihydroxycalix[4]arene and 5,17-di-tert-butyl-11,23-di-carboxyl-26,28-bis(3-mercaptopropoxyl)-25,27-di-hydroxycalix[4]arene) were synthesized. Their structures were characterized by Fourier transform infrared spectroscopy (FTIR), ¹H and ¹³C NMR spectroscopy, and elemental analysis techniques. Moreover, their extraction capabilities at different parameters such as pH, shaking speed, and shaking time were examined toward dichromate ions. Results implied that all mercaptoalkyl-substituted calixarene derivatives showed an extraction capability toward dichromate anion while the carboxyl-functionalized calixarene-marcapto-alkyl derivative exhibited the highest extraction capability.     

Dual gas jet-assisted fibre laser blind cutting of dry pine wood by statistical modelling

This paper presents a statistical analysis of the performance of an Ytterbium fibre laser utilising single and dual gas jets in a single pass to blind cut dry pine wood. Cutting wood with lasers is a multi-factor process and a proper combination of the parameters involved is needed to achieve high quality and optimum process efficiency. This study employs design of experiments and statistical modelling approach to investigate the significant process parameters along with their interactions. A high brightness, 1 kW IPG single mode Ytterbium-doped fibre laser was employed to produce blind cuts on samples of dry pine wood. The experiments were performed parallel to the direction of the wood fibre. The parameters investigated include laser power, focal plane position, traverse speed, gas pressure and single and dual gas jets. Results were compared using a number of process responses which define the efficiency of the cut in terms of kerf depth, mass removal and energy consumption as well as quality of the cut section considering the heat-affected zone, kerf width and roughness of the edge of the surface. It has been found that application of an additional gas jet produced a surface finish superior to the single jet.     

Jacobian Coordinates on Genus 2 Curves

This paper presents a new projective coordinate system and new explicit algorithms which together boost the speed of arithmetic in the divisor class group of genus 2 curves. The proposed formulas generalize the use of Jacobian coordinates on elliptic curves, and their application improves the speed of performing cryptographic scalar multiplications in Jacobians of genus 2 curves over prime fields by an approximate factor of 1.25x. For example, on a single core of an Intel Core i7-3770 (Ivy Bridge), we show that replacing the previous best formulas with our new set improves the cost of generic scalar multiplications from 239,000 to 192,000 cycles and drops the cost of specialized GLV-style scalar multiplications from 155,000 to 123,000 cycles.     

Stress-strain response of a cast 319-T6 aluminum under thermomechanical loading

The stress-strain behavior of cast 319-T6 aluminum-copper alloys with three different secondary dendrite arm spacings (SDASs) was studied at high temperatures and under thermomechanical deformation, exposing marked cyclic softening. A two state-variable unified inelastic constitutive model proposed earlier was modified to describe the stress-strain responses of these alloys by considering the variation of hardening and recovery functions of back-stress and drag stress. The SDAS was incorporated in the model as a length-scale parameter, and the material constants were determined systematically from experiments on a cast 319-T6 aluminum with small and large SDASs. The capabilities of the constitutive model were checked by the comparisons of simulations to experiments in the small-strain regime (<0.005). The results show that the model provides successful simulations for material response after thermal exposure at high temperature and cyclic transient stress-strain behavior. The causes of mechanical behaviors at the macro scale are discussed based on microstructural changes during thermal exposure.     

Swage casting of A380 alloy

Swage casting is a new casting technique which combines the advantages of squeeze, centrifugal and semi-solid casting methods. In this new casting method, components with one rotating axis can be produced on a swage casting machine from molten metal in a one-step operation. A shape like a “bomb-body” is chosen to demonstrate the advantages of this new method by using A380 Al–Si–Cu alloy. The same alloy is also cast with centrifugal and squeeze casting methods. In this study, the swage casting method and its features are briefly described. The final microstructures, mechanical properties and amount of porosity of the cast pieces produced by squeeze, centrifugal and swage casting methods are compared. Swage cast pieces showed a different composition of microstructure that consists of fine dendritic particles at the chill ends and a mixture of spherical and rosette shaped particles at the core. The swage cast pieces also have a slightly higher mechanical strength as indicated by tensile strength and Brinell hardness values.