Structural Explanation of the Dielectric Enhancement of Barium Titanate Nanoparticles Grown under Hydrothermal Conditions

When synthesized under certain conditions, barium titanate (BaTiO₃, BTO) nanoparticles are found to have the non-thermodynamic cubic structure at room temperature. These particles also have a several-fold enhanced dielectric constant, sometimes exceeding 6000, and are widely used in thin-layer capacitors. A hydrothermal approach is used to synthesize BTO nanocrystals, which are characterized by a range of methods, including X-ray Rietveld refinement and the Williamson–Hall approach, revealing the presence of significant inhomogeneous strain associated with the cubic phase. However, X-ray pair distribution function measurements clearly show the local structure is lower symmetry than cubic. This apparent inconsistency is resolved by examining 3D Bragg coherent diffraction images of selected nanocrystals, which show the existence of ≈50 nm-sized domains, which are interpreted as tetragonal twins, and yet cause the average crystalline structure to appear cubic. The ability of these twin boundaries to migrate under the influence of electric fields explains the dielectric anomaly for the nanocrystalline phase.     

Deposition of Carotenoids in Eggs from Hens Fed Diets Containing Saponified and Unsaponified Oleoresin Paprika

Deposition of carotenoids in saponified paprika (SP) and unsaponified oleoresin paprika (OP) in egg yolks as well as the dietary level for desired pigmentation were evaluated. Sixty-four hens on a carotenoid-depletion diet were divided into two replicated groups of each of eight dietary treatments containing from 0 to 16 mg paprika carotenoids per kg feed. Colour and the carotenoid content of egg yolk increased linearly ( P< 0·01) with the amounts of paprika carotenoids in the diets. The colours of egg yolks from hens fed similar concentra-tions of OP or SP were not significantly different ( P< 0·01). A low dose (4 mg kg⁻¹) of OP or SP provided yolk colour equivalent to the colour of eggs in supermarkets. High-performance liquid chromatographic analyses showed that carotenoids deposited in the yolk are in the free alcohol form, regardless of the form of carotenoids in the diet. Capsanthin, the predominant carotenoid in paprika, was deposited in egg yolk less efficiently than zeaxanthin and lutein.     

The glucosinolate content of the leaf and stem of fodder kale (Brassica oleracea L.), rape (Brassica napus L.) and radicole (Raphanobrassica)

The glucosinolate content of three fodder kales, one fodder rape, one semi-artificial rape and one radicole were determined. The major glucosinolates (mmol kg^?1 dry matter) were: in kale leaf, glucobrassicin (3.21) and sinigrin (3.12); in kale stem, sinigrin (5.82); in rape leaf, gluconapin (3.14) and progoitrin (13.99); in rape stem, gluconapin (3.29) and progoitrin (20.18); in semi-artificial rape leaf, gluconapin (25.64) and progoitrin (9.00); in semi-artificial rape stem, gluconapin (35.33) and progoitrin (12.08); in radicole leaf, progoitrin (4.74) and glucobrassicin (3.28); and in radicole stem, gluconapin (3.26) and progoitrin (5.53). The implications for plant breeding are discussed.     

Suppression of phonon‐mediated hot carrier relaxation in type‐II InAs/AlAsxSb1 − x quantum wells: a practical route to hot carrier solar cells

InAs/AlAs_xSb_{1 − x} quantum wells are investigated for their potential as hot carrier solar cells. Continuous wave power and temperature‐dependent photoluminescence indicate a transition in the dominant hot carrier relaxation process from conventional phonon‐mediated carrier relaxation below 90 K to a regime where inhibited radiative recombination dominates the hot carrier relaxation at elevated temperatures. At temperatures below 90 K, photoluminescence measurements are consistent with type‐I quantum wells that exhibit hole localization associated with alloy/interface fluctuations. At elevated temperatures, hole delocalization reveals the true type‐II band alignment, where it is observed that inhibited radiative recombination due to the spatial separation of the charge carriers dominates hot carrier relaxation. This decoupling of phonon‐mediated relaxation results in robust hot carriers at higher temperatures, even at lower excitation powers. These results indicate type‐II quantum wells offer potential as practical hot carrier systems. Copyright © 2016 John Wiley & Sons, Ltd.     

Thermoelectric Properties of NaCo<Subscript>2–<Emphasis Type="Italic">x</Emphasis></Subscript>Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript><Emphasis Type="Italic">y</Emphasis></Subscript>

NaCo₂O₄ has one of the highest figures of merit among all ceramic thermoelectric materials. Because of its large thermopower and low resistivity, the ceramic oxide NaCo₂O₄ is a promising candidate for potential thermoelectric applications. NaCo₂O₄ is, moreover, a ceramic compound with high decomposition temperature and chemical stability in air and it does not contain any toxic elements. Like all 3-d transition ions, Co ions have multiple spin and oxidation states. In this investigation, thermopower and electrical conductivity of NaCo₂O₄ as a function of substitution of Co by Fe ions were measured. Fe substitution for Co causes resistivity to increase, whereas the Seebeck coefficient remained nearly invariant, especially above 330 K. An erratum to this article can be found at     

触摸屏技术的发展

触摸屏让人机交互更直截了当 DisplaySearch的预测表明到2016年整个触摸屏市场的价值将可能达到140亿美元,是去年的3倍多。目前很多新的应用领域开始看到触控技术的优势,从而产生巨大的滚雪球效应。一些电子设备和装置将这种直观方法用于其用户界面,并能够在竞争产品中脱颖而出。因此。OEM已经在关注这一技术,希望借此增加市场份额。下文介绍了触摸屏的“简短历史”一从最初的无足轻重,到今天几乎无处不在的地位。     

Improved barium fluoride process YBa2Cu3)7-x films via post-anneal monitoring

The continuous monitoring of the conversion, of Y, Cu and BaF₂ precursors to form superconductor thin films has been achieved using a fluorine-specific-ion electrode immersed in an effluent gas-washing cell. High-quality thin films of YBa₂Cu₃O_7-x deposited on NdGaO₃, LaA10₃ and LaGaO₃, have been produced by limiting the wet oxygen annealing phase of the post-deposition anneal. When the films were over-annealed in humidified oxygen the superconducting transition temperature as measured by inductive methods and the crystal quality, determined by x-ray rocking curves were degraded.     

Modeling of spiking analog neural circuits using organic semiconductor thin film transistors with silicon oxide nitride semiconductor gates

This paper uses the results of the characterization of amorphous semiconductor thin film transistors (TFTs) with the quasi-permanent memory structure referred to as silicon oxide nitride semiconductor (SONOS) gates, to model spiking neural circuits. SONOS gates were fabricated and characterized. In addition, MOSFETs using organic copper phthalocyanine (CuPc) were fabricated with these SONOS gates to demonstrate proof of concept performance. Analog spiking circuits were then modeled using these low performance TFTs to demonstrate the general suitability of organic TFTs in neural circuits. The basic circuit utilizes a standard comparator with charge and discharge circuits. A simple Hebbian learning circuit was added to charge and discharge the SONOS device. The use of these elements allows for the design and fabrication of high-density 3-dimensional circuits that can achieve the interconnect density of biological neural systems.     

Nutritional aspects of soft drinks

The metabolic consequences in man, both immediate and long term, of consuming soft drinks are discussed. Emphasis is placed on the role in energy and lipid metabolism of various carbohydrate constituents, on the effects on gastric emptying of the various constituents and on the biochemical implications of fructose containing drinks.     

Facile Synthesis of Red/NIR AIE Luminogens with Simple Structures,Bright Emissions,and High Photostabilities,and Their Applications for Specific Imaging of Lipid Droplets and Image‐Guided Photodynamic Therapy

Red/near‐infrared (NIR) fluorescent molecules with aggregation‐induced emission (AIE) characteristics are of great interest in bioimaging and therapeutic applications. However, their complicated synthetic approaches remain the major barrier to implementing these applications. Herein, a one‐pot synthetic strategy to prepare a series of red/NIR‐emissive AIE luminogens (AIEgens) by fine‐tuning their molecular structures and substituents is reported. The obtained AIEgens possess simple structures, good solubilities, large Stokes shifts, and bright emissions, which enable their applications toward in vitro and in vivo imaging without any pre‐encapsulation or ‐modification steps. Excellent targeting specificities to lipid droplets (LDs), remarkable photostabilities, high brightness, and low working concentrations in cell imaging application make them remarkably impressive and superior to commercially available LD‐specific dyes. Interestingly, these AIEgens can efficiently generate reactive oxygen species upon visible light irradiation, endowing their effective application for photodynamic ablation of cancer cells. This study, thus, not only demonstrates a facile synthesis of red/NIR AIEgens for dual applications in simultaneous imaging and therapy, but also offers an ideal architecture for the construction of AIEgens with long emission wavelengths.