Influence of sn‐1,3‐lipase‐catalysed interesterification on the oxidative stability of soybean oil‐based structured lipids

The oxidative stability of structured lipids (SLs) synthesised by specific sn‐1,3‐lipase catalysed interesterification of soybean oil (SBO) with caprylic acid (CA) in a stirred batch reactor was studied. SLs contained considerable amounts of tocopherol (TOH) isomers, although they lost almost 25% of endogenous TOHs during production. The effects of the addition of different TOH homologues (α, β, γ, δ), ascorbyl palmitate (AP, 200 ppm), lecithin (Le, 1000 ppm), butylated hydroxytoluene (BHT, 100 ppm) and butylated hydroxyanisole (BHA, 100 ppm) on the oxidative stability of SLs were investigated. Induction time (IT) of SBO, determined by the Rancimat method, decreased from 8.4 to 5.8 h at 110 °C after the modification. On the other hand, purified SLs and purified SBO had the same IT due to the tocopherol reduction during silica purification. No significant difference was observed between IT of SLs and SLs plus different α‐tocopherol concentrations (50, 100, 150, 200, 300, 500 and 1000 ppm) (P > 0.05). However, the addition of Le and/or AP significantly improved oxidative stability of purified SLs and SBO. The ternary blend containing δ‐TOH, AP and Le had higher IT than ternary blends of α‐TOH, β‐TOH or γ‐TOH. Furthermore, ternary blend containing BHA, AP and Le had higher IT than ternary blends of BHT, AP and Le. In addition, there was an increase in peroxide value (PV), conjugated diene (CD) content and p‐anisidine value (AV) during oxidation of oils at 60 °C. Antioxidant mixtures of α‐TOH (50 ppm) and δ‐TOH (500 ppm) with AP and Le decreased PV, CD and AV effectively. Copyright © 2006 Society of Chemical Industry     

Design of a front-end integrated circuit for 3D acoustic imaging using 2D CMUT arrays

Integration of front-end electronics with 2D capacitive micromachined ultrasonic transducer (CMUT) arrays has been a challenging issue due to the small element size and large channel count. We present design and verification of a front-end drive-readout integrated circuit for 3D ultrasonic imaging using 2D CMUT arrays. The circuit cell dedicated to a single CMUT array element consists of a high-voltage pulser and a low-noise readout amplifier. To analyze the circuit cell together with the CMUT element, we developed an electrical CMUT model with parameters derived through finite element analysis, and performed both the pre- and postlayout verification. An experimental chip consisting of 4 X 4 array of the designed circuit cells, each cell occupying a 200 X 200 microm2 area, was formed for the initial test studies and scheduled for fabrication in 0.8 microm, 50 V CMOS technology. The designed circuit is suitable for integration with CMUT arrays through flip-chip bonding and the CMUT-on-CMOS process.     

Determining the Effective Constitutive Parameters of Finite Periodic Structures: Photonic Crystals and Metamaterials

A novel approach to find the effective electric and magnetic parameters of finite periodic structures is proposed. The method uses the reflection coefficients at the interface between a homogenous half-space and the periodic structure of different thicknesses. The reflection data are then approximated by complex exponentials, from which one can deduce the wavenumber, and the effective electric and magnetic properties of the equivalent structure by a simple comparison to the geometrical series representation of the generalized reflection from a homogenous slab. Since the effective parameters are for the homogenous equivalent of the periodic structure, the results obtained are expected to be independent of the number of unit cells used in the longitudinal direction. Although the proposed method is quite versatile and applicable to any finite periodic structure, photonic crystals and metamaterials with metallic inclusions have been used to demonstrate the application of the method in this paper.     

Ultra-Robust Flexible Electronics by Laser-Driven Polymer-Nanomaterials Integration

Polyethylene terephthalate (PET) is the most widely used polymer in the world. For the first time, the laser-driven integration of aluminum nanoparticles (Al NPs) into PET to realize a laser-induced graphene/Al NPs/polymer composite, which demonstrates excellent toughness and high electrical conductivity with the formation of aluminum carbide into the polymer is shown. The conductive structures show an impressive mechanical resistance against >10000 bending cycles, projectile impact, hammering, abrasion, and structural and chemical stability when in contact with different solvents (ethanol, water, and aqueous electrolytes). Devices including thermal heaters, carbon electrodes for energy storage, electrochemical and bending sensors show this technology's practical application for ultra-robust polymer electronics. This laser-based technology can be extended to integrating other nanomaterials and create hybrid graphene-based structures with excellent properties in a wide range of flexible electronics’ applications.     

Maximization of heat transfer density from a vertical array of flat tubes in cross flow under fixed pressure drop using constructal design

The density of heat transfer rate from a vertical array of flat tubes in cross flow is maximized under fixed pressure drop using constructal design. With the constructal design, the tube arrangement is found such that the heat currents from the tubes to the coolant flow easily. The constraint in the present constructal design is the volume where the tubes are arranged inside it. The two degrees of freedom available inside the volume are the tube‐to‐tube spacing and the length of the flat part of the tubes (tube flatness). The tubes are heated with constant surface temperature. The equations of continuity, momentums, and energy for steady, two‐dimensional, and laminar forced convection are solved by means of a finite‐volume method. The ranges of the present study are Bejan number (dimensionless pressure drop) (10³ ≤ Be ≤ 10⁵) and tube flatness (dimensionless length of the tube flat part) (0 ≤ F ≤ 0.8). The coolant used is air with Prandtl number (Pr = 0.72). The results reveal that the maximum heat transfer density decreases when the tube flatness decreases at constant Bejan number. At constant tube flatness, the heat transfer density increases as the dimensionless pressure drop (Bejan number) increases. Also, the optimal tube‐to‐tube spacing is constant, irrespective of the tube flatness at constant Bejan number.     

Effect on Particle Size to Emitted X-Ray Intensity in Pellet Cement Sample Analyzed with WDXRF Spectrometer

Abstract

The particle size and heterogeneity effects on the analyte line were investigated for the analysis of powdered samples by X-ray fluorescence technique. In the analysis of samples utilizing the powder method, these effects caused serious errors with variations in particle size for the emitted intensity. The fluorescence intensities of some elements in pellet samples of cement (the range of particle sizes, < 32 µm, 32–38 µm, 38–45 µm, 45–63 µm, 45–75 µm, 75–106 µm, and 106–150 µm and, at press pressure 3.50 and 1.41 × 10⁷ kg/m²), are measured using a wavelength dispersive X-ray fluorescence (WDXRF) spectrometer for 14 pellets prepared according to the powder method. The results show that the K _α X-ray fluorescence intensities from samples can effect about 17% maximum differences in normalized intensities within selected particle sizes. These experimental results were interpreted by comparing with the other experimental results in the literature.     

Using LaModel to analyze coal bumps

Coal bumps have long been a safety hazard in coal mines, and even after decades of research, the exact mechanics that cause coal bumps are still not well understood. Therefore, coal bumps are still difficult to predict and control. The LaModel program has a long history of being used to effectively analyze displacements and stresses in coal mines, and with the recent addition of energy release and local mine stiffness calculations, the LaModel program now has greatly increased capabilities for evaluating coal bump potential. This paper presents three recent case histories where coal stress, pillar safety factor, energy release rate and local mine stiffness calculations in LaModel were used to evaluate the pillar plan and cut sequencing that were associated with a number of bumps. The first case history is a longwall mine where a simple stress analysis was used to help determine the limiting depth for safely mining in bump-prone ground. The second case history is a room-and-pillar retreat mine where the LaModel analysis is used to help optimize the pillar extraction sequencing in order to minimize the frequent pillar line bumps. The third case history is the Crandall Canyon mine where an initial bump and then a massive pillar collapse/bump which killed 6 miners is extensively back-analyzed. In these case histories, the calculation tools in LaModel are ultimately shown to be very effective for analyzing various aspects of the bump problem, and in the conclusions, a number of critical insights into the practical calculation of mine failure and stability developed as a result of this research are presented.     

The Characteristic Parameters of Ni/<Emphasis Type="Italic">n</Emphasis>-6H-SiC Devices Over a Wide Measurement Temperature Range

Ni/n-type 6H-SiC/Ni Schottky barrier diodes (SBDs) have been prepared by the DC magnetron sputtering deposition technique. Their current-voltage characteristics (I-V) have been measured in the measurement temperature range of 40-400 K with steps of 20 K under dark conditions. The barrier height (BH) values from the temperature-dependent forward and reverse bias I-V characteristics by different methods coincide with each other which indicates the elimination of the polarity between the Si and C ions. The ideality factor value remains almost unchanged in the 160-400 K range, and below 160 K, it has the values of 1.57 at 140 K, and 3.82 at 60 K. The BH has the values of 0.79 eV at 400 K, and 0.71 eV at 300 K. The decrease in the BH is due to the fact that the current will preferentially flow through the lowest BH with decreasing temperature due to barrier inhomogeneity. The value of 0.71 eV at 300 K is in close agreement with the values of 0.65 and 0.83 eV reported from the forward bias I-V characteristics for the Ni /n-type 6H-SiC in the literature. Thus, it has been concluded that the reduced barrier devices are promising for applications in devices operating at cryogenic temperatures as infrared detectors, sensors in thermal imaging and small signal zero-bias rectifiers and microwave mixers.     

Second Stage Gas Turbine Blade Premature Replacement Investigation

This article investigates the root causes of the premature failure and replacement of a set of second-stage turbine blades from a heavy industrial gas turbine engine. The investigations included dye-penetrant testing, optical microscopy, X-ray diffractometry (XRD), Environmental Scanning Electron Microscopy (ESEM), and energy dispersive X-ray spectroscopy (EDS) techniques. Moreover, the effect of heat treatment process on restoring the blade microstructure so that the properties were suitable for service was also explored. As a result of the investigation, the second-stage turbine blades premature failure was attributed to the grain boundary secondary phase precipitates. These precipitates were present in the “as-found” condition of the investigated blades.