二苯甲酮-β-环糊精包合物的制备表征

采用研磨法合成了二苯甲酮-β-环糊精包合物,经差示量热扫描分析、热重分析、红外分析、X射线衍射分析、对包合物进行了鉴定,证明二苯甲酮-β-环糊精确实形成了一种新的体系.     

Preparation of micron‐size monodispersed PS/P(St/MAA) microspheres by seeded dispersion polymerization

Uniform polystyrene (PSt) particles with the size of 1.9 μm were first prepared via dispersion polymerization, and then used as the seeds in a second‐stage dispersion copolymerization of styrene (St) and methacrylic acid (MAA) to produce carboxyl‐carrying microspheres. The PSt seed particles were swollen by monomer mixture of St and MAA, including an oil‐soluble initiator 2,2′‐azobisiso‐butyronitrile (AIBN), before polymerization. Finally, uniform PS/P(St/MAA) (polydispersity index, PDI = 1.02) microspheres with the size of 2.2 μm were obtained. The average particle size and size distribution of the final microspheres were investigated. MAA contents between 54 and 97 mg/g were detected from the PS/P(St/MAA) particles produced under different conditions. Dispersion medium has great influence on the kinetics of polymerization, due to its effect on the partitioning of monomers, solvents, and initiator in the particle phase, probably as well as on the conformation of the dispersion agent on the surface of the particles. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3586–3591, 2006     

MgO－B_2O_3－SiO_2系晶化分形的计算机模拟

采用两段热处理技术，利用Ｘ射线衍射分析、扫描电镜观察等方法研究广２ＭｇＯ－Ｂ＿２Ｏ＿３－ＳｉＯ＿２系的晶化过程，晶化析出相２ＭｇＯ·Ｂ＿２Ｏ＿３的微观形貌具有分形特征，采用密度－密度相关函数法计算其分形维数为１．６３。为揭示２ＭｇＯ·Ｂ＿２Ｏ＿３生长机制，采用Ｍｏｎｔｅ－Ｃａｒｌｏ方法及改进的ＤＬＡ模型对分形生长过程进入计算机模拟。模拟结果与实际分形结构、分形维数相符，表明２ＭｇＯ·Ｂ＿２Ｏ＿３生长是扩散控制凝聚过程。可以预见，分形理论与计算机模拟相结合，将会在探讨未知机理方面发挥重要作用。     

Synthesis and dielectric properties of polystyrene‐clay nanocomposite materials

Polystyrene‐clay nanocomposite (PsCN) materials were synthesized and their properties of crystallinity, thermal behavior, and dielectric characteristics were investigated. A polymerizable cationic surfactant, [2‐(dimethylamino)ethyl]triphenylphonium bromide, was used for the intercalation of montmorillonite (MMT). The organophilic MMT was prepared by Na⁺‐exchanged MMT and ammonium cations of a cationic surfactant in an aqueous medium. Organophilic styrene monomers were intercalated into the interlayer regions of organophilic clay hosts followed by a free‐radical polymerization. Exfoliation to 2 wt % MMT in the polystyrene (PS) matrix was achieved as revealed by X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Thermal properties by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were also studied. The dielectric properties of PsCNs in the form of film with clay loading from 1.0 to 5.0 wt % were measured under frequencies of 100 Hz–1 MHz at 25–70°C. A decreased dielectric constant and low dielectric loss were observed for PsCN materials. The dielectric response at low frequency that originated from dipole orientation was suppressed due to the intercalation of clay materials. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1368–1373, 2004     

基于模糊PID的电液位置伺服控制器设计研究

介绍了电液位置伺服控制系统的组成与工作原理,并建立了系统的数学模型。将模糊控制与PID控制结合在一起,设计了模糊PID控制器,即通过模糊控制器输出对PID参数进行在线调整。利用MATLAB软件进行仿真,比较常规PID控制与模糊PID控制仿真结果,发现模糊PID控制器提高了系统的动态性能和稳态特性。     

替硝唑在水溶液中溶解度的实验测定及关联

通过自制的固一液平衡装置,采用高效液相色谱法分别测定了温度在278.15～31.815 K时替硝唑在纯水、5%葡萄糖溶液和0.9%氯化钠溶液中的溶解度,并对实验数据分别采用理想溶液模型和经验方程进行了关联.对于纯水体系和0.9%氯化钠溶液体系,实验数据用理想溶液模型关联能较满意地表征实验结果.两种关联方法中,经验方程能较好地关联所测得的溶解度数据,误差较小.     

Infrared reflectance and transmission spectra of semiconducting non-stoichiometric CdGe x As2

The infrared reflectance and transmission spectra of amorphous CdGe _x As₂ were investigated to study the amorphous structure with varying Ge content. The mid-infrared optical absorption edges of amorphous CdGe _x As₂ with 0<x<1.2, were observed in the range 1.6–1.7 m, indicating a structural similarity in short-range order throughout. Comparing the reflectance and transmission spectra of amorphous and devitrified crystalline phases established that the structures of amorphous CdGe _x As₂ transformed from the CdAs₂ basic structure to the chalcopyrite (CdGeAs₂) structure, as one progressed fromx=0 tox=1.2. The infrared spectra were interpreted interactively with radial distribution function, magnetic susceptibility, density measurements, and crystallization studies. The crystallization behaviour of amorphous CdGe _x As₂ that was heat treated at different temperatures was investigated using far-infrared transmission spectra.     

基于深度学习的集群式供应链应急物资需求预测研究

在突发事件和大数据情景下,建立基于数据流模糊C均值聚类算法的集群式供应链应急物资需求重要度决策算法,有助于辨识集群式供应链子系统应急物资需求的重要程度。针对集群式供应链中各子供应链之间的耦合特性和预测指标的快速变化数据流特征,提出基于长短期记忆网络的集群式供应链应急物资需求动态预测算法,提取集群式供应链多个子系统应急物资需求参数的时序特征,动态地、分布地对互联大系统的应急物资需求不确定性进行系统辨识估计。仿真实验结果表明了基于长短期记忆网络的集群式供应链互联大系统应急物资需求动态预测算法的可行性和精确性。     

基于工程教育认证的《C语言程序设计》教学改革与实践

《C语言程序设计》是高校理工类非计算机专业学生的公共基础课。在工程教育认证背景下,如何满足工程认证标准,培养社会所需要的复合型专业人才,为课程的教学改革提出了新要求。紧密围绕新目标,整合教学内容、增加综合实验、建设线上资源、完善教材、部分教学内容采用翻转课堂教学,全方位提高学生学习积极性主动性,为培养学生解决复杂工程问题的能力打下坚实的基础。     

Supervised discrete hashing through similarity learning

Multimedia Tools and Applications - Supervised hashing has achieved better accuracy than unsupervised hashing in many practical applications owing to its use of semantic label information. However,...