Nostoc Linckia as Biosorbent of Chromium and Nickel from Electroplating Industry Wastewaters

The present study relates to the use of cyanobaeterium Nostoc linkia for removal of chromium and nickel from wastewater of galvanic industry. To determine concentrations of Cr and Ni in wastewater samples atomic absorption spectrometry was used. The samples of dried nostoc biomass after exposure to wastewater were subject to nondestructive instrumental neutron activation analysis. During 30 rain of the contact ofbiomass with wastewater 84% of chromium was removed from the wastewaters. Beside chromium after 30 rain nostoc biomass accumulates the amount of iron and zinc that exceeds their concentrations in the control biomass samples by a factor of 6 and 8, respectively. Nickel content in biomass after interaction with Cr-containing wastewater increases sixty fold and copper-sixteen fold. During the same time of biomass-Ni-containing wastewater interaction, 50% of nickel were accumulated. The method of Fourier transform infrared spectroscopy was applied to identify functional groups responsible for metal binding.     

一款数字化血压监护仪参考设计

数字化血压监护仪可以帮助内科医生诊断出高血压病并帮助患者控制高血压.便携式血压监护仪则能让病人在家里无需医生就可以经济地测量血压,从而有助于早期诊断和高血压控制.本文将介绍一款飞思卡尔公司的血压监护仪参考设计.     

Short-term and moderate UV-B radiation effects on secondary plant metabolism in different organs of nasturtium (Tropaeolum majus L.)

Glucotropaeolin and total phenolic concentrations were assessed in three different organs (inflorescences, leaves, unripe seeds) of nasturtium (Tropaeolum majus L.), which are consumed as herbal plant products, in order to determine the effect of short-term and moderate UV-B exposure as targeted postharvest stress treatment on the secondary plant metabolism. For this purpose, nasturtium plants were subjected to two UV-B radiation levels: 0.075 and 0.15 W h m^? 2. The results clearly demonstrate that the plant response to short-term and moderate UV-B exposure is organ-, plant tissue age-, and phytochemical-specific and that these factors influence a change of secondary metabolism as revealed by the different phytochemical concentration levels elicited.Industrial relevanceIn food processing UV treatment is mainly attributed to disinfection. This study examined the feasibility of short-term and moderate UV-B application as emerging technology for enhancing health-promoting phytochemicals in freshly consumed plant products (inflorescences, leaves, unripe seeds) demonstrated by the herbal plant nasturtium. Optimizing phytochemical concentration by targeted postharvest UV-B applications will add health value and subsequently generate new opportunities for growers and processors by achieving the health-oriented food market.     

GIS-supported mapping of shallow geothermal potential of representative areas in south-western Germany—Possibilities and limitations

The increasing interest in the utilization of shallow geothermal energy comes with the wish for better knowledge about the factors influencing its efficiency. For this purposes we focused on the subsurface condition's influence on the use of borehole heat exchangers (BHEs) coupled with a heat pump for heating purposes, since this is the most popular heat-extracting technique. We created maps showing the potential for this technique provided by the thermal underground properties. Therefore, we established an underground model for two study areas in south-western Germany with different geological settings using a geographic information system (GIS). The subsurface has been divided into layers with similar thermal properties based on geological, hydrogeological and lithological information. The layers have been attached with specific heat extraction values, according to the German VDI guideline 4640. For depths of 50 and 100 m, the weighted mean value of the specific heat extraction was calculated and presented within maps. These maps point out how the heat-extraction potential differs within and between the study areas and how it depends on depth.     

Real-Time Optimization Using Machine Learning Models Applied to the 4,4′-Diphenylmethane Diisocyanate Production Process

In this work, the optimal time-varying allocation of steam in a large-scale industrial isocyanate production process is addressed. This is a problem that falls into the category of real-time optimization (RTO). The application of RTO in practice faces two problems: First the available rigorous process models may not be suitable for use in real-time connected to the process. Second, there is always a mismatch between the predictions of the model and the behavior of the real plant. We address the first problem by training a neural net model as a surrogate to data generated by a rigorous simulation model so that the model is simple to implement and short execution times result. The second problem is tackled by adapting the optimization problem based on measured data such that convergence to the optimal operating conditions for the real plant is achieved.     

From nanoscale liquid spheres to anisotropic crystalline particles of tin: decomposition of decamethylstannocene in organic solvents

Routes are presented for synthesizing nano- and mesostructured β-tin particles in the form of monocrystalline spheres, cubes, and bars, as well as polycrystalline rods and needles, by the decomposition of decamethylstannocene in organic solvents under various conditions. The formation of the observed shapes is based on the presence of liquidlike and of partly crystalline droplets. These particle stages allow structure-determining processes such as entire coalescence, oriented superficial coalescence or superficial induced crystallization. Entire coalescence and oriented superficial coalescence take place in the absence of surfactants; the superficially induced crystallization occurs in the presence of ionic additives. The observed tin morphologies depend on the competition between droplet growth and crystallization behavior. The different tin particles are investigated by electron microscopy (SEM, TEM, HRTEM), selected area electron diffraction (SAED), and differential scanning calorimetry (DSC).     

Quasicontinuum simulation of crack propagation in bcc-Fe

We have investigated fracture in bcc-Fe through multiscale simulations. The quasicontinuum (QC) method with an embedded atom method (EAM) interatomic potential is applied. The analyses have been carried out assuming different crystallographic orientations and different T-stress under Mode I loading. Both anisotropic and isotropic formulations of the modified boundary layer (MBL) approach has here been investigated and compared. The results show that the mechanisms at the crack tip and the critical stress intensity factor K_Ic are sensitive to both the crystallographic orientation and whether or not the formulation of the boundary conditions are isotropic or anisotropic. Mechanisms such as cleavage crack propagation, twinning, and dislocation emission are observed in the analyses. A short literature review on atomistic and multiscale simulations of fracture in bcc-Fe has been performed and evaluated, and also compared with the current results.