Produkte der thermischen En-Reaktion von ungesättigten Fettstoffen und Maleinsäureanhydrid

Products of the Thermal Ene-Reaction of Unsaturated Fatty Compounds and Maleic Anhydride The thermal ene reaction of the methylates of unsaturated fatty acids 10-undecenoic acid, oleic acid and (E)-10-eicosendioic acid with maleic anhydride was carried out at 190°C. The mono addition products were isolated and their stereochemistry was deduced from ¹HNMR- and ¹³C-NMR-spectroscopy.     

Compact multiphoton/single photon laser scanning microscope for spectral imaging and fluorescence lifetime imaging

An inverted fluorescence microscope was upgraded into a compact three-dimensional laser scanning microscope (LSM) of 65 x 62 x 48 cm dimensions by means of a fast kHz galvoscanner unit, a piezodriven z-stage, and a picosecond (ps) 50 MHz laser diode at 405 nm. In addition, compact turn-key near infrared femtosecond lasers have been employed to perform multiphoton fluorescence and second harmonic generation (SHG) microscopy. To expand the features of the compact LSM, a time-correlated single photon counting unit as well as a Sagnac interferometer have been added to realize fluorescence lifetime imaging (FLIM) and spectral imaging. Using this unique five-dimensional microscope, TauMap, single-photon excited (SPE), and two-photon excited (TPE) cellular fluorescence as well as intratissue autofluorescence of water plant leaves have been investigated with submicron spatial resolution, <270 ps temporal resolution, and 10 nm spectral resolution.     

Creep-induced local lattice parameter changes in a monocrystalline nickel-base superalloy

The γ-γ lattice mismatch of specimens of the monocrystalline nickel-base superalloy SRR 99 has been measured by a high-resolution X-ray diffraction technique for the undeformed state and after high-tem-perature creep deformation. During creep deformation beyond the minimum creep rate (total strain =0.5%), the lattice mismatches, measured in and perpendicular to the [001] stress axis, respectively, un-dergo changes in opposite directions. This reflects the buildup of a complex deformation-induced triaxial state of internal stress in the phases y and γ. The overall resolved shear stresses that act in γ and y due to the combined action of the external and internal stresses are estimated, and the conditions under which cutting of the γ phase by dislocations should occur are discussed.     

Enhancing nitrification in vertical flow constructed wetland utilizing a passive air pump

Nitrification of simulated secondary effluent solution using a variant of the vertical flow bed constructed wetland was studied. In this system oxygen required for the nitrification process is supplied by a passive air pump. The passive air pump is based on a fill and draw cycle, where oxygen depleted air is removed from the system while fresh air is introduced. Each volume of effluent drained is displaced by an equal volume of fresh air. Spatial and temporal oxygen distribution in the system as a function of drained effluent volume was investigated. Experimental results of nitrification and the corresponding oxygen consumption show good agreement with theoretical calculations based on physico–chemical considerations. Observations show that while oxygen distribution within the media was found to be non-uniform at the beginning of each cycle, it approached more uniform distribution with time. The latter resulted mainly from diffusion of oxygen in the gaseous phase.     

Strategic Planning for Employment Self-Containment in Metropolitan Sub-Regions

Metropolitan strategic plans often focus on strengthening local employment opportunities to address the congestion and commuting issues threatening city sustainability. The success of such strategies relies on a more equitable distribution of jobs between sub-regions and can be comparatively benchmarked through one of the three related measures of employment self-sufficiency, self-containment or jobs-housing balance. However, in practice, planning policy implementation to meet these targets seldom reduces automobile commuting. This paper investigates self-containment across a range of occupation and industry types to highlight large differences in commuting and employment patterns through a case study of Perth’s Northwest sub-region, Western Australia. Its findings suggest the application of current sub-regional policy and targets within Perth may reinforce the wage and skill disadvantage of outer metropolitan sub-regions over the inner core. It recommends a more nuanced understanding of these measures taking into account the complex dynamics of both employment opportunities and commuting patterns across sub-regions of a city.     

Scale and scope of environmental planning transformations: The Israeli case

This paper explores the scale and scope of transformations in the environmental planning field, and the factors that may advance or impede their widespread adoption. A conceptual model is offered which examines scope (defined as type, breadth and structure of the transformation), and the scale of its impact (categorized as stakeholder, organizational, institutional or societal) and applies it to the analysis of several cases in Israel where environmental transformations, affecting the way in which planning is conducted, have been adopted. Conclusions include identification of conditions for facilitating and advancing transformations, including knowledge of innovative alternatives, initiative, willingness to adopt new practices, and identification of policy windows that emerge during conflict, reform, or crisis. The fostering of relations between environmental non-government organizations and planning systems and leadership roles are also significant in catalyzing environmental transformation.     

Embeddedness of regions in European knowledge networks: a comparative analysis of inter-regional R&D collaborations,co-patents and co-publications

This paper investigates the embeddedness of European regions in different types of inter-regional knowledge networks, namely project-based R&D collaborations within the European framework programmes (FPs), co-patent networks and co-publication networks. Embeddedness refers to the network positioning of regions captured in terms of social network analytic (SNA) centrality measures. The objective is to estimate how region-internal and region-external factors influence network embeddedness in the distinct network types, in order to identify differences in their driving factors at the regional level. In our modelling approach, we apply advanced spatial econometric techniques by means of a mixed effects panel version of the spatial Durbin model (SDM) and introduce a set of variables accounting for a capacity specific, a relational as well as a spatial dimension in regional knowledge production activities. The results reveal conspicuous differences between the knowledge networks. Internal capacity- and technology-related aspects but also spatial spillover impacts from surrounding regions prove to be particularly important for centrality in the co-patent network. We also find significant—region-internal and region-external—impacts of general economic conditions on a region’s centrality in the FP network. However, we cannot observe substantial spillover effects of region-external factors on centrality in the co-publication network. Thus, the distinctive knowledge creation foci in each network seem to find expression in the network structure as well as its regional determinants.     

“This is for the Children,the Grandchildren …”: Houses of Moroccan Immigrants in Metropolitan Tel Aviv

The meaning of migrant housing materiality has not been adequately researched, especially when compared to the meaning of the home for immigrants, a matter of extensive discussion in the past two decades. This paper focuses on the meaning of housing materiality for 12 immigrants who migrated from Morocco to Israel some 60?years ago. Drawing on qualitative data gathered in 2007 and 2008, the paper develops a theoretical framework considering “house as community” and “house materiality” as two interrelating explanations for the migrant housing materiality. Through this framework, and with the concepts of performance and performativity, the paper first explores former houses of participants in Morocco and then presents current houses in Tel Aviv, Israel, to establish links between the two housing forms and reveal the meanings of objects in the homes. It is argued that as a reaction to the dominant Israeli society, housing materiality enables participants to educate successive generations and Israeli society at large about the rich cultural life of Moroccan-Jews that existed before their migration to Israel.     

R&D networks and regional knowledge production in Europe: Evidence from a space‐time model

In this study we estimate space‐time impacts of the embeddedness in R&D networks on regional knowledge production using a dynamic spatial panel data model with non‐linear effects for 229 European NUTS 2 regions in the period 1998–2010. Embeddedness refers to the positioning in networks where nodes represent regions that are linked by joint R&D projects funded by EU Framework Programmes. We find evidence that increasing embeddedness in EU funded R&D networks leads to positive immediate impacts on regional knowledge production, and that regions with lower levels of own knowledge endowments more likely exploit the positive effects. However, the long‐term impacts of a region's embeddedness in these R&D networks are comparatively small.     

Single-molecule circuits with well-defined molecular conductance

We measure the conductance of amine-terminated molecules by breaking Au point contacts in a molecular solution at room temperature. We find that the variability of the observed conductance for the diamine molecule-Au junctions is much less than the variability for diisonitrile- and dithiol-Au junctions. This narrow distribution enables unambiguous conductance measurements of single molecules. For an alkane diamine series with 2-8 carbon atoms in the hydrocarbon chain, our results show a systematic trend in the conductance from which we extract a tunneling decay constant of 0.91 +/- 0.03 per methylene group. We hypothesize that the diamine link binds preferentially to undercoordinated Au atoms in the junction. This is supported by density functional theory-based calculations that show the amine binding to a gold adatom with sufficient angular flexibility for easy junction formation but well-defined electronic coupling of the N lone pair to the Au. Therefore, the amine linkage leads to well-defined conductance measurements of a single molecule junction in a statistical study.