A short communication on growing Jatropha in Oman

A stripping technique has been used to cencentrate selected hydrocarbons present in water samples at the parts per billion level for analysis by gas chromatography. The chromatograms of hydrocarbons thus stripped from several different water samples show similarities. Washing out of atmospheric pollutants by rainfall is postulated as an explanation of these results. This hypothesis is supported by a comparison of the data with those for trace atmospheric analysis. The comparison shows that the same compounds are present in similar relative amounts both in water samples and the atmosphere. After a period of rain the atmospheric concentrations decrease whilst the water bound concentrations increase.     

Batch adsorption of organic pollutants from oxidation pond effluents using fly ashes

The batch shaking adsorption study was conducted to determine the potential of fly and volcanic ashes in removing organic pollutants from oxidation pond effluents. Factors affecting organic pollutant removals, such as concentrations and sizes of fly and volcanic ashes, initial pond effluent organic concentrations, washed and unwashed conditions of fly and volcanic ashes, were investigated. The TOC (total organic carbon) removal efficiency varied from 30 to 58 percent. The organic removal efficiency increased with increasing ash concentrations, with decreasing initial pond effluent organic concentrations and with decreasing sizes of ashes.     

TiB2 Powders Synthesis by Borothermal Reduction in TiO2 Under Vacuum

TiB₂ powders were synthesized by borothermal reduction in nanoscale TiO₂ with boron under vacuum. Reaction processes were investigated, and the effect of by‐product B₂O₃ was evaluated. Results showed that TiO₂ was firstly reduced by boron to form TiBO₃ and Ti₂O₃, and then to produce TiB₂ and B₂O₃ with increasing temperature. The reaction processes of TiB₂ powders synthesis included two‐step reduction in TiO₂ by boron and the removal of B₂O₃. The presence of B₂O₃, which was previously reported as the most important factor in promoting the coarsening of ZrB₂ and HfB₂ powders by borothermal reduction, did not lead to significant coarsening of TiB₂ powders. Due to the minor effect of B₂O₃, TiB₂ powders with small particle size and low oxygen content could be prepared by direct heat treatment of TiO₂ and boron at 1550°C under vacuum for 1 h. The particle size and oxygen content of synthesized TiB₂ powders were ~0.9 μm and ~1.7 wt%, respectively.     

Sintering Behavior and Dielectric Properties of Ultra‐Low Temperature Fired Silver Molybdate Ceramics

Ag₂MoO₄ ceramic was prepared by using the solid‐state reaction method, which could be sintered at 450°C for 2 h, having a relative permittivity of 8.08, a Qf value of 17 000 GHz, and a temperature coefficient of resonance frequency about ?133 ppm/°C. Ag₂MoO₄ ceramic was chemically compatible with silver but reacted seriously with aluminum to form (Ag_0.5Al_0.5)MoO₄ during the sintering. The fitting of infrared spectra and the Shannon's additive rule were employed to study intrinsic dielectric behaviors of the ceramics at microwave region. Ionic displacive polarization and the electronic polarization contributed almost equally to the dielectric permittivity of the ceramic at microwave region. The Ag₂MoO₄ ceramics could be a good candidate for ultra‐low temperature co‐fired microwave devices.     

Rheology of natural fibers thermoplastic compounds: Flow length and fiber distribution

The presented study investigates the flow length and the corresponding fiber content distribution in the injection‐moulded natural fiber reinforced thermoplastics and its relation to fiber type and processing parameters such as injection pressure, temperature, injection rate and mould tempering by increasing die temperature. In this research, polypropylene compounds with nominally 30 wt % hemp and sisal fibers are investigated. The influence of the injection pressure (500 and 1000 bar), melt temperature (180°C, 200°C, and 220°C), and die temperature (23°C and 80°C) on the fiber content distribution all over the sample is investigated. An increasing linear trend of fiber content along the spiral length is observed as an evidence of a fiber/polymer multiflow system. A pattern for fiber content distribution with respect to the fiber length along the injected spiral can be distinguished, where the longer fibers are usually found at the end of the injected part and the shorter fibers remain near mould entrance point. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39861.     

Zein‐based ultrathin fibers containing ceramic nanofillers obtained by electrospinning. II. Mechanical properties,gas barrier,and sustained release capacity of biocide thymol in multilayer polylactide films

The combination of electrospinning technology and nanomaterials such as nanoclays can synergistically lead to novel materials with enhanced properties and functionalities for their usage in passive and active packaging applications. Part I of this work was focused on the development of ultrathin zein fibers containing nanoclays, which were oriented along the fiber axis and increased the thermal properties. Part II presents the use of the hybrid fibers as passive and active components in multilayer packaging structures. The hybrid fibers are incorporated in poly(lactic acid) films via a two‐step process: Electrospinning and compression molding. The composites thus produced presented improved mechanical and barrier properties than the unfilled material. The natural biocide extract thymol is then incorporated in the coating, and its sustained release properties are shown. The antimicrobial capacity of the hybrid fibers was also determined against foodborne bacteria. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40768.     

Dynamic Reductive Kinetic Resolution of Benzyl Ketones using Alcohol Dehydrogenases and Anion Exchange Resins

Dynamic reductive kinetic resolutions of racemic 3‐arylalkanones have been performed by the proper combination of an alcohol dehydrogenase and a basic anionic resin. The best results were found for the bioreduction with the alcohol dehydrogenase type A from Rhodococcus ruber DSM 44541 overexpressed in Escherichia coli (E. coli/ADH‐A) and the commercially available evo‐1.1.200, while the Amberlite IRA‐440 C and the DOWEX‐MWA‐1 resins allowed efficient in situ racemizations. Reaction conditions were optimized in terms of enzyme source and loading, type and amount of resin, pH, temperature and reaction times, obtaining a series of (R,R)‐substituted propan‐2‐ols with good conversions and both diastereoselectivity and stereoselectivity. As a proof of concept, the subsequent intramolecular cyclization of a selected propan‐2‐ol substrate afforded a valuable isochroman heterocycle without any loss of the optical purity.

     

Copper‐Catalyzed Aerobic Formation of Unstable Sulfinyl Radicals for the Synthesis of Sulfinates and Thiosulfonates

Copper‐catalyzed aerobic coupling of thiols and alcohols affords sulfinates and thiosulfonates. These products are assumed to form via sulfinyl radicals which are not commonly found in oxidative coupling reactions of thiols. A reaction mechanism involving sulfinyl radicals is proposed, and mass and electron paramagnetic resonance (EPR) experimental results are provided.