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221.
Iwona E. Gowacka Magdalena Grabkowska-Druyc Graciela Andrei Dominique Schols Robert Snoeck Karolina Witek Sabina Podlewska Jadwiga Handzlik Dorota G. Piotrowska 《International journal of molecular sciences》2021,22(15)
A novel series of N-substituted cis- and trans-3-aryl-4-(diethoxyphosphoryl)azetidin-2-ones were synthesized by the Kinugasa reaction of N-methyl- or N-benzyl-(diethyoxyphosphoryl)nitrone and selected aryl alkynes. Stereochemistry of diastereoisomeric adducts was established based on vicinal H3–H4 coupling constants in azetidin-2-one ring. All the obtained azetidin-2-ones were evaluated for the antiviral activity against a broad range of DNA and RNA viruses. Azetidin-2-one trans-11f showed moderate inhibitory activity against human coronavirus (229E) with EC50 = 45 µM. The other isomer cis-11f was active against influenza A virus H1N1 subtype (EC50 = 12 µM by visual CPE score; EC50 = 8.3 µM by TMS score; MCC > 100 µM, CC50 = 39.9 µM). Several azetidin-2-ones 10 and 11 were tested for their cytostatic activity toward nine cancerous cell lines and several of them appeared slightly active for Capan-1, Hap1 and HCT-116 cells values of IC50 in the range 14.5–97.9 µM. Compound trans-11f was identified as adjuvant of oxacillin with significant ability to enhance the efficacy of this antibiotic toward the highly resistant S. aureus strain HEMSA 5. Docking and molecular dynamics simulations showed that enantiomer (3R,4S)-11f can be responsible for the promising activity due to the potency in displacing oxacillin at β-lactamase, thus protecting the antibiotic from undesirable biotransformation. 相似文献
222.
A detailed analysis of potential versus time measurements at galvanostatic charge/discharge conditions (external current change
from −1 to +1 mA cm−2) for two La–Ni alloys in Ar-saturated 0.1 M KOH solution is presented. It is shown that passivation of the electrodes does
not affect the potential jump as a result of current switching over. The value of potential jump allows to calculate the exchange
current density for H2O/H2 system on the tested material. Anodic potential of the hydrogenated electrode (at i
a = const) linearly increases with logarithm of time which allows to evaluate precisely time necessary for oxidation of hydrogen
absorbed during cathodic charging. The method described enables to determine effectiveness of hydrogen absorption by materials
applied for negative electrodes of NiMH batteries. 相似文献
223.
Robert Darveaux Lih-Tyng Hwang Arnold Reisman Iwona Turlik 《Journal of Electronic Materials》1989,18(2):267-274
Two-dimensional finite difference computer simulations were used for thermal analysis of an advanced multi-chip package design.
In order to model high performance VLSI and ULSI applications, power dissipations ranging from 10 to 40 W/cm2 on each chip and zero to 5 W/cm2 on the substrate were simulated. It was found that heating due to resistive losses in the thin film interconnections between
chips can impact package thermal performance. The calculated device-to-water thermal resistance was 0.4° C/W and the worst
case chip-to-chip temperature variation was less than 22° C. This excellent thermal performance illustrates the effectiveness
of the package’s water cooled heat sink with direct backside contact to each die. Methods to improve thermal performance are
discussed. 相似文献
224.
The hydrogen and metal alkali forms of Y zeolite were tested in chlorination of CH2O with HCl. It has been found that over alkali metal and hydrogen forms the only chlorinated product was methyl chloride, whereas in the presence of NH4Y zeolite both methyl and methylene chlorides were formed. The conversion pathway of CH2O itself seems to play an important role in the chlorination reaction mechanism. Methanol or methoxy species and dimethoxymethane are suggested as possible intermediates in the formation of CH3Cl and CH2Cl2. 相似文献
225.
Iwona Wyżkiewicz Natalia Lewandowska Michał Chudy Zbigniew Brzózka Zbigniew Magoński Barbara Dziurdzia Małgorzata Jakubowska Artur Dybko 《Microsystem Technologies》2007,13(7):657-661
A new method for fabrication of hybrid ceramic-polymer structures with diversified geometry of microchannel was elaborated.
This method is universal, non-complicated, and utilises commercially available materials and basic equipment for thick film
technology and photolithography. A microchip for capillary electrophoresis was prepared as an example of microfluidic structure
fabrication. The chip was prepared by using a photosensitive paste (dielectric FODEL 6050) which was screen printed onto a
ceramic substrate, exposed through an appropriate mask, developed, fired and then glazed. In this way, we obtained the structure
which can be bonded with poly(dimethylsiloxane) PDMS after oxygen plasma treatment. The application of transparent PDMS as
a seal of the microchannel enabled the optical detection. 相似文献
226.
Maria Wojciechowska Iwona Tomska-Foralewska Wiesław Przystajko Michał Zieliński 《Catalysis Letters》2005,104(3-4):121-128
Catalytic properties of Cr2O3 supported on MgF2 or Al2O3 have been modified by magnesium oxide. The catalysts have been obtained by the co-impregnation method and characterised by:
BET, XRD and TPR. As follows from the results, the oxides supported on magnesium fluorine react with each other already at
400 °C, leading to formation of an amorphous spinel-like phase. On the Al2O3 support such an MgCr2O4 spinel has appeared at much higher temperatures. The addition of magnesium oxide has a significant effect on the activity
and selectivity of the catalysts studied in the CO oxidation reaction at room temperature and in the reaction of cyclohexane
dehydrogenation. The magnesium–chromium catalysts supported on MgF2 have been found to show much higher activity and selectivity than the analogous systems supported on Al2O3. 相似文献
227.
Lazar Iwona Adamczyk-Habrajska Małgorzata Pawełczyk Marian Górny Michał Zawada Anna Roleder Krystian 《Journal of Electroceramics》2019,42(1-2):87-87
Journal of Electroceramics - The original version of this article unfortunately contained a mistake. The copyright line was incorrect in the HTML version of this article. The copyright line should... 相似文献
228.
Chmiel Wojciech Skalna Iwona Jędrusik Stanisław 《Multimedia Tools and Applications》2019,78(4):4693-4721
Multimedia Tools and Applications - We investigate the problem of vehicle route planning in a dynamic environment. In order to better reflect real-life situations, we assume that travel times are... 相似文献
229.
230.
Jastrzebska M Mróz I Barwiński B Zalewska-Rejdak J Turek A Cwalina B 《Journal of materials science. Materials in medicine》2008,19(1):249-256
Pericardial tissue (bovine or porcine), chemically stabilized with glutaraldehyde (GA), is widely used in cardiovascular surgery
in the form of bioprosthetic valves. GA reacts with tissue proteins and creates inter- and intra-molecular cross-links, resulting
in improved durability. However, tissue calcification and mechanical damage are still unresolved problems. The purpose of
this study was to examine the surface topography of normal human aortic valve and GA-stabilized porcine pericardium tissue
in order to gain comparative insight into supramolecular structure of both tissues. The analysis was focused on morphologic
evaluation of collagen constituents of the tissues. Atomic force microscopy working in the contact mode in air was employed
in the study. Considerable diversity in the spatial orientation of collagen fibrils for the human aortic valve and pericardial
tissue were observed. It was found that different forms of collagen fibril packing, i.e. dense and “in phase” or loose, could
have an impact on the collagen D-banding pattern. Stabilization with GA introduced significant changes in the surface topography
of collagen fibrils and in their spatial organization on the tissue surface. Strong disturbance in the fibril’s D-spacing
was observed. It was also suggested, that the observed structural changes at the supramolecular level might make an important
contribution to the progressive damage and calcification of the tissue. The presented results demonstrate that the AFM method
can be useful for non-destructive structural characterization of heart valves and bioprosthetic heart valve material. 相似文献