Classic and novel brominated flame retardants (BFRs) in common sole (Solea solea L.) from main nursery zones along the French coasts

Brominated flame retardants (BFRs) were investigated in juvenile common sole from nursery zones situated along the French coast in 2007, 2008 and 2009. Extensive identification was performed with regard to PBDEs, novel BFRs 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) and decabromodiphenylethane (DBDPE), and other non-PBDE BFRs, namely, hexabromobenzene (HBB) and 2,2′,4,4′,5,5′-hexabromobiphenyl (BB-153). Polybrominated diphenyl ether (PBDE) concentrations (Σ 14 congeners) ranged from 0.01 ng/g to 0.16 ng/g wet weight (ww) in muscle, and 0.07 ng/g to 2.8 ng/g ww in liver. Concentrations were in the lower range of those reported in the literature in other European locations. Lower PBDE concentrations, condition indices and lipid contents were observed in the Seine estuary in 2009, possibly in relation to a lower water flow. The PBDE patterns and ratios we observed suggested that juvenile sole have a relative high metabolic degradation capacity. Non-PBDE BFRs were detected at lower levels than PBDEs, i.e., within the < method detection limit - 0.005 ng/g ww range in muscle, and < method detection limit - 0.2 ng/g ww range in liver. The data obtained is of particular interest for the future monitoring of these compounds in the environment.     

Particles and vegetation: implications for the transfer of particle-bound organic contaminants to vegetation

This paper presents a comprehensive review of the mechanisms responsible for the transfer of atmospheric particulate deposition and soil particulate re-suspension onto vegetation. The nature of atmospheric aerosols and dry/wet particulate deposition are reviewed, together with information from the literature on radionuclides as tracers of the air particle/soil particle to vegetation transfer processes. Information from these fields is used to make inferences about the potential significance of these pathways in supplying particle-bound semi-volatile organic chemicals (e.g. polycyclic aromatic hydrocarbons, polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls) to vegetation. Retention of compounds on particles brought to the above-ground plant surfaces is discussed. In the absence of definitive field/experimental studies, calculations are made drawing on the literature data to estimate the contributions of atmospheric and soil particle-bound organic contaminants to the plant concentration. These show that depending on the site-specific, species-specific and compound-specific scenarios considered, particulate-bound inputs may be negligible or may dominate the supply of organic contaminants to the above-ground portion of plants. However, field/experimental studies and direct measurements are needed to provide reliable quantitative data on this topic.     

Free vibration of a clamped-free circular cylindrical shell partially filled with liquid—Part I: Theoretical analysis

Theoretical analyses are presented for the linear free vibration of a clamped-free cylindrical shell partially filled with an incompressible, inviscid liquid. For the vibration of the shell itself, the dynamic version of the Donnell equations was used and the problem was solved with the modified Galerkin procedure, taking the effect of the axisymmetric deformation due to the static liquid pressure into consideration. Concerning the vibration relevant to the liquid motion, the solution for the velocity potential was assumed as a sum of two sets of linear combinations of the suitable harmonic function, the unknown parameters of which were imposed to satisfy both boundary conditions along the wetted shell wall and the free liquid surface in a sense of appropriate series expansions. The procedure stated in the foregoing leads to a determinantal equation for the determination of the natural frequencies of the present shell-liquid system. To compare with the experimental results which will be stated in a companion paper,¹⁴ detailed numerical results will be presented in another companion paper¹³ on the free vibration characteristics of the two test cylinders partially filled with water.     

A Microcomputer Model for Flood Prediction with Applications

Abstract: A generally applicable mathematical model, tailored for use on a Personal Computer, as the design tool to simulate unsteady flood flow in a network of interconnected rivers has been developed and applied to the Sham Chun River along the border between Hong Kong and the People's Republic of China. The effect on the improved Sham Chun River due to the proposed river training in the River Indus, one of its tributaries, is evaluated. The one-dimensional unsteady flow model itself is broadly applicable to a wide range of hydrologic conditions and varying field situations. It incorporates real hydraulic features including branched channels and 'tidal flats' flooding and drying. The time history of water stages and discharges are computed at any desired location throughout the connected essentially one-dimensional channel network subject to initial and boundary conditions. Details are given of techniques adapted in using the computational scheme to quantify the unsteady flow condition and the means to assure an efficient numerical solution as well as to verify the accuracy of the computed outputs by subjection to carefully selected schematic simplified test cases and real prototype cases with numerical solution method is a useful predictive engineering tool in river design.     

Levels of copper in the urine of women from nonpolluted farming regions of Japan.

Nearly 1500 spot urine samples were collected in the winter of 1987-1988 from women of seven farming prefectures located throughout Japan. Samples were analyzed for copper by flameless atomic absorption spectrometry. The copper content of the urine samples (Cu-U) distributed log-normally with a geometric mean (geometric standard deviation) of 36.9 (1.47) micrograms/l after adjustment for the specific gravity of urine of 1.016. The 95% confidence range was 17.1-79.7 micrograms/l. Neither alcohol consumption nor smoking habit affected the Cu-U. A literature survey showed that the observed level appears to be somewhat higher than previously reported values.     

Interaction effects of multiple pool fires

What are the effects of flame behavior of a number of fires burning in close proximity to one another? The results of measurements of burning rates, heat feedback, flame height, and flame trailing are reported for fires involving liquid pools.     

A box beam finite element for the elastic analysis of thin-walled structures

The purpose of this paper is to present a formulation of a curved thin-walled box beam finite element having a variable cross-section with at least one vertical axis of symmetry.

To allow for the effects of warping and distortion, three degrees of freedom have been included in the formulation. These degrees of freedom have been designated as the rate of change of twisting angle, the distortional angle of the cross-section, and the rate of change of distortional angle. The effect of shear lag has also been included.

The element may be used for the elastic analysis of a variety of thin-walled structures and in particular for the preliminary analysis of box bridge decks where a three-dimensional analysis may be unnecessary. The accuracy of the element has been demonstrated by comparison of the results obtained with known results from other methods for some examples.     

Fire Safety Engineering Research and Technology Centre (FireSERT) University of Ulster: Recent Developments

The Institute of Fire Safety Engineering Research and Technology Centre (FireSERT) at the University of Ulster in Northern Ireland has been a major provider of higher technical fire safety education, fire related research and services to industry for over 20 years. Its internationally recognised research spans the fields of fire dynamics, structural fire engineering, human behaviour in fire and more recently fire (CFD) modelling. Since 1991, it has offered the only PG Dip/MSc Fire Safety Engineering programme in the United Kingdom. In September 2000 FireSERT was the recipient of a £5.7 m Joint Infrastructure Fund (JIF) Award to build new fire safety engineering laboratories on the University's Jordanstown campus. These new facilities unparallel in the University sector in the UK offer greater scope and depth to the FireSERT's research portfolios. The new facilities will be extensively used in support of FireSERT's suite of MSc Fire Safety Engineering and DPhil programmes. This paper presents a brief history of FireSERT and its achievements, together with an update on the new facility, current research themes, taught programmes, research opportunities and visions for the future.     

Landscape scale vegetation-type conversion and fire hazard in the San Francisco bay area open spaces

Successional pressures resulting from fire suppression and reduced grazing have resulted in vegetation-type conversion in the open spaces surrounding the urbanized areas of the San Francisco bay area. Coverage of various vegetation types were sampled on seven sites using a chronosequence of remote images in order to measure change over time. Results suggest a significant conversion of grassland to shrubland dominated by Baccharis pilularison five of the seven sites sampled. An increase in Pseudotsuga menziesii coverage was also measured on the sites where it was present. Increases fuel and fire hazard were determined through field sampling and use of the FARSITE fire area simulator. A significant increase in biomass resulting from succession of grass-dominated to shrub-dominated communities was evident. In addition, results from the FARSITE simulations indicated significantly higher fire-line intensity, and flame length associated with shrublands over all other vegetation types sampled. These results indicate that the replacement of grass dominated with shrub-dominated landscapes has increased the probability of high intensity fires.     

A colorimetric method for ammonia in natural waters

An improved phenol-hypochlorite method for determining ammonia in water using nitroprusside as catalyst has been investigated. Unlike other recently published methods, the method is simple (and sufficiently sensitive for low-level analyses) and does not require accurate time intervals between reagents, not expensive equipment. The method is well suited for routine use.

Beer's Law was obeyed over the whole ammonia range investigated. Reproducibility was 1·3 per cent with 10 μg N, and 5·7 per cent with 1 μg N.