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91.
The fracture mechanics investigation of the polypropylene (PP)/ethylene–propylene–diene terpolymer (EPDM)/ionomer ternary blends was performed in terms of the J-integral by measuring fracture energy via the locus method. Blends were prepared in a laboratory internal mixer. The composition of PP and EPDM was fixed at a 50/50 ratio by weight. Two kinds of Poly(ethylene-co-methacrylic acid) (EMA) ionomers were used. The J-integral value at crack initiation, Jc, of the PP/EPDM/EMA ionomer ternary blends were affected by the cation types (Na+ or Zn2+) and contents (5–20 wt %) of the added EMA ionomers. The ternary blend having 5 wt % of Na-neutralized ionomer showed a higher Jc value than that of any other ternary blends. The results were discussed with regard to the fracture topology by a scanning electron microscope (SEM). © 1994 John Wiley & Sons, Inc. 相似文献
92.
We synthesized high-quality and oriented periodic mesoporous organosilica (PMO) monoliths through a solvent evaporation process using a wide range of mole ratios of the components: 0.17–0.56 1,2-bis(triethoxysilyl)ethane (BTSE): 0.2 cetyltrimethylammonium chloride (CTACl): 0–1.8 × 10−3 HCl: 0–80 EtOH: 5–400 H2O. X-ray diffraction (XRD) patterns and transmission electron microscopy (TEM) images indicated that the mesoporous channels within the monolith samples were oriented parallel to the flat external surface of the PMO monolith and possessed a hexagonal symmetry lattice (p6mm). The PMO monolith synthesized from a reactant composition of 0.35 BTSE: 0.2 CTACl: 1.8 × 10−6 HCl: 10 EtOH: 10 H2O had a pore diameter, pore volume, and surface area – obtained from an N2 sorption isotherm – of 25.0 Å, 0.96 cm3 g−1 and 1231 m2 g−1, respectively. After calcination at 280 °C for 2 h in N2 flow, the PMO monolith retained monolith-shape and mesostructure. Pore diameter and surface area of the calcined PMO monolith sample were 19.8 Å, 0.53 cm3 g−1 and 1368 m2 g−1, respectively. We performed 29Si and 13C CP MAS NMR spectroscopy experiments to confirm the presence of Si–C bonding within the framework of the PMO monoliths. We investigated the thermal stability of the PMO monoliths through thermogravimetric analysis (TGA). In addition, rare-earth ions (Eu3+, Tb3+ and Tm3+) were doped into the monoliths. Optical properties of those Eu3+, Tb3+ and Tm3+-doped PMO monoliths were investigated by photoluminescence (PL) spectra to evaluate their potential applicability as UV sensors. 相似文献
93.
Stephen H. Garofalini Ming Tai Ha Joelyn Urraca 《Journal of the American Ceramic Society》2018,101(3):1135-1148
Molecular dynamics simulations of 7 compositionally different sodium calcium alumino‐borosilicate glasses showed formation of 4B and 5Al more consistent with experimental data without compromising the other structural features that match experimental results observed in recent simulations of these glasses. Analysis of the dry surfaces of these glasses show a lack of 4B in the top 5‐6 Å of the surface in comparison to the bulk concentration for all glasses and no 5Al. Upon exposure to water, the simulations show that the 3B in the top 5‐6 Å of the glasses are preferentially attacked, decreasing the number of B bonds to O originally from the glass, indicating a change in the glass network. Inclusion of all B–O bonds in the top 5‐6 Å (i.e., including O from water) shows a decrease in 3B but an increase in 4B that is consistent with NEXAFS analysis, which the simulations show are hydroxylated. There is an increase in the concentration of 3Al in the dry surface in comparison to the bulk, but exposure to water converts almost all of these 3Al to 4Al. Hydroxyl concentrations vary from 2.6/nm2 to 4.1/nm2, with SiOH and BOH dominating these surface hydroxyls. Upon exposure to water, network linkages to B are preferentially ruptured. This, and the preferential loss of the nonbridging oxygen sites attached to Na, provide atomistic evidence of the initial stages of removal of B and Na from glass surfaces exposed to water. 相似文献
94.
Sang Bu Ha Yoon Ho Cho Yun Chan Kang Jong-Ho Lee Jong-Heun Lee 《Journal of the European Ceramic Society》2010,30(12):2593-2601
The effects of 14 different metal-oxide additives (metal = Mn, Fe, Co, Ni, Cu, B, Li, V, Zn, Si, Ca, Al, Bi, and Ba) on the sintering, phase purity, and electrical properties of strontium- and magnesium-doped lanthanum gallate (LSGM) are studied. The density, phase purity, and electrical conductivity depend closely on the sintering aids and sintering temperatures. The addition of V, Zn, Si, Co, and Fe improves the densification, phase purity, and electrical conductivity, with V showing the most promising effect on the low-temperature sintering of the phase-pure LSGM specimen with high conductivity. 相似文献
95.
96.
Processing of alumina‐coated glass‐bonded silicon carbide membranes for oily wastewater treatment 下载免费PDF全文
Su Chang Kim Hee‐Jong Yeom Young‐Wook Kim In‐Hyuck Song Jang‐Hoon Ha 《International Journal of Applied Ceramic Technology》2017,14(4):692-702
Crack‐free γ‐Al2O3‐coated glass‐bonded SiC membranes were successfully prepared using a simple heat‐treatment and dip‐coating process at a temperature as low as 850°C in air. The changes in the porosity, flexural strength, flux, and oil rejection rate of the membranes were investigated while changing the initial SiC particle size. Larger SiC particles led to bigger pores, resulting in higher flux in the oily water and a lower oil rejection rate. The SiC membranes with a support prepared from 10 μm SiC powder showed an exceptionally high oil rejection rate (99.9%) with a feed oil concentration of 600 mg/L at an applied pressure of 101 kPa. The typical porosity, flexural strength, steady state flux, and oil rejection rate of the alumina‐coated SiC membrane were ~45%, ~81 MPa, 1.78×10?5 m3 m?2s?1, and 99.9%, respectively. 相似文献
97.
Tae Hee Shin Jong-Yoon Ha Hyun-Cheol Song Seok-Jin Yoon Hyung-Ho Park Ji-Won Choi 《Ceramics International》2013,39(2):1327-1333
This paper reports on the formation of highly densified piezoelectric thick films of 0.01Pb(Mg1/2W1/2)O3–0.41Pb(Ni1/3Nb2/3)O3–0.35PbTiO3–0.23PbZrO3+0.1 wt% Y2O3+1.5 wt% ZnO (PMW–PNN–PT–PZ+YZ) on alumina substrate by the screen-printing method. To increase the packing density of powder in screen-printing paste, attrition milled nano-scale powder was mixed with ball milled micro-scale powder, while the particle size distribution was properly controlled. Furthermore, the cold isostatic pressing process was used to improve the green density of the piezoelectric thick films. As a result of these processes, the PMW–PNN–PT–PZ+YZ thick film, sintered at 890 °C for 2 h, showed enhanced piezoelectric properties such as Pr=42 μC/cm2, Ec=25 kV/cm, and d33=100 pC/N, in comparison with other reports. Such prominent piezoelectric properties of PMW–PNN–PT–PZ+YZ thick films using bi-modal particle distribution and the CIP process can be applied to functional thick films in MEMS applications such as micro actuators and sensors. 相似文献
98.
Il Kim Min Ju Yi Kyoung Ju Lee Dae-Won Park Bu Ung Kim Chang-Sik Ha 《Catalysis Today》2006,111(3-4):292-296
As means of the chemical fixation of carbon dioxide and the synthesis polycarbonates, copolymerizations of carbon dioxide with various epoxides, such as cyclohexene oxide, cyclopentene oxide and propylene oxide were investigated in the presence of double metal cyanide (DMC) catalysts. The DMC catalysts were prepared by reacting K3Co(CN)6 with ZnX2 (X = F, Cl, Br, I) together with tertiary butyl alcohol and poly(tetramethylene ether glycol) as complexing reagents and were characterized by various spectroscopic methods. The DMC catalysts showed high activity for epoxides and CO2 copolymerization to yield aliphatic polycarbonates of narrow polydispersity and moderate molecular weight. 相似文献
99.
Jong-Eun Ha 《International Journal of Control, Automation and Systems》2013,11(5):984-990
In this paper, we present a robust image processing algorithm for the automatic manipulation of tie rod in the automotive assembly process. A sensing system consisting of a camera and a slit laser is used to obtain 3D data for processing. It is attached to the robot’s arm. A nut runner is used as an end-effector of the robot to manipulate the bolt and nut on the tie rod. For the successful operation, a robust image processing algorithm that can cope with diverse illumination variations in manufacturing conditions is required. We present a robust algorithm for the extraction of laser contours on images. It consists of two steps where color and grey information is used to cope with clutters caused by laser reflections on metal surfaces. Experimental results using many images under real conditions show the robustness of the proposed algorithm. 相似文献
100.
Caleb A. Ellefson Oscar Marin-Flores Su Ha M. Grant Norton 《Journal of Materials Science》2012,47(5):2057-2071
Molybdenum dioxide (MoO2) is a transition metal oxide with unusual metal-like electrical conductivity and high catalytic activity toward reforming
hydrocarbons. This review covers the synthesis techniques used to fabricate MoO2 in a variety of morphologies and particle sizes. Processing from molybdenum ore and reduction from MoO3 are also covered, with emphasis on reduction mechanisms and kinetic considerations. Discussions of various solution-based
and gas phase synthesis techniques shed light on strategies to achieve various unique morphologies, which leads into a brief
discussion of nanoscale MoO2. Nanoscale MoO2 is of interest for important technological applications including catalysts for partial oxidation of hydrocarbons, solid
oxide fuel cell anodes, and high-capacity reversible lithium ion battery anodes. 相似文献