SUTIL – Network selection based on utility function and integer linear programming

This work presents SUTIL, a mechanism for network selection in the context of next generation networks (NGN). SUTIL selection mechanism prioritizes networks with higher relevance to the application and lower energy consumption and it enables full and seamless connectivity to mobile user devices and applications. Consequently, SUTIL contributes to realize the vision of ubiquitous computing, in which services, devices, and sensor-enriched environments interact anytime, anywhere to accomplish human designed tasks. The provided solution is based on utility function and integer linear programming and it aims at: (i) maximizing the user satisfaction while meeting application QoS and (ii) minimizing the energy consumption of devices when connecting to a target network. The solution is global since it considers for a given base station all devices that are simultaneously candidate for handoff. Simulation results showed the benefits of SUTIL usage in NGN environments.     

“Click” Synthesis of a Heterobifunctional Ferrocenyl Dendrimer with Molecular Recognition Properties and Influence of the Ferrocenyl Redox Potential on the Formation of Gold Nanoparticles

Alkyne protection by complexation of ethynylferrocene with dicobalt octacarbonyl followed by regioselective acetylation, then deprotection and “click” reaction with a nona-azido-terminated arene-cored dendrimer leads to the heterodifunctional nona(1,2,3-triazolyl-acetylferrocenyl) dendrimer. Cyclic voltammetry of this metallodendrimer shows recognition of both ATP^2? and Pd²⁺. HAuCl₄ is reduced much more slowly to gold nanoparticles by the nona(triazolyl-acetylferrocenyl dendrimer than by the nona(triazolylferrocenyl) dendrimer due to the shift of redox potential in the new heterodifunctional dendrimer compared to that of the parent ferrocenyl dendrimer.     

A novel pectin material: extraction, characterization and gelling properties

A novel pectin was acid extracted from chickpea husk (CHP). CHP presented a 67% (w/w) of galacturonic acid, an intrinsic viscosity of 374 mL/g and a viscosimetric molecular weight of 110 kDa. Fourier transform infrared spectroscopy spectrum of CHP indicated a degree of esterification of about 10%. The CHP-calcium system formed ionic gels with a storage (G') modulus of 40 Pa and gel set time (G' > G″) of 3 min at 1% (w/v), and a G' of 131 Pa and gel set time of 1 min at 2% (w/v). The G' of CHP gels was not greatly affected by temperature. The results attained suggest that chickpea husk can be a potential source of a gelling pectin material.     

Atomization and combustion of canola methyl ester biofuel spray

The spray atomization and combustion characteristics of canola methyl ester (CME) biofuel are compared to those of petroleum based No. 2 diesel fuel in this paper. The spray flame was contained in an optically accessible combustor which was operated at atmospheric pressure with a co-flow of heated air. Fuel was delivered through a swirl-type air-blast atomizer with an injector orifice diameter of 300 μm. A two-component phase Doppler particle analyzer was used to measure the spray droplet size, axial velocity, and radial velocity distributions. Radial and axial distributions of NO, CO, CO₂ and O₂ concentrations were also obtained. Axial and radial distributions of flame temperature were recorded with a Pt–Pt/13%Rh (type R) thermocouple. The volumetric flow rates of fuel, atomization air and co-flow air were kept constant for both fuels. The droplet Sauter mean diameter (SMD) at the nozzle exit for CME biofuel spray was smaller than that of the No. 2 diesel fuel spray, implying faster vaporization rates for the former. The flame temperature decreased more rapidly for the CME biofuel spray flame than for the No. 2 diesel fuel spray flame in both axial and radial directions. CME biofuel spray flames produced lower in-flame NO and CO peak concentrations than No. 2 diesel fuel spray flames.     

Thermal degradation of high‐temperature fluorinated polyimide and its carbon fiber composite

High‐temperature polymers are being used for a broad range of applications, such as composite matrices for structural applications (e.g., high speed aircraft). Polyimides are a special class of polymers that meet the thermal and oxidative stability requirements for high temperature composite aerospace applications. A weight loss study was performed on a fluorinated polyimide resin and its carbon fiber composite in an effort to determine its thermal stability and degradation mechanisms. Experiments were conducted using a preheated oven and thermogravimetric analysis to obtain the weight loss. Regardless of the method used, the resin and composite exhibited excellent thermal stability (less than 1% weight loss) below 430°C, regardless of 2–20 min of exposure. After 20 min of exposure at 510°C, the composite remained relatively stable with only 5.3% weight loss using the oven technique, whereas the neat polyimide sustained 12.6%. When degradation occurred, it was found to be the result of thermolysis and oxidation (to a lesser extent). © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Evolution of damage in AA-5083 processed by equal channel angular extrusion using different die geometries

In this study, the influence of the die geometry on the introduced damage of the processed parts by ECAE is studied. It will be shown experimentally and by FEM simulations that the die geometry greatly influences the imparted damage, if the die geometry is not selected adequately. This could lead to obtain processed materials which could be useless for posterior mechanical applications because of cracks nucleated inside of them, which will decrease the mechanical properties such as fatigue resistance and formability among others.Several FEM models have been solved in order to obtain a mathematical model to predict the influence of the die geometry.Moreover, several parts have been processed using different die geometries in order to determine the damage within the processed material experimentally and also to validate FEM simulations. A 5083 aluminium alloy in (O) state, which means that has been fully annealed, has been selected and different die geometries have been manufactured for processing this aluminium alloy.     

A simple approach to solving the kinematics of the 4-UPS/PS (3R1T) parallel manipulator

Journal of Mechanical Science and Technology - This work reports on the position, velocity and acceleration analyses of a four-degrees-of-freedom parallel manipulator, 4-DoF-PM for brevity, which...     

Evaluation of the column components size on the vapour enrichment and system performance in small power NH3–H2O absorption refrigeration machines

This paper presents an analysis of the influence of the distillation column components size on the vapour enrichment and system performance in small power NH₃–H₂O absorption machines with partial condensation. It is known that ammonia enrichment is required in this type of systems; otherwise water accumulates in the evaporator and strongly deteriorates the system performance and efficiency. The distillation column analysed consists of a stripping adiabatic section below the column feed point and an adiabatic rectifying packed section over it. The partial condensation of the vapour is produced at the top of the column by means of a heat integrated rectifier with the strong solution as coolant and a water cooled rectifier. Differential mathematical models based on mass and energy balances and heat and mass transfer equations have been developed for each one of the column sections and rectifiers, which allow defining their real dimensions. Results are shown for a given practical application. Specific geometric dimensions of the column components are considered. Different distillation column configurations are analysed by selecting and discarding the use of the possible components of the column and by changing their dimensions. The analysis and comparison of the different column arrangements has been based on the system COP and on the column dimensions.     

Influence of single wall carbon nanotubes and thermal treatment on the morphology of polymer thin films

Homogeneous and stable thin films of poly(butylene terephthalate) PBT and its nanocomposites based on single wall carbon nanotubes (SWCNTs) were prepared by spin coating. PBT thin films show crystalline structures for thicknesses above 40 nm, consisting of submicrometer size 2D-spherulites. In the case of nanocomposites, carbon nanotubes act as nucleating agents and provide a template for the crystallization of PBT. This gives rise to hybrid shish-kebab structures, even in the thinnest films (∼10 nm thick). Melting and recrystallization provoke the crystallization of PBT and its nanocomposites, and can be used to control morphology. For PBT thin films, the orientation of crystalline lamellae undergoes a transformation, changing from a disposition perpendicular to the substrate (“edge-on”) to a parallel arrangement (“flat-on”) after recrystallization. In the case of the nanocomposites, the CNT influence on the polymer crystallization morphology in thin films is less significant than in the bulk due to the effect of the substrate interactions. Using Raman microscopy it is possible to directly observe both, the degree of dispersion and the location of carbon nanotubes in the films. The results reveal that bigger agglomerates act as more effective nucleating points than isolated bundles of SWCNTs during crystallization of the polymer matrix.     

Correlation lengths, porosity and water adsorption in TiO₂ thin films prepared by glancing angle deposition

This paper reports a thorough microstructural characterization of glancing angle deposited (GLAD) TiO(2) thin films. Atomic force microscopy (afm), grazing-incidence small-angle x-ray scattering (GISAXS) and water adsorption isotherms have been used to determine the evolution of porosity and the existence of some correlation distances between the nanocolumns constituting the basic elements of the film's nanostructure. It is found that the deposition angle and, to a lesser extent, the film thickness are the most important parameters controlling properties of the thin film. The importance of porosity and some critical dimensions encountered in the investigated GLAD thin films is highlighted in relation to the analysis of their optical properties when utilized as antireflective coatings or as hosts and templates for the development of new composite materials.