Tc(VII) Sorption by Fibrous Sorbents

It is shown that technetium can be extracted from acidic media by the fibrous complexing sorbent POLIORGS 35, containing hydrazidine groups, and from neutral and nitric-acid solutions with a complex salt composition (with nitrate-ion concentration not exceeding 10 g/liter) by strongly basic anionite POLIORGS AV-17 with quaternary ammonium bases. The effect of the pH of the solutions on the sorption of technetium is studied. It is shown that the sorption depends on the nature and concentration of the salt background of the solutions. The kinetics and mechanism of sorption of technetium by fibrous sorbents and the possibility of their desorption and reuse in sorption–desorption cycles are investigated. It is shown that the fibrous sorbents POLIORGS 35 and POLIORGDS AV-17 are promising for extracting technetium from waters with a high mineral content (up to 20 g/liter).     

Inhibitory Effect of some carbazides on corrosion of aluminium in hydrochloric acid and sodium hydroxide solutions

The dissolution of aluminium in hydrochloric acid and sodium hydroxide solutions in the presence of semicarbazide, thiosemicarbazide and sym.diphenylcarbazide as corrosion inhibitors has been studied using thermometric, weight-loss and polarization methods. The three methods gave consistent results. The higher inhibition efficiency of these compounds in acidic than in alkaline madia may be due to the less negative potential of aluminium in hydrochloric acid solution, favouring adsorption of the additive. The adsorption of these compounds were found to obey Frumkin adsorption isotherm. Cathodic polarization measurements showed that these compounds are cathodic inhibitors and their adsorption in the double layer does not change the mechanism of the hydrogen evolution reaction. The results are analysed in terms of both molecular and cationic adsorption.     

Comparative Assessment of the Effect of Chemical and Radiation Factors on Workers and the General Public Resulting from the Salvaging of Nuclear-Powered Submarines

The results of observations performed over many years are used to make an assessment of the degree to which the concentration of chemical and radioactive substances escaping into the environment during salvaging of nuclear-powered submarines exceeds the admissable norms for workers at the main ship-repair facilities in Russia and for the general public in the surrounding territories. It is shown that the chemical substances are a determining factor in environmental contamination. Their content in the atmosphere and sea water exceeds the admissable norms near sources, on the territory of the enterprises, and (for individual indicators) at populated points. Under these conditions, the concentration of technogenic radionuclides does not exceed the admissable norms and its damaging effect on man is hundreds and thousands of times less than that of chemicals.     

89-GHz fT room-temperature silicon MOSFETs

The authors report the implementation of deep-submicrometer Si MOSFETs that at room temperature have a unity-current-gain cutoff frequency (f_T) of 89 GHz, for a drain-to-source bias of 1.5 V, a gate-to-source bias of 1 V, a gate oxide thickness of 40 Å, and a channel length of 0.15 μm. The fabrication procedure is mostly conventional, except for the e-beam defined gates. The speed performance is achieved through an intrinsic transit time of only 1.8 ps across the active device region     

A subunit interaction in chloroplast ATP synthase determined by genetic complementation between chloroplast and bacterial ATP synthase genes

F1F0-ATP synthases utilize protein conformational changes induced by a transmembrane proton gradient to synthesize ATP. The allosteric cooperativity of these multisubunit enzymes presumably requires numerous protein-protein interactions within the enzyme complex. To correlate known in vitro changes in subunit structure with in vivo allosteric interactions, we introduced the beta subunit of spinach chloroplast coupling factor 1 ATP into a bacterial F1 ATP synthase. A cloned atpB gene, encoding the complete chloroplast beta subunit, complemented a chromosomal deletion of the cognate uncD gene in Escherichia coli and was incorporated into a functional hybrid F1 ATP synthase. The cysteine residue at position 63 in chloroplast beta is known to be located at the interface between alpha and beta subunits and to be conformationally coupled, in vitro, to the nucleotide binding site > 40 A away. Enlarging the side chain of chloroplast coupling factor 1 beta residue 63 from Cys to Trp blocked ATP synthesis in vivo without significantly impairing ATPase activity or ADP binding in vitro. The in vivo coupling of nucleotide binding at catalytic sites to transmembrane proton movement may thus involve an interaction, via conformational changes, between the amino-terminal domains of the alpha and beta subunits.     

"Aging and forgetting in prospective and retrospective memory tasks": Correction.

Reports an error in the original article by E. A. Maylor (Psychology and Aging, 1993[Sep], Vol 8[3], 420–428). There is an error in the picture recognition data. This was one of the tasks administered in an earlier group testing session (see page 421). The number of false positives for an older S was incorrectly entered onto the data sheet as 31 instead of only 13. (The following abstract of this article originally appeared in record 1994-01191-001.) Ss (aged 52–83 yrs) named 30 famous people 4 times over the course of an hour and responded to 2 targets (a beard and a pipe) by marking the trial number on the response sheet. Initial performance in the prospective memory task was related only to a measure of incidental learning. Subsequent forgetting (i.e., success followed by failure) occurred more often for older Ss than for younger Ss, but there was no difference between the age groups in recovery (i.e., failure followed by success). Forgetting was predicted by age, even after a composite measure of general ability was included in the regression. Recovery was related to general ability alone. Results both replicate and extend those from a reanalysis of a previous study (E. A. Maylor, 1990). They provide a striking contrast with the effect of age on retrospective memory.… (PsycINFO Database Record (c) 2010 APA, all rights reserved)