Zn-Ca-Fe氧化物催化水解微晶纤维素

以尿素为沉淀剂制备了一系列复合金属沉淀物,将其在高温条件下煅烧获得一系列复合金属氧化物固体催化剂,并将其用于催化微晶纤维素的水解反应;考察了反应温度、反应时间、搅拌转速、催化剂用量和微晶纤维素用量对反应的影响。实验结果表明,在反应温度160℃、反应时间20 h、搅拌转速400 r/mnin、微晶纤维素2.0 g、Zn-Ca-Fe氧化物0.9 g和H_2O 200 mL的条件下,微晶纤维素的转化率高达42.56%,葡萄糖的收率为69.20%,且微晶纤维素水解液为中性溶液。在相同反应条件下,Zn-Ca-Fe氧化物可重复使用5次,其催化活性无明显降低。     

River, reservoir and lake sediment contamination by heavy metals downstream from urban areas of Switzerland

This paper quantifies sediment contamination by heavy metals in four reservoirs and one lake located downstream from major urban areas in Switzerland. The waterbodies include the Wettingen Reservoir (located on the Limmat River downstream from Zürich), the Klingnau Reservoir (on the lower Aare River), the Wohlen Reservoir (downstream from Berne), the Verbois Reservoir (downstream from Geneva) and Vidy Bay (Lake Geneva, city of Lausanne). For all sediment cores and contaminants, a trend is observed from high contaminant values in the lower part of the cores, decreasing to lower concentrations in the upper part of the cores. However, for each site and each element, specific features are recognized. Applying the criteria of the Swiss ordinance on soil protection, all sediment cores must be classified as contaminated by one or more contaminants and at variable levels. From these data, it is concluded that: reservoirs and lakes located downstream from major urban centres in Switzerland have accumulated significant volumes of contaminated sediments in the past, representing the largest, but not the most intensely, contaminated sites on a national scale; the main environmental risk is remobilization of the contaminants and their return to the food chain, particularly by infiltration into the groundwater; and although the processes of remobilization are identified, the conditions of occurrence and the amplitude of the processes are still poorly known. Different options of reservoir and lake sediment management also are discussed and further research topics defined.     

Application of the SIMS Method in Studies of Cr Segregation in Cr-Doped CoO: I, Aspects of Quantitative Analysis

Aspects of calibration of intensities of SIMS secondary ions vs concentration as well as sputtering time vs depth are considered for Cr-doped CoO. Advantages and limitations of the SIMS method in quantitative analysis of segregation-induced concentration profiles in oxide crystals are discussed. The studies indicate a substantial effect due to charging the surface during sputtering. The depth calibration was performed by using the Ta₂O₅/Ta system as a standard. Good depth resolution was revealed. The calibration dependence of Cr intensities on concentration is characterized by a wide scatter of data caused by charging the surface. Very good shape reproducibility of the intensity ratio vs depth profiles was revealed. Therefore, normalized intensity ratios can be used for calibration.     

“Softer” optimization and control models via fuzzy linguistic quantifiers

A “softening” of a basic formulation of multicriterion optimization and control (multistage decision making) is presented. For optimization, instead of seeking an optimal solution that best satisfies all the fuzzy objectives as has been done so far, we seek an optimal solution that best satisfies most, much more than 50%, etc. (a linguistic quantifier, in general) of the fuzzy objectives. For control, we seek in turn an optimal sequence of controls that best satisfies the fuzzy constraints and fuzzy goals at most, much more than 50%, etc. of the control stages. A calculus of linguistically quantified statements based upon fuzzy sets and possibility theory is used. Some applications to softer evidence aggregation in expert systems are also indicated.     

A new method of determination of the permeability of vapors of volatile liquid substances through polymer membranes

A new apparatus for the determination of vapor permeability of volatile liquid substances through polymer membranes has been described. The permeability of the vapor is calculated from the measurements of the depression rate of the liquid meniscus in a calibrated capillary tube. The conditions of the measurements by means of the described method are very close to those of the average and practical application of foils. The method is characterized by a simple design of the apparatus, easy handling, and simplicity of the determinations, so it may constitute the basis of vapor permeability determination standards. The results obtained by means of the described method were compared with those derived from the partition cell method.     

Dilatometric studies of the phase transitions of sodium potassium tartrate tetrahydrate (RS)

Temperature dependence of the thermal expansion coefficients of Rochelle salt (RS) crystals for the basic crystallographic directions have been measured in the temperature range from 100 K to 308 K by an air-capacitor dilatometer. Anomalies of thermal expansion coefficients at about 210 K and 153 K have been observed, besides these corresponding to known ferroelectric phase transitions at the temperatures of 255 and 297 K.     

Kalman filtering of traffic fluctuations for real-time network management

Discrete- time stochastic models of sequential traffic records in telephone networks are considered. They appear to be well suited for a use of the Kaiman filter. A version of the filtering algorithm is adopted to deal with traffic fluctuations. The overall approach is tested against the real data gathered by the supervisor of the French toll network. The adaptive traffic estimator is inserted into a simulator of a testbed network operated in the urban zone of Paris. The traffic estimations provided by the filter are used to decide an overflow hierarchy.     

General Probability of System Failure

This paper presents a general method to determine probabilities of failure of any fixed subset of coherent system components under various conditions. The method uses a known reliability structure of the system and the known joint probability distribution of its component times-to-failure. This method is universal and can be applied in many cases. Nevertheless, for large systems it is troublesome. In practice a problem is solved using a numerical program.     

Teaching Multibody Dynamics at Warsaw University of Technology

The paper concerns the usage of the method of multibody systems (MBS) in teaching students at the Warsaw University of Technology. Research results from the MBS discipline are being used in several ways. Large-scale computer software is being used to illustrate lecture material, some MBS research results are included in lecture topics and independent courses are taught, based directly on MBS research. During senior courses, advanced software is also used as a computational tool as well as an integral part of Virtual Prototyping. The paper presents also several examples of student projects created with MBS.