A Reaction of Thioamides with Zinc Ammoniates Leading to Simple Amidines. Discovery of a New Zwitterionic Monomethylamidine

The reacion of thioamides with the R₁R₂N–ZnCl ammoniates leads to N-mono-, N,N′-di-, N,N-disubstituted, and unsubstituted amidines with high concentrations of amines in absolute ethanol. The efficient direct formation of the N,N′-dimethylamidine can be explained by a greater reactivity of methylamine compared with dimethylamine. Discovery of a new zwitterion (induced by a carbonyl oxygen) suggests that the stabilization in the thymine N-methylamidine is too slight to prevent the subsequent reaction with methylamine.     

Off-design analysis of SOFC hybrid system

This paper sets out the results of mathematical modeling and numerical simulations of the off-design (part-load) operation of the solid oxide fuel cell hybrid system (SOFC-HS).     

CERCLA landfill closures: Construction considerations

A properly functioning cover over an uncontrolled landfill which is regulated under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) depends on both a well-engineered cover design and prudent construction practices.

This paper focuses on several geosynthetic construction issues which ultimately impact the performance of the final constructed cover. Preparation and placement issues related to subgrade preparation, geosynthetic placement, cover soil placement and test sections are presented. Storage and seaming of the geosynthetics are discussed. Construction quality control and quality assurance programs are emphasized. In addition, relevant design issues pertaining to settlements, interface friction, and rigid-nonrigid connections are discussed.

Although these issues apply to all landfills, this paper is based on experience gained from design, review and construction oversight of CERCLA landfill covers by the US Army Corps of Engineers.     

Fabrication and electrical properties of laser-shaped thick-film and LTCC microresistors

The dimensions of discrete passives, passive integrated components (arrays, networks) and embedded integral ones should be reduced significantly in the nearest future. Therefore the relations between technological accuracy and limitations, minimal geometrical dimensions and electrical as well as stability properties become more and more important. This paper presents systematic studies of thick-film or LTCC microresistors made with the aid of laser shaping. The investigations are concerned with miniaturization of two resistor dimensions, namely length (down to 30 μm) and width (also down to 30 μm). The sheet resistance, hot temperature coefficient of resistance (HTCR) as well as long-term stability and durability of test structures to various short electrical pulses were related to geometrical properties of microresistors. Such investigations proved that combining of current materials and fabrication methods used in modern thick-film and LTCC technologies with laser shaping made possible fabrication of 30 × 30 μm² microresistors with satisfactory electrical properties and can serve as interesting alternative for thick-film and LTCC resistors miniaturization.