Surface Protection and Morphological Study of Copper by Green Corrosion Inhibitor: 8QSC in HNO<Subscript>3</Subscript> Medium

The inhibition performance and surface protection of green corrosion inhibitor 8-quinoline sulphonyl chloride (8QSC) on copper (Cu) was evaluated by chemical (weight loss) method in 0.5, 1.0 and 2.0 M HNO₃ solutions and by electrochemical methods such as potentiodynamic polarization (PDP), AC-impedance spectroscopy (AC-IS) and linear polarization resistance in 1.0 M HNO₃ solution at room temperature. Both chemical and electrochemical techniques showed that 8QSC is an efficient green corrosion inhibitor for copper and the efficiency reached 90.4% by weight loss method and 88.4% by AC-IS method at optimum concentration of (300 ppm) 8QSC. The adsorption behavior of 8QSC on copper metal in acid medium obeyed the Langmuir isotherm. The thermodynamic parameters of the adsorption processes were calculated and discussed. AC-IS technique exhibits one capacitive loop, indicating that the corrosion reaction was controlled by charge transfer process. The PDP curves revealed that 8QSC acts as a mixed-type inhibitor. Protective layer of 8QSC on copper surface was examined by SEM, AFM and FT-IR techniques. The experimental results corroborated with results obtained from theoretical DFT studies.     

MODELING OF HYDROPROCESSING REACTIONS

Langmuir-Hinshelwood-Hougen-Watson rate expressions are developed for the hydroprocessing of quinoline, naphthalene and dibenzothiophene based on batch reactor data at 350^°C and at 500 psig. Based on competitive adsorption, the kinetics are extended to binary mixtures of quinoline/naphtha-lene and quinoline/dibenzothiophene. In doing so, the differences in hydrogenation and hydro-genolysis sites are taken into consideration. In all cases, the agreement between the predicted and experimental results are good     

Compressive mechanical properties of sawdust/high density polyethylene composites under various strain rate loadings

This article is concerned with the static and dynamic mechanical properties of high‐density polyethylene (HDPE) reinforced with sawdust (SD) at a strain rate of up to 10³ s^?1. In this study, the static and dynamic properties of HDPE/SD composites with different filler loadings of 5, 10, 15, 20, and 30 wt% SD were deliberated at different levels of strain rates (0.001, 0.01, 0.1, 650, 900, and 1100 s^?1) using a conventional universal testing machine and the split Hopkinson pressure bar apparatus. The results showed that the stress–strain curves, yield behavior, stiffness, and strength properties of the HDPE/SD composites were strongly affected by both the strain rate and the filler loadings. Furthermore, the rate sensitivityof the HDPE/SD composites showed a great dependency on the applied strain rate, increasing as the strain rate increased. However, the thermal activation values showed a contrary trend. Meanwhile, for the postdamage analysis, the results showed that the applied strain rates influenced the deformation behavior of the tested HDPE/SD composites. Moreover, for the fractographic analysis at dynamic loading, the composites showed that all the specimens underwent a severe catastrophic deformation. J. VINYL ADDIT. TECHNOL., 24:162–173, 2018. © 2016 Society of Plastics Engineers     

On-Line Learning Failure-Tolerant Neural-Aided Controller for Earthquake Excited Structures

This paper presents an on-line learning failure-tolerant neural controller capable of controlling buildings subjected to severe earthquake ground motions. In the proposed scheme the neural controller aids a conventional H∞ controller designed to reduce the response of buildings under earthquake excitations. The conventional H∞ controller is designed to reduce the structural responses for a suite of severe earthquake excitations using specially designed frequency domain weighting filters. The neural controller uses a sequential learning radial basis function neural network architecture called extended minimal resource allocating network. The parameters of the neural network are adapted on-line with no off-line training. The performance of the proposed neural-aided controller is illustrated using simulation studies for a two degree of freedom structure equipped with one actuator on each floor. Results are presented for the cases of no failure and failure of the actuator on each of the two floors under several earthquake excitations. The study indicates that the performance of the proposed neural-aided controller is superior to that of the H∞ controller under no actuator failure conditions. In the presence of actuator failures, the performance of the primary H∞ controller degrades considerably, since actuator failures have not been considered for the design. Under these circumstances, the neural-aided controller is capable of controlling the acceleration and displacement structural responses. In many cases, using the neural-aided controller, the response magnitudes under failure conditions are comparable to the performance of the H∞ controller under no-failure conditions.     

Experimental studies on the thermal performance of a parabolic dish solar receiver with the heat transfer fluids SiC + water nano fluid and water

An experimental investigation has been carried out with aa point focusing dish reflector of 12 square meters aperture area,exposed to the average direct normal irradiations of 810 W/m2.This work focuses on enhancinge the energy and exergy efficiencies of the cavity receiver by minimizing the temperature difference between the wall and heat transfer fluids.Two heat transfer fluids Water and SiC + water nano fluid have been prepared from 50 nm particle size and 1％ of volume fraction,and experimented separately for the flow rates of 0.2 lpm to 0.6 lpm with an interval of 0.1 lpm.The enhanced thermal conductivity of nano fluid is 0.800115 W/mK with the keff/kb ratio of 1.1759 determined by using the Koo and Kleinstreuer correlation.The maximum attained energy and exergy efficiencies are 29.14％ and 24.82％ for water,and 32.91％ and 39.83％ for SiC+water nano fluid.The nano fluid exhibits enhanced energy and exergy efficiency of 12.94％ and 60.48％ than that of water at the flow rate of 0.5 lpm.The result shows that the system with SiC+Water produces higher exergy efficiency as compared to energy efficiency;in the case ofwater alone,the energy efficiency is higher than exergy efficiency.     

Phytosterols in Seaweeds: An Overview on Biosynthesis to Biomedical Applications

Seaweed extracts are considered effective therapeutic alternatives to synthetic anticancer, antioxidant, and antimicrobial agents, owing to their availability, low cost, greater efficacy, eco-friendliness, and non-toxic nature. Since the bioactive constituents of seaweed, in particular, phytosterols, possess plenty of medicinal benefits over other conventional pharmaceutical agents, they have been extensively evaluated for many years. Fortunately, recent advances in phytosterol-based research have begun to unravel the evidence concerning these important processes and to endow the field with the understanding and identification of the potential contributions of seaweed-steroidal molecules that can be used as chemotherapeutic drugs. Despite the myriad of research interests in phytosterols, there is an immense need to fill the void with an up-to-date literature survey elucidating their biosynthesis, pharmacological effects, and other biomedical applications. Hence, in the present review, we summarize studies dealing with several types of seaweed to provide a comprehensive overview of the structural determination of several phytosterol molecules, their properties, biosynthetic pathways, and mechanisms of action, along with their health benefits, which could significantly contribute to the development of novel drugs and functional foods.     

Surface protection of mild steel in acidic chloride solution by 5-Nitro-8-Hydroxy Quinoline

The effect of commercially available quinoline nucleus based pharmaceutically active compound 5-Nitro-8-Hydroxy Quinoline (NHQ) against the corrosion of mild steel (MS) in 1 M acidic chloride (HCl) solution was investigated by chemical (weight loss – WL) and electrochemical (Tafel polarization, Linear polarization and Electrochemical impedance spectroscopy) techniques. From all the four methods, it is inferred that the percentage of inhibition efficiency increases with increasing the inhibitor concentration from 50 to 300 ppm. The adsorption behavior of inhibitor obeyed through Langmuir isotherm model. Thermodynamic parameters were also calculated and predict that the process of inhibition is a spontaneous reaction. EIS technique exhibits one capacitive loop indicating that, the corrosion reaction is controlled by charge transfer process. Tafel polarization studies revealed that the investigated inhibitor is mixed type and the mode of adsorption is physical in nature. The surface morphologies were examined by FT-IR, SEM and EDX techniques. Theoretical quantum chemical calculations were performed to confirm the ability of NHQ to adsorb onto mild steel surface.     

Wind energy status in India: A short review

Renewable energy represents an area of tremendous opportunity for India. Energy is considered a prime agent in the generation of wealth and a significant factor in economic development. Energy is also essential for improving the quality of life. Development of conventional forms of energy for meeting the growing energy needs of society at a reasonable cost is the responsibility of the Government. Limited fossil resources and associated environmental problems have emphasized the need for new sustainable energy supply options. India depends heavily on coal and oil for meeting its energy demand which contributes to smog, acid rain and greenhouse gases’ emission. Last 25 years has been a period of intense activities related to research, development, production and distribution of energy in India.Though major energy sources for electrical power are coal and natural gas, development and promotion of non-conventional sources of energy such as solar, wind and bio-energy, are also getting sustained attention. The use of electricity has grown since it can be used in variety of applications as well as it can be easily transmitted, the uses of renewable energy like wind and solar is rising. Wind energy is a clean, eco-friendly, renewable resource and is nonpolluting. The gross wind power potential is estimated at around 48,561 MW in the country; a capacity of 14,989.89 MW up to 31st August 2011 has so far been added through wind, which places India in the fifth position globally. This paper discusses the ways in which India has already supported the growth of renewable energy technologies i.e. wind energy and its potential to expand their contribution to world growth in a way that is consistent with world's developmental and environmental goals. The paper presents current status, major achievements and future aspects of wind energy in India.     

Characteristics of Cast Stone cementitious waste form for immobilization of secondary wastes from vitrification process

The high-temperature in vitrification process of radioactive wastes could cause radioactive technetium (⁹⁹Tc) in secondary liquid wastes to become volatile. Solidified cementitious waste forms at low temperature were developed to immobilize radioactive secondary waste. This research focuses on the characterization of a cementitious waste form called Cast Stone. Properties including compressive strength, surface area, phase composition, and technetium leaching were measured. The results indicate that technetium diffusivity is affected by simulant type. Additionally, ettringite and AFm (Al₂O₃–Fe₂O₃–mono) main crystalline phases were formed during hydration. The Cast Stone waste form passed the qualification requirements for a secondary waste form, which are compressive strength of 3.45 MPa and technetium diffusivity of 10^?9 cm²/s. Cast Stone was found to be a good candidate for immobilizing secondary waste streams.