建立预算资金行业财务管理中心的探索

会计集中核算制度是财政体制改革的一项重要举措,它对改变现行财政资金分散收付方式发挥了很大的作用.应在会计集中核算的基础上建立行业财务管理中心,并作为会计集中核算改革的进一步深入和补充.探讨了建立行业财务管理中心的重要性和必要性以及行业财务管理中心的模式,并在行业财务管理中心引入融资理念.     

Novel Hyperbranched predominantly Alternating Copolymers Made From A Charge Transfer Complex monomer pair of p-(chloromethyl)styrene and Acrylonitrile via Controlled Living Radical Copolymerization

Summary Novel hyperbranched copolymers were successfully synthesized by the controlled charge transfer complex inimer and living radical copolymerization of p-(chloromethyl)styrene (PCMS) and acrylonitrile (AN). The resulting copolymers were characterized by SEC, NMR, FTIR, DSC and elemental analysis etc.. The influences of reaction conditions, such as the polymerization temperature, the catalyst (CuBr) concentration and the monomer ratio, on the resulting copolymers were investigated in detail. The monomer reactivity ratios were evaluated to be r_PCMS=0.937 and r_AN=0.088 respectively by the Fineman-Ross method. The higher are the polymerization temperature and the ratio of catalyst to monomer, the higher is the branching degree of the resulting copolymer. When the amount of monomer AN was used in excess than that of the monomer PCMS in the raw feed, the hyperbranched predominantly alternating copolymers HP[PCMS-co-AN] could be obtained. These hyperbranched copolymers were successfully used as functional macroinitiators to synthesize the star-shaped poly(PCMS-co-AN)/poly(MMA) block copolymers.     

Adaptive weighted outer-product learning associative memory

Associative-memory neural networks with adaptive weighted outer-product learning are proposed in this paper. For the correct recall of a fundamental memory (FM), a corresponding learning weight is attached and a parameter called signal-to-noise-ratio-gain (SNRG) is devised. The sufficient conditions for the learning weights and the SNRG's are derived. It is found both empirically and theoretically that the SNRG's have their own threshold values for correct recalls of the corresponding FM's. Based on the gradient-descent approach, several algorithms are constructed to adaptively find the optimal learning weights with reference to global- or local-error measure.     

应用图论及广义简约梯度法进行压力管网优化设计

广义简约梯度法(GRG)是非线性规划算法中最有效的算法之一，本文把图论应用于广义简约梯度法优化的过程中，使输入简便，计算简化，应用GRG算法对武汉市的汉阳管网进行了模拟优化设计，并对管段的计算管径用线性规划法进行标准化，取得了满意的结果     

Voigt线型及其精确快速算法

通过把上半复平面分为４个区，并在每一区利用不同近似，建立了一种精确快速计算Ｖｏｉｇｔ函数、修正的Ｖｏｉｇｔ函数和Ｖｏｉｇｔ函数偏导数的算法，其最大相对误差小于５×１０－４．该算法是Ｌｉｎｅ－ｂｙ－Ｌｉｎｅ大气透过率／辐射强度计算及其相关应用的有效算法．     

ICA结构进化和未来网

ICA是一种含有中间件的网络软件体系结构,旨在以结构进化取得功能突破,据以全面支持来自用户的以及来自系统的各种应用需要。ICA的出台,表明国际上已建立起一种未来网定位新理念。ICA所代表的“信息通信”领域内的网络软件结构进化,立足于把未来网规范为三层结构,即“应用(Application)层”、“中间件(Middleware)层”和“基础(Baseware)层”。ICA的出现,对我国谋求新崛起是大好机遇,这不仅可以直接振兴我国网络软件产业,更可激励我国在新一轮的网络进化的进程中力争跻身“领潮国”的行列。“ICA融合了各种最新信息技术的长处”。ICA结构进化,标志着当今网络进化的时代特征。推进和实现基于ICA的未来网,有着较佳的可行性。     

Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene

The deactivation characteristics of Pd/SiO₂ in the selective hydrogenation of acetylene were correlated with changes in the amount of the C4 species produced. The amounts of butenes produced changed in parallel with the catalyst activity, indicating that the rate limiting step for butene production was the same as that for acetylene hydrogenation. On the other hand, the amount of 1,3-butadiene produced changed, showing a maximum with catalyst deactivation because 1,3-butadiene is an intermediate in the sequential reaction process which involves both the production and consumption of 1,3-butadiene. This was verified by a simultaneous TG/reaction experiment showing that 1,3-butadiene was a precursor of green oil. The catalyst showed a self-regenerative behavior in its activity and the amounts of C4 species produced during the early stage of deactivation because two opposite factors, which contributed to either the lowering or the promotion of activity, were involved in the process. A specific type of polymer species, produced during the initial period of deactivation, is proposed to be responsible for the promotion of catalyst activity.     

A hybrid extended finite element/level set method for modeling phase transformations

A hybrid numerical method for modelling the evolution of sharp phase interfaces on fixed grids is presented. We focus attention on two‐dimensional solidification problems, where the temperature field evolves according to classical heat conduction in two subdomains separated by a moving freezing front. The enrichment strategies of the eXtended Finite Element Method (X‐FEM) are employed to represent the jump in the temperature gradient that governs the velocity of the phase boundary. A new approach with the X‐FEM is suggested for this class of problems whereby the partition of unity is constructed with C¹(Ω) polynomials and enriched with a C⁰(Ω) function. This approach leads to jumps in temperature gradient occurring only at the phase boundary, and is shown to significantly improve estimates for the front velocity. Temporal derivatives of the temperature field in the vicinity of the phase front are obtained with a projection that employs discontinuous enrichment. In conjunction with a finer finite difference grid, the Level Set method is used to represent the evolution of the phase interface. An iterative procedure is adopted to satisfy the constraints on the temperature field on the phase boundary. The robustness and utility of the method is demonstrated with several benchmark problems of phase transformation. Copyright © 2002 John Wiley & Sons, Ltd.     

城市环境的影响与作用

揭示了城市环境的基本性质的基本特征，研究了城市环境对人的心理影响和生理影响。指出城市环境建设不公要满足人的物质需要，还要满足人的精神需要。     

利用高酸值餐饮废油脂制备生物柴油

以高酸值餐饮废油脂为原料,在酯化反应后再经两步酯交换反应制备生物柴油。在酯化反应中添加吸水剂可降低油脂的酸值,经一次酯化反应即可将油脂的酸值降至2m g/g左右,满足酯交换反应的要求。考察了酯化反应中吸水剂的添加方式、种类及其用量对酯化反应的影响,以及酯交换催化剂的种类及用量对脂肪酸甲酯(FAME)收率和产物组成的影响。实验结果表明,以凹凸棒土为吸水剂(用量为餐饮废油脂中游离脂肪酸质量的3%),且在酯化反应30m in时加入,酯化效果较好;以质量比为1∶1的NaOH和KOH混合物为催化剂进行两步酯交换反应时,催化剂的最佳用量依次为1.00%和0.75%(质量分数,基于油脂的质量),FAME收率最高达到96.33%。