梯度功能氧化物电极的电性能研究

首次将梯度法应用于电极材料的制作中,进行了梯度法对电极的表面形貌和电性能影响的一系列实验,包括梯度的组成及变化次数,每次的涂制次数,梯度一层的热氧化温度和时间等。     

硅质钢包内衬脱除层的研制与使用

以石英砂为主要原料，研制了一种硅质钢包内村脱除层。该脱除层用于铝镁浇注料整体浇注钢包内村时，可使包役期满的工作层顺利脱除；使永久层耐火材料得到保护；可节约耐火材料１．６２ｋｇ／ｔ钢。     

对硝基苯胺反应釜优化控制系统的研制

对硝基苯胺反应釜优化控制系统是以调优工作为基础,KMM可编程调节器为核心的计算机优化控制系统。该系统采用选择控制和采样调节,并有显示、记录、报警、手/自动切换等多种功能,具有功能齐全,抗干扰能力强,操作方便,稳定可靠等特点。     

基于等转化率法的生物焦CO_2气化反应动力学参数研究

利用热重分析仪在800~950℃对稻秆焦和木屑焦CO2等温气化过程进行了研究。分别采用等转化率法和随机孔模型求解了稻秆焦和木屑焦气化反应的动力学参数。通过等转化率法发现,随着碳转化率的增加,反应活化能随着碳转化率的升高而增大,稻秆焦和木屑焦在碳转化率为0.02时刻(即接近初始时刻)的活化能分别为157.2 k J/mol和166.4 k J/mol;采用随机孔模型计算得到稻秆焦和木屑焦的活化能分别为155.1 k J/mol和165.5 k J/mol,与等转化率法求得的碳转化率为0.02时刻的活化能接近,表明随机孔模型可以准确地描述稻秆焦和木屑焦的气化特性。同时发现,同一气化温度下,稻秆焦的结构参数大于木屑焦的结构参数;不同温度下的同一焦炭的结构参数f与对应的气化温度存在良好的指数关系。最后结合结构参数f与气化温度的指数关系表达式,得出稻秆焦和木屑焦的等温气化反应动力学随机孔模型速率表达式。     

微热光电系统整体性能的试验研究

在设计和加工模块式微热光电系统关键部件的基础上,进行了系统的整体性能试验,包括流量、喷嘴形状和燃料对其性能的影响。试验结果表明：气体流量增加,燃烧室壁面温度升高,光电池的输出电量升高;相比圆形喷嘴,使用矩形喷嘴能改善预混合气在燃烧室内的分布,提高燃烧驻留时间,使燃烧更充分,增大光电池的电能输出;相同体积流量下,高热值的甲烷燃料比氢气燃料更能提高微热光电系统的性能。试验条件下较好的性能输出数据如下：当采用矩形喷嘴和甲烷燃料时,最大输出功率为0.319W,相应的能量密度达到166146W/m3;两种燃料最大整体效率都是在流量600mL.min-1时,且采用氢气燃料整体效率比甲烷的高,其最大效率为0.249%。     

Proton exchange membrane fuel cell system diagnosis based on the multivariate statistical method

Although electric-powered vehicles have developed rapidly in recent years, with significant progress in the lithium power battery industry, the Fuel Cell Electric Vehicle (FCEV) is still a competitive choice for a clean transportation solution, because of its extended driving range, zero emissions, and fast fuel recharging capability. In particular the fuel cell hybrid bus used for city traffic is the FCEV type most likely to be commercialized. Demonstration programs for a fuel cell bus fleet have been operated for a few years in China. It is necessary to develop comprehensive diagnostic tools to increase the reliability of these systems, because fuel cell city buses serve large numbers of passengers using public transportation. This paper presents a diagnostic analysis and implementation study based on the Principal Component Analysis (PCA) method for the fuel cell system. This diagnostic system was successfully implemented for detecting a fuel cell stack sensor network failure in the fuel cell bus fleet at the Shanghai Expo in 2010.     

循环流化床烟气脱硫中过湿现象的实验研究与分析

在循环流化床烟气脱硫试验研究中，发现的反应塔内的过湿现象，进行了分析与讨论，并研究了过湿现象对脱硫装置的脱硫效率和稳定运行的影响，指出脱硫塔内过湿区既是脱硫反应的主反应区，也是主要的结垢区，它对脱硫装置稳定高效运行起着重要作用。图6参5     

涡流室式柴油机性能的改进和排放的降低

本文系统全面地分析了国内涡流室式柴油机的性能和排放方面的发展现状,并介绍了进一步的研究成果和提高其性能,减少排放的一系列行之有效的方法和措施。     

安装角变化下垂直轴风力机气动性能的研究

建立了3D垂直轴风力机模型,应用FLUENT软件求解三维非定常不可压缩N-S方程和RNGκ-ε湍流模型,采用SIMPLE算法并结合滑动网格技术,数值模拟了安装角变化下垂直轴风力机的三维非定常流场,分析了不同时刻的速度、涡量分布、风力机总转矩的变化规律及风能利用系数。结果表明,计算区域流场复杂,垂直轴风力机的转矩呈周期性变化,风能利用系数随安装角变化而变化。     

The effect of H2S and CO mixtures on PEMFC performance

Proton exchange membrane fuel cells (PEMFCs) most likely will use reformed fuel as the primary source for the anode feed which always contains carbon dioxide (CO) and hydrogen sulfide (H₂S). Trace amount of CO and H₂S can cause considerable cell performance losses. A comparison between the effect of CO and that of H₂S on PEMFC performance was made in this paper. Under the same conditions, the H₂S poisoning rate is much higher than CO because of different adsorption intensity. When the fuel stream contains the gas mixture (25 ppm CO and 25 ppm H₂S), the fuel cell performance deteriorates more quickly than 50 ppm CO but slowly than 50 ppm H₂S and can be only partially recovered by reintroducing neat H₂. The resulting effects of the mixtures can be divided into two parts roughly: during the inception phase, the cell voltage drops quickly and the actual values of anode overvoltage are bigger than the corresponding calculated values; then the deterioration rate of the cell performance decreases gradually.