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111.
Nuno Mateus Joana Oliveira João Pissarra Ana M. González-Paramás Julian C. Rivas-Gonzalo Celestino Santos-Buelga Artur M.S. Silva Victor de Freitas 《Food chemistry》2006
A new pyranoanthocyanin–vinylphenol pigment was detected in an aged Port red wine. The UV–Vis spectrum of this pigment was found to have a λmax of 538 nm that is bathochromically shifted from that of original anthocyanins, exhibiting a more purple hue in acidic solution. This newly formed pigment was synthesized in model solution through the reaction between malvidin 3-O-glucoside–pyruvic acid adduct and vinylphenol and its structure was assigned by NMR and mass spectrometry. This pigment is reported herein for the first time. 相似文献
112.
Marcus V.C. AlvesJader R. Barbosa Jr. Alvaro T. PrataFernando A. Ribas Jr. 《International Journal of Refrigeration》2011,34(1):74-83
This work presents a mathematical analysis of an oil supply system for reciprocating compressors. The system is based on a single screw pump attached to the bottom end of the vertical rotating shaft immersed in the oil sump. The fluid flow in the pump was modeled with a semi-analytical approach based on the solution for the laminar fully developed oil flow in a screw extruder via the Generalized Integral Transform Technique. The screw pump model is coupled with that for the flow in the shaft region so as to provide an estimate of the oil flow rate and of the so-called ‘climbing-time’, i.e., the amount of time needed for a fluid particle to travel from the oil sump to the top of the shaft. The calculation method was verified against experimental data and Computational Fluid Dynamics modeling results. 相似文献
113.
Helena Ribeiro Joana Marto Sara Raposo Maria Agapito Vera Isaac Bruna G. Chiari Pedro F. Lisboa Alexandre Paiva Susana Barreiros Pedro Simões 《European Journal of Lipid Science and Technology》2013,115(3):330-336
Spent coffee grounds (SCG), which are the residue obtained from the treatment of coffee with hot water or steam, can be used for industrial applications, due to the high content in lipids. The cosmetic products might be a suitable application for these types of residues because the barrier properties of the stratum corneum (SC) are largely dependent on the intactness of the lipid lamellae that surrounds the corneocytes. The purpose of this work was to assess the feasibility of using the lipid fraction of SCG extracted with supercritical carbon dioxide in the development of new cosmetic formulations with improved skin lipids (sebum) and hydration. The use of spent coffee lipid extract in cosmetic industry seems to be a suitable approach to recycle the wastes from coffee industry. Emulsion containing 10% of the lipid fraction of SCG (SpentCofOil cream) presented promising characteristics in the improvement of sebum skin levels with a good acceptance by consumers when compared to an emulsion containing 10% w/w of green coffee oil (GreenCofOil cream) and a placebo without coffee oil (NoCofOil cream). Practical applications: In this work, the authors develop and characterize a cream containing 10% of the lipid fraction of SCG extracted with supercritical carbon dioxide with improved skin lipids (sebum) and hydration. 相似文献
114.
Sergio Neves Monteiro Felipe Perissé Duarte Lopes Anderson Paula Barbosa Alice Barreto Bevitori Isabela Leão Amaral Da Silva Lucas Lopes Da Costa 《Metallurgical and Materials Transactions A》2011,42(10):2963-2974
Recent investigations on the tensile properties of natural cellulose-based fibers revealed an increasing potential as engineering
materials. This is particularly the case of very thin fibers of some species such as sisal, ramie, and curaua. However, several
other commonly used fibers such as flax, jute, hemp, coir, cotton, and bamboo as well as less known bagasse, piassava, sponge
gourde, and buriti display tensile properties that could qualify them as engineering materials. An overview of the strength
limits attained by these fibers is presented. Based on a tensile strength vs density chart, it is shown that natural fibers stand out as a relevant class of engineering materials. 相似文献
115.
S.C. Lima N. AddedM.D.L. Barbosa G.F. TrindadeM.I.D.A. Fleming 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2011,269(24):3025-3031
Ceramics objects are the most common artifacts found during excavation of archaeological sites and often depicts cultural habits and manufacturing technologies of the culture. The determination of macroscopic and microscopic characteristics of the ceramic objects such as the ceramic porosity, addition of tempers in the clay, main chemical components and the trace elements present in the ceramic can reveal many aspects about the manufacturing processes used by the culture, its degree of development, the provenance of the raw materials and the exchange networks. Also the radiography can help to investigate the manufactured processes, the size of the tempers used and the conservation status of the artifacts. In this present work two non-destructive techniques, radiography and PIXE (Particle Induced X-ray Emission) were used to characterize one set of thirty-six pre-Hispanic ceramic pieces from the Chimu Culture conserved in the Museu de Arqueologia e Etnologia (MAE/USP). The PIXE analyses performed in the external beam setup at LAMFI (Laboratório de Análise de Materiais por Feixes Iônicos) allowed measure the principal chemical elements such as Al, Si, K, Ti, Fe and Ca, present in this group of pieces. X-ray imagings allowed identify the manufacture processes, the granularity of the tempers used, as well as the similarity and the differences between the pieces studied. 相似文献
116.
José Lucena Barbosa Júnior Maurício Cordeiro Mancini Miriam Dupas Hubinger 《International Journal of Food Science & Technology》2013,48(12):2463-2473
A simple mathematical model to predict dehydration and impregnation process during osmotic dehydration of orange‐fleshed honeydew in sucrose and corn syrup solutions was proposed. Results showed low dispersion and a good fitting capability for WL and SG kinetics. Diffusivity values for WL ranged from 0.96 × 10?10 to 2.22 × 10?10 and 1.04 × 10?10 to 3.10 × 10?10 m2 s?1 in corn syrup and sucrose solutions, respectively. For SG, the obtained range was 0.72 × 10?10 to 2.35 × 10?10 and 0.71 × 10?10 to 2.46 × 10?10 m2 s?1 in corn syrup and sucrose solutions, respectively. The half‐life of dehydration rates (t1/2) was from 30.9 to 71.2 min and from 19.4 to 57.5 min in corn syrup and sucrose solutions, respectively. Diffusivities values obtained according to the proposed model were close to the ones observed from diffusive model; t1/2 was a promising criterion for the process time definition. 相似文献
117.
Joana S. Cristóv?o Sónia S. Leal Isabel Cardoso Cláudio M. Gomes 《International journal of molecular sciences》2013,14(9):19128-19145
Superoxide dismutase 1 (SOD1) aggregation is one of the pathological markers of amyotrophic lateral sclerosis (ALS), a fatal neurodegenerative disorder. The underlying molecular grounds of SOD1 pathologic aggregation remains obscure as mutations alone are not exclusively the cause for the formation of protein inclusions. Thus, other components in the cell environment likely play a key role in triggering SOD1 toxic aggregation in ALS. Recently, it was found that ALS patients present a specific altered metabolomic profile in the cerebrospinal fluid (CSF) where SOD1 is also present and potentially interacts with metabolites. Here we have investigated how some of these small molecules affect apoSOD1 structure and aggregation propensity. Our results show that as co-solvents, the tested small molecules do not affect apoSOD1 thermal stability but do influence its tertiary interactions and dynamics, as evidenced by combined biophysical analysis and proteolytic susceptibility. Moreover, these compounds influence apoSOD1 aggregation, decreasing nucleation time and promoting the formation of larger and less soluble aggregates, and in some cases polymeric assemblies apparently composed by spherical species resembling the soluble native protein. We conclude that some components of the ALS metabolome that shape the chemical environment in the CSF may influence apoSOD1 conformers and aggregation. 相似文献
118.
Exact corotational shell for finite strains and fracture 总被引:2,自引:2,他引:0
The corotational method for frame-invariant elements is generalized to obtain a consistent large-strain shell element incorporating
thickness extensibility. The resulting element allows arbitrary in-plane deformations and is distinct from the traditional
corotational methods (either quadrature-based or element-based) in the sense that the corotational frame is exact. The polar
decomposition operation is performed in two parts, greatly simplifying the linearization calculations. Expressions for the
strain-degrees-of-freedom matrices are given for the first time. The symbolic calculations are performed with a well-known
algebraic system with a code generation package. Classical linear benchmarks are shown with excellent results. Applications
with hyperelasticity and finite strain plasticity are presented, with asymptotically quadratic convergence and very good benchmark
results. An example of finite strain plasticity with fracture is solved successfully, showing remarkable robustness without
the need of enrichment techniques. 相似文献
119.
Rodrigo R. Oliveira Felipe C. Noguez Cristiano A. Costa Jorge L. Barbosa Mario P. Prado 《Expert systems with applications》2013,40(6):2023-2031
Logistics represent the biggest cost for transportation companies. Companies are investing in monitoring and tracking systems aiming at improving services, reducing costs and ensuring the safety in cargos transports. This article presents an intelligent model to obtain the position of vehicles, using off-the-shelf mobile devices named SWTRACK. The proposal allows distributors companies to track loads and to have real-time information about their whereabouts during a travel. SWTRACK presents an automatic travel management to initialize and finish travels without user interaction. Furthermore, it provides a mechanism to monitor detours in planned routes and to send alarms notification through mobile devices. To build that mechanism, we studied the Geofence concept and existing techniques to prepare two solutions based on continuous monitoring. Those solutions were compared and discussed. We also conducted a model evaluation using off-the-shelf mobile devices. Moreover, we provide an impact analysis regarding GPS precision and battery power consumption. In the end, we show that the proposed model generates a reliable system for tracking vehicles. 相似文献
120.