癸二酸二甲酯与1,2,2,6,6-五甲基哌啶醇的酯交换反应

对癸二酸二甲酯与1,2,2,6,6-五甲基哌啶醇的酯交换反应进行了研究;分别考察了四异丙基钛酸酯、氨基锂、氧化二辛基锡3种催化剂的性能;采用氢核磁共振确定了产物的结构;考察了以四异丙基钛酸酯为催化剂时反应温度、反应时间、原料配比和催化剂用量对反应的影响。实验结果表明,四异丙基钛酸酯催化剂的催化效果最好;在癸二酸二甲酯与1,2,2,6,6-五甲基哌啶醇摩尔比1∶1.79、四异丙基钛酸酯催化剂的用量为反应物总质量的0.31%、反应温度180℃、反应时间6h的条件下,所得产物中单(1,2,2,6,6-五甲基-4-哌啶基)癸二酸甲酯(简称单酯)质量分数为23%和双(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯(简称双酯)质量分数为73%,单双酯质量比为1∶3.17,产物收率为93.3%。该方法可得到理想的单双酯比例及产物收率,具有很好的工业应用前景。     

径向水平井弯曲转向机构影响因素仿真研究

针对径向水平井钻进中钻杆弯曲转向前进运动困难的问题,通过建立弯曲转向机构仿真有限元模型,对其主要影响因素:滑道轨迹曲率、间隙、工作压力、滚轮形状与位置和钻杆壁厚等用ANSYS软件进行仿真研究。研究表明:影响截面变形的主要因素是滑道曲率的改变和滑道摩擦因数,钻井失败时钻杆所受阻力的增大不是因为升高工作压力导致截面变形过大与滑道干涉所致,钻杆经校直段,钻头中轴线与校直中心线存在一定的角度,即钻杆的前进轨迹就会偏离理论值,或与地层干涉,或可能再次发生弯曲变形;另一主要原因是转向器滑道工作恶化。增加钻杆壁厚,降低工作压力和滑道摩擦因数,设计合理弯曲转向机构是解决问题的关键。     

A novel compact ring dual-mode filter with adjustable second-passband for dual-band applications

In this letter, a novel compact ring dual-mode with adjustable second-passband for dual-band applications are presented. A ring resonator with two different geometric dimensions are derived and designed to have identical fundamental and the first higher-order resonant frequencies, and to establish appropriate couplings in the structure. Moreover, the proposed filter has smaller size as compared with the basic topology of stopband filters and stepped-impedance-resonator (SIR) filters. The measured filter performance is in good agreement with the simulated response.     

FCC汽油叠合生产柴油的研究——(Ⅰ)叠合催化剂的研制

采用中孔γ-Al2O3为载体，以非贵金属Ni为活性金属组分，以金属Sn为助剂组分，制备了FCC汽油叠合生产柴油的催化剂。在实验室小型连续流动式固定床装置上，以FCC汽油为原料，考察了主活性金属负载量、助催化剂、催化剂制备条件对催化剂性能的影响。研究结果表明，在活性金属Ni质量分数为8％，助催化剂Sn质量分数为1％，浸渍时间6h，焙烧温度500℃，焙烧时间4h的条件下，制备的叠合催化剂的催化性能最好。并对催化剂进行了1500h的稳定性试验和再生性能考察，结果表明该叠合催化剂具有良好的稳定性和再生性能。     

炼油厂碱性污水生物催化氧化预处理工艺研究

在对炼油厂碱性污水水质分析的基础上,提出采用生物催化氧化工艺对碱性污水进行预处理。试验结果表明,在水力停留时间为4 h,曝气量(标准状态)为8 m3／h的条件下,碱性污水的硫化物去除率可达90％以上,出水中的硫化物平均值为15．2 mg/L,CODCR、酚和油的去除率分别为47．5％,44．1％,50．8％,其中CODCR体积负荷为3．85 kg／(m3·d),是传统生化处理的10倍, 达到了污水预处理的目的。     

水泥砂浆衬里在输水钢管内壁防腐中的应用

结合工程实例,阐述了在输水水质腐蚀性不大的情况下,输水钢管的内壁防腐采用水泥砂浆衬里的必要性和优点,并介绍了设计要点和安装施工注意事项。     

润滑油用纳米TiO2的表面改性及自修复性能研究

采用油酸对纳米TiO2进行表面改性，使其稳定分散于基础油中。利用HQ-1摩擦磨损试验机考察纳米TiO2的自修复性能，并探讨其自修复机理。试验结果表明，经改性后的纳米TiO2粉体作为润滑添加剂具有良好的分散稳定性、减摩抗磨性和自修复性。     

Blind estimation of OFDM carrier frequency offset via oversampling

Blind deterministic estimation of the orthogonal frequency division multiplexing (OFDM) frequency offset via oversampling is proposed in this paper. This method utilizes the intrinsic phase shift of neighboring sample points incurred by the frequency offset that is common among all subcarriers. The proposed method is data efficient - it requires only a single OFDM symbol to achieve reliable estimation, hence making it more suitable to systems with stringent delay requirement and mobility-induced channel variation. The proposed scheme is devised to perfectly retrieve frequency offset in the absence of noise. Quite remarkably, we show that in the presence of channel noise, this intuitive scheme is indeed the maximum likelihood estimate of the carrier frequency offset. The possible presence of virtual carriers are also accommodated in the system model, and some interesting observations are obtained. The Cramer-Rao lower bound is derived for the oversampling-based signal model, and we show through numerical simulation that the proposed algorithm is efficient. Practical issues such as identifiability, the front-end filter bandwidth, and the possible presence of correlated noises are also carefully addressed.     

笼形团簇材料

近年来,在原子、分子和凝聚态两层次之间出现了原子团簇这一重要的学科领域。本文介绍了笼形团簇材料的国内外最新研究进展,分析了笼形团簇材料的研究现状,并对其未来的发展方向进行了展望。     

WAVE INTERACTION WITH PERFORATED CAISSON BREAKWATERS

The reflection coefficient of perforated caissons and the total horizontal forces acting on them were experimentally and numerically analyzed and discussed when wave propagates normally. To consider the viscosity effect of fluid and nonlinear action of waves on structures, the VOF (Volume Of Fluid) method combined with the k-ε turbulence model was used to simulate the interaction between waves and structures. Governing equations were solved with the finite difference method. Through 2D experimental study in the wave flume, the empirical relationship between the reflection coefficient of perforated caissons and the main affecting factors were obtained from the experimental data using the least square method. Also the correlation between the ratio of the total horizontal force acting on perforated caisson and the force acting on solid caisson and the main affecting factors were regressed from the experimental data.