Hydrophobic Chromophores in Aqueous Micellar Solution Showing Large Two‐Photon Absorption Cross Sections

A series of new hydrophobic two‐photon absorbing (2PA) chromophores with varied electron‐donating groups in quasi‐linear and multibranched structures are synthesized to correlate their structure/photophysical property relationships. The feasibility of using these large two‐photon absorption cross‐sectional (δ, expressed in GM = 1 × 10^–50 cm⁴ s photon^–1 molecule^–1) materials in aqueous solution is also explored. All four hydrophobic 2PA materials can be encapsulated into micelles generated by dispersing an amphiphilic block copolymer, poly(methacrylic acid)‐block‐polystyrene (PMAA‐b‐PS), into water. The micellar nanostructures are characterized using dynamic light scattering, atomic force microscopy, and transmission electron microscopy. After these dyes are incorporated into micelles, they exhibit strong fluorescence in water. It is found that the quantum yield and δ values of these chromophores are strongly dependent on the diameters of the micelles, concentrations of the PMAA‐b‐PS, and molecular structures of the 2PA chromophores. One of the compounds that has a strong triarylamino donor and a multibranched structure exhibits a large δ value of 2790 GM and high quantum yield (0.56) in micelle‐containing water. Although this value is smaller than the original value of 5300 GM in toluene, it is still substantially larger than the values of most water‐soluble 2PA materials, which have δ values of less than 100 GM.     

A Multi‐Strategic Concept‐Spotting Approach for Robust Understanding of Spoken Korean

We propose a multi‐strategic concept‐spotting approach for robust spoken language understanding of conversational Korean in a hostile recognition environment such as in‐car navigation and telebanking services. Our concept‐spotting method adopts a partial semantic understanding strategy within a given specific domain since the method tries to directly extract pre‐defined meaning representation slot values from spoken language inputs. In spite of partial understanding, we can efficiently acquire the necessary information to compose interesting applications because the meaning representation slots are properly designed for specific domain‐oriented understanding tasks. We also propose a multi‐strategic method based on this concept‐spotting approach such as a voting method. We present experiments conducted to verify the feasibility of these methods using a variety of spoken Korean data.     

Deposition of CoPtP films from citric electrolyte

Magnetically hard CoPtP (up to 40 μm thickness) films for MEMS application were deposited from citrate electrolyte and considered in terms of their composition, structure, magnetic characteristics and deposition conditions. Films containing 83-92 at.% (a/o) Co were deposited in the presence of NaH₂PO₂ in the electrolyte, with current efficiency of about 20% (deposition rate 10-12 μm/h). Coercivity 2.7-2.8 kOe and remanence 3.0 kG were achieved magnetizing in the direction normal to the film plane. According to XRD analysis, films seem to consist of hexagonal phase of CoPt solid solutions. Current efficiency, composition and morphology of the films, as well as their magnetic characteristics, were influenced by the electrolyte prehistory and total charge passed through the electrolyte in previous operation.     

Two-dimensional synthetic aperture images over a land surface scene

The Soil Moisture and Ocean Salinity (SMOS) space mission is currently undergoing phase-B studies at the European Space Agency. The SMOS payload is an L-band interferometric radiometer based on a two-dimensional aperture synthesis concept. This paper presents the first images obtained by a demonstrator of the SMOS instrument over land surfaces at the Avignon test site in 1999     

Characterization method of thermomechanical parameters for microelectronic materials

Reliability of thermomechanical simulations is critically linked to the accuracy of the mechanical properties that govern the behaviour of structure, like Young's modulus (E) and coefficient of thermal expansion (CTE). For many cases, the values found in literatures are dealing with bulk properties without detailed information on temperature effects. To address such issues, it is necessary to measure the materials parameters as a function of temperature. The measurement of CTE is usually accomplished by evaluating the thermal deflections of a subjected material layer deposited on a substrate, providing that E is known at a specific temperature of experiment. A bilayer method, based on theory of elasticity, is proposed to determine both E and CTE for a given temperature with a good resolution. This paper presents the theoretical analysis, the design and process of the microsystem test structures, and the main calculation results.     

Mergers and Acquisitions in the Telecommunications Industry: Myths and Reality

This paper investigates how market participants react to mergers and acquisitions (M&As) involving telecommunications companies. The empirical evidence suggests that such activities convey bad news to the market. This is consistent with the synergy trap hypothesis and extant empirical findings of value‐reducing diversification strategies in recent literature. The evidence also indicates that a cross‐border, rather than a domestic M&A deal, is the main driver of the negative market reaction. Further, our evidence of negative impacts on the bidder's business after an M&A reinforces our main finding that market participants, on average, perceive M&A activities to be detrimental to shareholder value. This suggests that value creation or synergy through an M&A deal is not warranted even though it can generate an increase in size of the firm.     

Microstructure and Electrical Properties of Low Temperature Processed Ohmic Contacts to p‐Type GaN

With Ni/Au and Pd/Au metal schemes and low temperature processing, we formed low resistance stable Ohmic contacts to p‐type GaN. Our investigation was preceded by conventional cleaning, followed by treatment in boiling HNO₃:HCl (1:3). Metallization was by thermally evaporating 30 nm Ni/15 nm Au or 25 nm Pd/15 nm Au. After heat treatment in O₂ + N₂ at various temperatures, the contacts were subsequently cooled in liquid nitrogen. Cryogenic cooling following heat treatment at 600 ·C decreased the specific contact resistance from 9.84·10^?4 Ωcm² to 2.65·10^?4 Ωcm² for the Ni/Au contacts, while this increased it from 1.80·10^?4 Ωcm² to 3.34·10^?4 Ωcm² for the Pd/Au contacts. The Ni/Au contacts showed slightly higher specific contact resistance than the Pd/Au contacts, although they were more stable than the Pd contacts. X‐ray photoelectron spectroscopy depth profiling showed the Ni contacts to be NiO followed by Au at the interface for the Ni/Au contacts, whereas the Pd/Au contacts exhibited a Pd:Au solid solution. The contacts quenched in liquid nitrogen following sintering were much more uniform under atomic force microscopy examination and gave a 3 times lower contact resistance with the Ni/Au design. Current‐voltage‐temperature analysis revealed that conduction was predominantly by thermionic field emission.     

Broadband access using subcarrier multiplexing and asymmetric digital subscriber lines

A broadband access system using subcarrier multiplexing on optical fibre and asymmetric digital subscriber lines (ADSL) or very high‐speed digital subscriber lines (VDSL) on unshielded twisted‐pair is proposed to provide broadband access. In this hybrid‐fibre/twisted‐pair (HFTP) system, the digital multiplexing/demultiplexing process is moved back to the central office by using subcarrier multiplexing for fibre transmission. Instead of installing in remote node, ADSL/VDSL transceivers are installed at the central office to greatly reduce the remote node complexity. The local node simply down‐converts the subcarrier multiplexed ADSL/VDSL signal to the baseband, suitable to send directly into the twisted‐pair. The reduction of complexity could result in a lower initial installation cost, especially for a low service penetration rate. Copyright © 2000 John Wiley & Sons, Ltd.     

Product Multicommodity Flow in Wireless Networks

We provide a tight approximate characterization of the n-dimensional product multicommodity flow (PMF) region for a wireless network of n nodes. Separate characterizations in terms of the spectral properties of appropriate network graphs are obtained in both an information-theoretic sense and for a combinatorial interference model (e.g., protocol model). These provide an inner approximation to the n ²-dimensional capacity region. Our results hold for general node distributions, traffic models, and channel fading models. We first establish that the random source-destination model assumed in many previous results on capacity scaling laws, is essentially a one-dimensional approximation to the capacity region and a special case of PMF. We then build on the results for a wireline network (graph) that relate PMF to its spectral (or cut) properties. Specifically, for a combinatorial interference model given by a network graph and a conflict graph, we relate the PMF to the spectral properties of the underlying graphs resulting in simple computational upper and lower bounds. These results show that the 1/radicn scaling law obtained by Gupta and Kumar for a geometric random network can be explained in terms of the scaling law of the conductance of a geometric random graph. For the more interesting random fading model with additive white Gaussian noise (AWGN), we show that the scaling laws for PMF can again be tightly characterized by the spectral properties of appropriately defined graphs-such a characterization for general wireless networks has not been available before. As an implication, we obtain computationally efficient upper and lower bounds on the PMF for any wireless network with a guaranteed approximation factor.     

A Generalization of the Blahut–Arimoto Algorithm to Finite-State Channels

The classical Blahut-Arimoto algorithm (BAA) is a well-known algorithm that optimizes a discrete memoryless source (DMS) at the input of a discrete memoryless channel (DMC) in order to maximize the mutual information between channel input and output. This paper considers the problem of optimizing finite-state machine sources (FSMSs) at the input of finite-state machine channels (FSMCs) in order to maximize the mutual information rate between channel input and output. Our main result is an algorithm that efficiently solves this problem numerically; thus, we call the proposed procedure the generalized BAA. It includes as special cases not only the classical BAA but also an algorithm that solves the problem of finding the capacity-achieving input distribution for finite-state channels with no noise. While we present theorems that characterize the local behavior of the generalized BAA, there are still open questions concerning its global behavior; these open questions are addressed by some conjectures at the end of the paper. Apart from these algorithmic issues, our results lead to insights regarding the local conditions that the information-rate-maximizing FSMSs fulfill; these observations naturally generalize the well-known Kuhn-Tucker conditions that are fulfilled by capacity-achieving DMSs at the input of DMCs.