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101.
102.
Andreas Reindl Rouven Borowsky Sebastian Boris Hein Juergen Geis-Gerstorfer Philipp Imgrund Frank Petzoldt 《Journal of Materials Science》2014,49(24):8234-8243
When it comes to bone replacement in load-bearing areas, there are currently no adequate biodegradable implants available. Several non-degradable metallic materials fulfill the requirements of biocompatibility and mechanical strength. However, besides magnesium, only iron is a degradable metallic material. The aim of this long-term degradation study was to investigate the effects of iron beta-tricalcium phosphate interpenetrating phase composite on degradation rate and strength in comparison to pure iron. Cylindrical samples with 0–50 vol% beta-tricalcium phosphate (ß-TCP) were prepared by powder injection molding. In addition to dense samples, porous iron samples with a porosity of 60.3 % were produced with polyoxymethylene as a placeholder. Dense and porous samples were immersed in 0.9 % sodium chloride solution (NaCl) or in phosphate buffered saline solution (PBS) for 56 days. Following immersion, the degradation rate, compressive yield strength, and ion release were determined. A maximum degradation rate of 196 µm/year was observed after 56 days for iron with 40 vol% ß-TCP. This was found to be 28 % higher than for pure iron. After immersion, the compressive yield strength of pure iron decreased by 44 % (NaCl) and 48 % (PBS). In comparison, iron with 40 % ß-TCP samples lost <1 % (NaCl) and 9 % (PBS) of strength following immersion. It was demonstrated that the solubility of calcium phosphate enhanced the corrosion processes and led to an increase in degradation, thus showing that the addition of ß-TCP to pure iron can be a promising route for a novel degradable bone substitute material, particularly for load-bearing areas due to the increased strength. 相似文献
103.
Pavol Hanus Bernhard Goebel Janis Dingel Johanna Weindl Juergen Zech Zaher Dawy Joachim Hagenauer Jakob C. Mueller 《Electrical Engineering (Archiv fur Elektrotechnik)》2007,90(2):161-173
The DNA sequencing efforts of the past years together with rapid progress in sequencing technology have generated a huge amount
of sequence data available in public molecular databases. This recent development makes it statistically feasible to apply
universal concepts from Shannon’s information theory to problems in molecular biology, e.g to use mutual information for gene
mapping and phylogenetic classification. Additionally, the genetic information in the cell is continuously subject to mutations.
However, it has to be passed from generation to generation with high fidelity, raising the question of existence of error
protection and correction mechanisms similar to those used in technical communication systems. Finally, better understanding
of genetic information processing on the molecular level in the cell can be acquired by looking for parallels to well established
models in communication theory, e.g. there exist analogies between gene expression and frame synchronization. 相似文献
104.
Katrin Mackenzie Juergen Battke Robert Koehler Frank-Dieter Kopinke 《Applied catalysis. B, Environmental》2005,59(3-4):171-179
The hydrolysis reaction of 1,1,2,2-tetrachloroethane (TeCA) is significantly enhanced by sorption on activated carbon. TeCA is quantitatively transformed into trichloroethene (TCE) at moderate pH values. This transformation is exploited as the basic step of a site-adapted groundwater-cleanup technology. The volatility of TCE is a factor of 23 higher than that of TeCA such that the partially dehydrochlorinated product can be easily stripped out of the groundwater flow. The base-mediated and the neutral dehydrochlorination of TeCA were studied as a function of temperature and pH value in batch and column experiments. Surprisingly, it was found that despite high loadings of the sorbent with TeCA and TCE (≥20 wt.%) the TeCA remains available for the hydrolysis reaction. 相似文献
105.
In this publication, several stainless steel microstructure reactors specially designed to obtain rapid and periodic temperature changes are presented. Different microstructure reactor designs have been manufactured and tested for their thermal behaviour and equally by running a test reaction under stationary and non-stationary temperature conditions. The devices were continuously electrically heated and periodically cooled by a deionized water flow. The objective of the experimental measurements was to demonstrate that non-stationary temperature conditions may lead to an increase in the reaction rate compared to the stationary conditions. The heterogeneously catalysed oxidation of CO was chosen as the test reaction. The catalyst used was a dispersion of platinum on a porous alumina support generated by sol-gel technology. The experiments realized under non-stationary temperature conditions with a temperature oscillation amplitude of 41 K and a period duration of 21 s show an increase in the mean CO2 concentration of a factor 1.72 compared to the mean concentration under quasi-stationary temperature conditions. The simulations of a simple monomolecular reaction under non-stationary temperature conditions indicate that the presence of a transitional surface coverage generated by the temperature oscillations may be a possible explanation for the observed phenomenon. 相似文献
106.
Torsten Henning Juergen J. Brandner Lutz Eichhorn Klaus Schubert Martin Schreiber Martin Güngerich Hermann Günther Peter J. Klar Vivian Rebbin Michael Fröba 《Microfluidics and nanofluidics》2007,3(3):299-305
We have incorporated microspheres, from 50 to 80 μm in diameter, of periodic mesoporous organosilica (inner surfaces up to
1,000 m2/g and pore sizes in the nanometre range) with two types of organic functionalities (benzene and ethane bridges, respectively)
inside microstructured channels (each 200 μm wide and 100 μm deep) and, exemplarily, monitored by Raman microscopy (Raman
spectroscopy through microscope optics) that the temperature characteristics of the adsorption–desorption equilibria of benzene
and ethanol vary significantly with the type of organic functionality of the microspheres and the pore morphology. The integration
of this class of nanostructured material into devices by means of microchannels is a promising novel approach to, among others,
substance separation in analytics, micro process engineering, and micro chemistry. 相似文献
107.
Marine C. R. Rauch Yann Gallou Léna Delorme Dr. Caroline E. Paul Prof. Dr. Isabel W. C. E. Arends Prof. Dr. Frank Hollmann 《Chembiochem : a European journal of chemical biology》2020,21(8):1112-1115
Elemental metals are shown to be suitable sacrificial electron donors to drive the stereoselective reduction of conjugated C=C double bonds using Old Yellow Enzymes as catalysts. Both direct electron transfer from the metal to the enzyme as well as mediated electron transfer is feasible, although the latter excels by higher reaction rates. The general applicability of this new chemoenzymatic reduction method is demonstrated, and current limitations are outlined. 相似文献
108.
Anja Henss Marcus Rohnke Thaqif El Khassawna Parameswari Govindarajan Gudrun Schlewitz Christian Heiss Juergen Janek 《Journal of the Royal Society Interface》2013,10(86)
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a well-established technique in material sciences but has not yet been widely explored for implementation in life sciences. Here, we demonstrate the applicability and advantages of ToF-SIMS analysis for the study of minerals and biomolecules in osseous tissue. The locally resolved analysis of fragment ions deriving from the sample surface enables imaging and differentiation of bone tissue and facilitates histology on non-stained cross sections. In a rat model, bilateral ovariectomy combined with either a multi-deficiency diet or steroid treatment was carried out to create osteoporotic conditions. We focused our study on the Ca content of the mineralized tissue and monitored its decline. Calcium mass images of cross sections show the progressive degenerative changes in the bone. We observed a decreased Ca concentration in the edge region of the trabeculae and a decline in the Ca/P ratio. Additionally, we focused on the non-mineralized matrix and identified fragment ions that are characteristic for the collagen matrix. We observed trabeculae with wide ranges of non-mineralized collagen for the diet group owing to an impaired mineralization process. Here, the advantage of coeval monitoring of collagen and minerals indicated an osteomalacic model rather than an osteoporotic one. 相似文献
109.
Dr. Dirk Holtmann Dr. Frank Hollmann 《Chembiochem : a European journal of chemical biology》2016,17(15):1391-1398
Monooxygenases are promising catalysts because they in principle enable the organic chemist to perform highly selective oxyfunctionalisation reactions that are otherwise difficult to achieve. For this, monooxygenases require reducing equivalents, to allow reductive activation of molecular oxygen at the enzymes' active sites. However, these reducing equivalents are often delivered to O2 either directly or via a reduced intermediate (uncoupling), yielding hazardous reactive oxygen species and wasting valuable reducing equivalents. The oxygen dilemma arises from monooxygenases' dependency on O2 and the undesired uncoupling reaction. With this contribution we hope to generate a general awareness of the oxygen dilemma and to discuss its nature and some promising solutions. 相似文献
110.
Parameter set selection for dynamic systems under uncertainty via dynamic optimization and hierarchical clustering
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Wei Dai Loveleena Bansal Juergen Hahn Daniel Word 《American Institute of Chemical Engineers》2014,60(1):181-192
It is common that only a subset of the parameters of models can be accurately estimated. One approach for identifying a subset of parameters for estimation is to perform clustering of the parameters into groups based upon their sensitivity vectors. However, this has the drawback that uncertainty cannot be directly incorporated into the procedure as the sensitivity vectors are based upon the nominal values of the parameters. This article addresses this drawback by presenting a parameter set selection technique that can take uncertainty in the parameter space into account. This is achieved by defining sensitivity cones, where a sensitivity cone includes all sensitivity vectors of a parameter for different values, resulting from the uncertainty, in the parameter space. Parameter clustering can then be performed based upon the angles between the sensitivity cones, instead of the angle between sensitivity vectors. The presented technique is applied to two case studies. © 2013 American Institute of Chemical Engineers AIChE J, 60: 181–192, 2014 相似文献