Compressive failure of UD-CFRP containing void defects: In situ SEM microanalysis

Here we present an in situ scanning electron microscopy (SEM) investigation of the compressive failure of unidirectional (UD) carbon fibre reinforced polymer (CFRP) composites with varying pre-existing void content. The experiments were carried out within a dual beam microscope, which couples a SEM with a focused ion beam (FIB), allowing sub-surface investigations of damage. In these tests, the specimen is monitored during the entire loading history, allowing the correlation of microstructural changes and the evolving load-displacement behaviour. Therefore, loading characteristics can be linked directly to failure events. Observations of the sequence of events leading to failure showed direct fibre deflection into a kinked shape eventually followed by fibre fracture. Failure of void-containing CFRP was shown to depend on the void shape as well as the proximity of the void to the kink band. In some cases voids stopped the propagation of kink bands, while in other cases the void caused the kink to deflect in a new direction. The failure structure was observed to change with time, both during hold-load segments as well as after unloading. Through cross-sectional ion beam milling in the unloaded state, the sub-surface damage was observed and shown to be similar to that observed at the surface.     

Association between alcohol-impaired driving enforcement-related strategies and alcohol-impaired driving

All states in the U.S. prohibit alcohol-impaired driving but active law enforcement is necessary for effectively reducing this behavior. Sobriety checkpoints, saturation patrols, open container laws, and media campaigns related to enforcement efforts are all enforcement-related strategies for reducing alcohol-impaired driving. We conducted surveys of all state patrol agencies and a representative sample of local law enforcement agencies to assess their use of alcohol-impaired driving enforcement-related strategies and to determine the relationship between these enforcement-related strategies and self-reported alcohol-impaired driving behavior obtained from the Behavioral Risk Factor Surveillance System. We found that sobriety checkpoints, saturation patrols, and enforcement of open container laws were associated with a lower prevalence of alcohol-impaired driving but, more importantly, a combination of enforcement-related strategies was associated with a greater decrease in alcohol-impaired driving than any individual enforcement-related activity. In addition, alcohol-impaired driving enforcement-related strategies were associated with decreased alcohol-impaired driving above and beyond their association with decreased binge drinking. Results suggest law enforcement agencies should give greater priority to using a combination of strategies rather than relying on any one individual enforcement activity.     

Time-dependent growth of biomimetic apatite on anodic TiO2 nanotubes

We report on the initial and later stages of apatite formation from simulated body fluid on titania with different surface morphologies (compact or nanotubular) and different crystal structures (anatase or amorphous). The nanotubular layers were fabricated by electrochemical anodization in fluoride-containing electrolytes. The study investigates the enhanced apatite deposition on titania nanotubes. In the initial stages of apatite growth, more nuclei are formed on the nanotubular surface than on flat compact TiO₂. While the crystallographic structure of the substrate plays a less important role than the morphology in the initial nucleation stages, it is of great importance in the later stages of apatite crystal growth. The nanotubular morphology combined with an anatase structure leads to the formation of apatite layers with a thickness of >6 nm in less than 2 days. No stable apatite layers can be observed on amorphous TiO₂ films, neither on compact nor on nanotubular substrates.XPS, FT-IR and XRD measurements reveal that carbonated hydroxyapatite (CHA) of low crystallinity is formed on annealed nanotubular and compact titania.Electrochemically grown and annealed TiO₂ nanotube arrays having anatase structure are expected to be a good precursor system for the formation of CHA and thus for the preparation of osseointegrative implants.     

Profiting from negawatts: Reducing absolute consumption and emissions through a performance-based energy economy

Current energy and GHG emissions policies either focus directly on emissions or promote renewable production and the implementation of specific efficiency measures. Meanwhile, the fundamental structure of the energy market based on profits through energy throughput remains largely unchallenged. This policy oversight prevents the transition to an energy economy in which profits are based on energy services delivered at the lowest energy cost: a performance-based energy economy (PBEE). The PBEE applies the combined concepts of the performance economy and energy services to the energy sector. Energy Service Companies (ESCOs) are discussed as an example of PBEE practices. The implications for energy suppliers and consumers as well as the conditions for PBEE diffusion and consequences for technological change are also explored. The expected environmental, social and economic benefits are described. However, absolute consumption and emissions reductions may prove elusive due to the rebound effect. In order to forestall rebound-led increases, complementary policy measures likely to lead to absolute reductions are required.     

Impairment of probabilistic reward-based learning in schizophrenia.

Recent models assume that some symptoms of schizophrenia originate from defective reward processing mechanisms. Understanding the precise nature of reward-based learning impairments might thus make an important contribution to the understanding of schizophrenia and the development of treatment strategies. The present study investigated several features of probabilistic reward-based stimulus association learning, namely the acquisition of initial contingencies, reversal learning, generalization abilities, and the effects of reward magnitude. Compared to healthy controls, individuals with schizophrenia exhibited attenuated overall performance during acquisition, whereas learning rates across blocks were similar to the rates of controls. On the group level, persons with schizophrenia were, however, unable to learn the reversal of the initial reward contingencies. Exploratory analysis of only the subgroup of individuals with schizophrenia who showed significant learning during acquisition yielded deficits in reversal learning with low reward magnitudes only. There was further evidence of a mild generalization impairment of the persons with schizophrenia in an acquired equivalence task. In summary, although there was evidence of intact basic processing of reward magnitudes, individuals with schizophrenia were impaired at using this feedback for the adaptive guidance of behavior. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Coping mediates the relationship between posttraumatic stress disorder (PTSD) symptoms and alcohol use in homeless, ethnically diverse women: A preliminary study.

Homeless women are at increased risk for problematic alcohol use and posttraumatic stress disorder (PTSD). While coping motives have been shown to mediate the relationship between PTSD symptoms and alcohol problems in victims of sexual assault and domestic violence, it is unknown whether this relationship is evident in other trauma-exposed populations. The focus of this study was to examine whether drinking to cope mediated the relationship between PTSD symptoms and current alcohol use in a group of homeless, ethnically diverse women. Twenty-three women were recruited from local shelters in a southwestern community and asked to complete measures assessing their current alcohol use, drinking motives, and PTSD symptoms. Results revealed that drinking to cope mediated the relationship between PTSD symptoms and current alcohol use. This finding supports the theory that homeless women may benefit from treatment interventions that address both their substance use and trauma issues. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Planned tournament selection

Tournament selection is a versatile method of selection and replacement used in evolutionary computation. Normally tournaments are chosen uniformly at random. This study demonstrates the effectiveness of planning tournaments in advance to control information flow within a population being evolved for optimization. Tests are performed on a variety of evolutionary test problems, finding that different planned tournament schemes yield significant differences in performance. The correct type of planned tournament is found to be problem dependent. In addition to a linear-function scheme for planning tournaments, this study also introduces a technique called multi-deme planned tournaments selection which permits simpler cases of a problem to be automatically used to reduce the time required to solve more complex cases.     

Effects of enzymatic hydrolysis on lentil allergenicity

Enzymatic hydrolysis and further processing are commonly used to produce hypoallergenic dietary products derived from different protein sources, such as cow's milk. Lentils and chickpeas seem to be an important cause of IgE‐mediated hypersensitivity in the Mediterranean area and India. Some studies have investigated the effects of enzymatic treatments on the in vitro immunological reactivity of members of the Leguminosae family, such as soybean, chickpea, lentil, and lupine. Nevertheless, there are only a few studies carried out to evaluate the effect on IgE reactivity of these food‐hydrolysis products with sera from patients with well‐documented allergy to these foods. In this study, lentil protein extract was hydrolyzed by sequential action of an endoprotease (Alcalase) and an exoprotease (Flavourzyme). Immunoreactivity to raw and hydrolyzed lentil extract was evaluated by means of IgE immunoblotting and ELISA using sera from five patients with clinical allergy to lentil. The results indicated that sequential hydrolysis of lentil results in an important proteolytic destruction of IgE‐binding epitopes shown by in vitro experiments. However, some allergenic proteins were still detected by sera from four out of five patients in the last step of sequential hydrolyzation.     

The contribution of urban green spaces to the improvement of environment in cities: Case study of Chania,Greece

This paper investigates how vegetation, mainly through evapotranspiration, affects the improvement of microclimatic conditions in urban areas and, more specifically, it examines the case for the city of Chania in Crete. The objectives of this study are to examine the bioclimatic role of green areas in urban sites as they affect the thermal comfort of residents, and to study the cross-correlation of factors that participate in this process.     

Synthesis, characterization, and evaluation of lubrication properties of composites of ordered mesoporous carbons and luminescent CePO4:Tb nanocrystals

Having new potential applications in forging processes in mind, composites of an ordered mesoporous carbon and luminescent metal phosphate nanocrystals were synthesized for the first time. Three kinds of CMK-3/CePO₄:Tb nanocomposites were prepared by treating a mesoporous CMK-3 host with different lanthanide phosphate precursor solutions. Characterization of the obtained nanocomposites by small-angle X-ray scattering, wide-angle X-ray diffraction, transmission electron microscopy, thermogravimetry, and nitrogen physisorption analysis showed that in two cases, the nanocrystals (ca. 2–3 nm in size) were located inside the mesopores, whereas in the third case the nanocystals (ca. 6 nm in size) merely adhered to the outer surfaces of the carbon particles. The CMK-3 and the two nanocomposites had ordered hexagonal structures (space group p6mm); all the materials possessed amorphous carbon walls. After combustion of the nanocomposites, the residues upon excitation with UV light exhibited the typical green luminescence of Tb³⁺. A preliminary evaluation of the lubrication properties of the CMK-3 and one nanocomposite material was performed. The friction factors determined by means of ring upsetting tests revealed that the carbon materials were able to lower frictional forces although they were 3–4 times less efficient than a commercial graphite-based reference lubricant.