Foamed Propellants

Foamed propellants based on polymer bonded nitramines show high conversion rates due to their porous structure. The properties of the material can be varied in a wide range by using different explosive fillers, energetic binders and porous structures. Foamed propellants with high energy content and variable burning and material characteristics can be formulated. Due to this flexibility, these propellants can be adjusted to manifold applications. The burning characteristics of these porous charges show specific differences compared to standard gun propellants, e.g. the mass conversion rates are essentially above those obtained by combustion of compact materials. In addition, the burning behavior of foamed propellants depending on pressure deviates from that expected by a straightforward use of Vieille's law. This paper presents an overview on investigations carried out in the field of foamed propellants at Fraunhofer ICT concerning thermodynamical calculations, studies on burning behavior and vulnerability.     

A Scale‐Transparent Reaction Calorimetric Assay For Rapid Catalyst Selection

The use of reaction calorimetry in a “one‐pot” catalyst screening protocol provides a rapid route to a scale‐transparent picture of catalyst activity when the target reaction is known, the field of catalyst candidates is finite and focused, and the results must be translated efficiently to larger scale reactions. The method is demonstrated for both homogeneous and heterogeneous multi‐phase catalytic reactions of interest in the pharmaceutical industry.     

Physico-chemical characterization of walnut shell biochar from uncontrolled pyrolysis in a garden oven and surface modification by ex-situ chemical magnetization

The shells of walnuts (WS) are major refuse in the global fruits and nuts trade. This, otherwise discarded, lignin-rich material can be carbonized to biochar—a value-added product with environmental applications such as carbon sequestration, soil amelioration, and pollutant adsorption. These applications are dictated by structural and chemical characteristics of the biochar carbon. Conventional controlled pyrolysis (CPy) of biomass is cost-intensive and technically too complex for widespread adoption, especially in emerging economies. Here, walnut shell biochar (BWS0) is derived through uncontrolled pyrolysis (UCPy) in a pyrolysis oven and further hybridized as magnetic biochar through ex-situ chemical co-precipitation. The physico-chemical characteristics of biochar and its water-extractable fractions are comprehensively investigated to understand their carbon structure and environmental applicability. The sp² amorphous carbon sequestered in BWS0 is 0.84 kg_CO2/kg_biomass with a BET (N₂) surface area of 292 m²/g and is comparable to biochar from CPy in terms of carbon structure. The polyaromatic hydrocarbons present are only trace amounts of naphthalene, biphenyl, and phenanthrene. The magnetization decreases porosity of BWS0 while greatly facilitating its separation from aqueous media. BWS0 is suitable for adsorption of cations (between pH 2.8 and 9.45) and hydrophobic pollutants with only 19 mg L⁻¹ fouling from their intrinsic dissolved organic carbon. In combination with fast-release N, P fertilizers, BWS0 (C/N of 24.8) is suitable for application in hydrophilic soils at higher loading rates. The results suggest an avenue where WS biochar can also be prepared via UCPy for direct environmental applications. Future investigations into soil incubation and adsorption tests are recommended.

Graphical abstract

     

Die Wupper‐Talbrücke Oehde – eine moderne Verbundbrücke

The Wupper River valley bridge – a state‐of‐the‐art composite bridge. The German motorway Autobahn A 1 is one of the nation's most important and frequently traveled highways, connecting the country's northern and southern regions. The road currently has two lanes in each direction, which do not provide enough capacity to carry the traffic volume without daily traffic jams and heavy delays. Therefore, the federal government and the Northrhine‐Westfalia Department of Transportation decided to ease the situation by adding one lane in each direction. This total of 6 lanes fits into the master plan of widening major highways around the Ruhr River region. North of Cologne, the Autobahn A 1 crosses mountainous terrain, so several bridges with total lengths between 240 and 420 meters have had to be widened, replaced, or, most commonly, supplemented by a new bridge. Such supplementation was used on the Wupper River Valley Bridge, called Oehde, close to the city of Wuppertal. The bridge illustrates an example of modern composite bridges adopting new methods in construction and design, and also marks an outstanding example of current composite structures in Germany.