Modelling induction skull melting design modifications

Induction Skull Melting (ISM) is used for heating, melting, mixing and, possibly, evaporating reactive liquid metals at high temperatures when a minimum contact at solid walls is required. The numerical model presented here involves the complete time dependent process analysis based on the coupled electromagnetic, temperature and turbulent velocity fields during the melting and liquid shape changes. The simulation is validated against measurements of liquid metal height, temperature and heat losses in a commercial size ISM furnace. The often observed limiting temperature plateau for ever increasing electrical power input is explained by the turbulent convective heat losses. Various methods to increase the superheat within the liquid melt, the process energy efficiency and stability are proposed.     

Electrophoretic deposition of monochrome and color phosphor screens for information displays

This paper reviews our research on the electrophoretic deposition (EPD) of phosphors for the processing of monochromatic and color screens for information displays. Our investigation began with the study of the fundamentals of the EPD process for phosphors. The processing variables which enhance the adhesion strength of phosphor deposits were determined. The optical performance of phosphors deposited by EPD was shown to be not affected by the process itself nor by the conditions which enhance phosphor adhesion. Processes developed to produce high-resolution color screens by combining EPD and photolithography techniques are described. Also, a method to electrophoretically deposit phosphor in a thermo-reversible gel from mixtures of poly(butyl methacrylate) and isopropanol was examined.     

Synthesis and Properties of NdMCr2O5 (M = Na, K, Cs) and NdMgCr2O5.5 Chromites

NdMCr₂O₅ (M = Na, K, Cs) and NdMgCr₂O_5.5 are prepared by solid-state reactions between appropriate oxides and carbonates and are shown to have a tetragonal structure. The heat capacity of these chromites, measured from 298.15 to 673 K, exhibits sharp changes attributable to second-order phase transitions. The C _p ⁰(T) data are represented by quadratic best fit equations. The electrical resistivity of the chromites is measured between 303 and 493 K. The results attest to semiconducting behavior of the materials in certain temperature ranges.     

Salt-water up-coning during extraction of fresh water from a tropical island

Rainwater can collect in a lens-shaped region within the rock of a tropical island, and may be separated from the underlying salt water by a sharp interface. This paper presents a nonlinear theory for determining the shape of this interface. The island is assumed to be saturated with rain, and provision is made for the outflow of rain-water through the sides of the island. The effect of a bore well on the shape of the interface is investigated, and the problem is solved using a spectral method. An integral-equation method is also presented for the case when the island has infinite width.     

A comparative study of the gas sensing behavior of nanostructured nickel ferrite synthesized by hydrothermal and reverse micelle techniques

A comparative study of gas sensing behavior of nanocrystalline nickel ferrite synthesized by micro-emulsion and hydrothermal method to liquefied petroleum gas (LPG) is presented. Nanocrystalline nickel ferrite synthesized by hydrothermal method indicated higher electrical conductivity and gas sensitivity at low operating temperature compared to nanocrystalline nickel ferrite synthesized by reverse micelle technique. This difference in the gas sensing behavior can be attributed to the presence of more oxygen vacancies (i.e. non-stoichiometry) in the hydrothermally synthesized nickel ferrite. Incorporation of palladium had a catalytic effect and the operating temperature was significantly reduced in both the samples. The higher operating temperature of the reverse micelle nickel ferrite material makes the sensor response speed faster (∼10 s) compared to the hydrothermally synthesized material (∼1 min).     

Synthesis of LiFePO4 with fine particle by co-precipitation method

LiFePO₄ is a potential candidate for the cathode material of the lithium secondary batteries. A co-precipitation method was adopted to prepare LiFePO₄ because it is simple and cheap. Nitrogen gas was needed to prevent oxidation of Fe²⁺ in the aqueous solution. The co-precipitated precursor shows the high reactivity with the reductive gas, and the single phase of LiFePO₄ is successfully synthesized with the aid of carbon under less reductive conditions. LiFePO₄ fine powder prepared by co-precipitation method shows high rate capability, impressive specific capacity and cycle property.     

On the role of high-energy electrons in the formation of a plasma-beam discharge structure in a diode with a slit cathode

The spatial structure of visible emission from plasma of a transverse nanosecond pulsed electric discharge in a gas-filled diode with a hollow (slit) cathode has been experimentally studied. A relation is established between the regime of electron energy relaxation and the plasma-beam discharge structure formation. High values of the electron emission coefficient are observed in the experiment, which cannot be explained using the notion of electron emission from a cathode bombarded by fast heavy particles.     

Increasing the efficiency of metal-air current sources operating in a pulse-train mode

A considerable (～1.4-fold) increase in the average output power of a chemical current source has been achieved by means of a periodic pulsed manipulation of the load. A scheme used for the pulse-train loading is presented and mechanisms ensuring an increase in the average output power of the current source are considered.