Kinetic model of anodic oxidation of titanium in sulphuric acid

A kinetic model for the galvanostatic oxidation of titanium is proposed and compared with experimental results. The kinetic model takes account of the oxidation of titanium, the incorporation process, the evolution of oxygen, the avalanche process, the dissolution of titanium oxide and the capacitance effect of the double layer. The results indicate that the dissolution rate of titanium oxide is negligible and that the rate of oxygen evolution plays an important role in the anodic oxidation. The kinetic model is developed further for the following three special cases: Case 1: when the anodization time approaches zero

Cost benefits from standardization of the packaging glass bottles

This study deals with a recycling system with two competing brewers. It is assumed that they coordinate their manufacturing operations through standardization of their glass bottles for easy implementation of extended producer responsibility (EPR). Immediate benefits from the standardization are three folds. Firstly, the sorting and exchange processes of the bottles collected for reuse by each brewer become no longer necessary. Secondly, cost reduction is achieved through streamlining of collection and reuse processes. Finally, under the stochastic demand of glass bottles their inventory holding costs and lost sales cost are reduced via inventory pooling. Through the development of the mathematical models we determine an optimal operation policy of the two brewers that maximizes the sum of benefits obtained from standardization. Numerical examples are solved to show the validity of the model. Sensitivity tests are also performed to examine the effects of system parameters on the objective function value and decision variables.     

Analysis of the false-positive error rate of tagged fragment marking scheme

IP traceback is an effective measure to deter internet attacks. A number of techniques have been suggested to realize IP traceback. The Fragment Marking Scheme (FMS) is one of the most promising techniques. However, it suffers a combinatorial explosion when computing the attacker?s location in the presence of multiple attack paths. The Tagged Fragment Marking Scheme (TFMS) has been suggested to suppress the combinatorial explosion by attaching a tag to each IP fragment. Tagging is effective because it allows the victim to differentiate IP fragments belonging to different routers, thereby greatly reducing the search space and finding the correct IP fragments. TFMS, however, increases the number of false positives when the number of routers on the attack path grows beyond some threshold. In this paper, we rigorously analyze the performance of TFMS to determine the correlation between the number of routers and the false positive error rate. Using a probabilistic argument, we determine the formulas for combination counts and error probabilities in terms of the number of routers. Under TFMS, our results show that we can reduce the required time to find an attacker?s location at the cost of a low error rate for a moderate number of routers.     

The effect of grain size and retained austenite on the ductile-brittle transition of a titanium-gettered iron alloy

The effect of microstructural changes on the ductile-brittle transition temperature (DBTT) was studied in a titanium-getter ed Fe-8Ni-2 Mn-0.15 Ti alloy. A fairly strong grain size dependence of the transition temperature, 8°C/mm^?1/2, was found. Grain size refinement from 38 μm (ASTM #6.5) to 1.5 μm (ASTM #15.5) through a four-step thermal treatment lowered the transition temperature by 162°C. A small amount of retained austenite was introduced into this grain-refined microstructure, and the transition temperature was reduced by an additional 120 ~ 150°C. The reduction of the DBTT due to retained austenite was smaller when the austenite was in a large-grained structure (64°C). The distribution and stability of retained austenite were also studied.     

Dynamic deformation behavior of ultrafine-grained low-carbon steels fabricated by equal-channel angular pressing

The dynamic deformation behavior of ultrafine-grained low-carbon steels fabricated by equal-channel angular pressing (ECAP) was investigated in this study. Dynamic torsional tests, using a torsional Kolsky bar, were conducted on four steel specimens, two of which were annealed at 480 °C after ECAP, and then the test data were compared in terms of microstructures, tensile properties, and adiabatic shear-band formation. The equal-channel angular pressed specimen consisted of very fine, equiaxed grains of 0.2 to 0.3 μm in size, which were slightly coarsened after annealing. The dynamic torsional test results indicated that maximum shear stress decreased with increasing annealing time, whereas fracture shear strain increased. Some adiabatic shear bands were observed at the gage center of the dynamically deformed torsional specimen. Their width was smaller in the equal-channel angular pressed specimen than in the 1-hour-annealed specimen, but they were not found in the 24-hour-annealed specimen. Ultrafine, equiaxed grains of 0.05 to 0.2 μm in size were formed inside the adiabatic shear band, and their boundaries had characteristics of high-angle grain boundaries. These phenomena were explained by dynamic recrystallization due to a highly localized plastic strain and temperature rise during dynamic deformation.     

Factors Affecting Hydrogen Production from Food Wastes by Clostridium-Rich Composts

This study used the technique of response surface approach to analyze the combined effects of heat-shocking temperature and time on anaerobic grass composts. Results indicate that the grass composts under heat-shocking temperature and time of 80°C and 3?h, respectively, could yield high populations of hydrogen-producing microorganisms. Metabolic results demonstrate that the composts are reliable, having considerable hydrogen-producing Clostridia. The multivariate analysis with response surface by considering specific hydrogen-producing potential and rate simultaneously indicate that the cultural media with Fe2+ = 132?mg/L; NH4+ = 537?mg/L; and PO43? = 1,331?mg/L were optimal for the hydrogen-producing Clostridia-rich composts using high-solids food wastes. The specific hydrogen production potential and rate were 77±3?mL?H2/gTVS and 520±20?mL?H2/g?TVS/day, respectively. The former was 38% of theoretical hydrogen-producing potential of Clostridium sp. using glucose. Of these factors, ammonium and phosphate are nutrients for the hydrogen-producing Clostridia growth while iron exerts a synergistic influence on them in the conversion of the food wastes into hydrogen.     

Leak behavior of SCC degraded steam generator tubings of nuclear power plant

A forced outage due to a steam generator tube leak in a Korean nuclear power plant has been reported [Kim, J.S., Hwang, S.S., et al., 1999. KAERI Internal Report (Korean). Destructive analysis on pulled tubes from Ulchin unit 1. Korea Atomic Energy Research Institute]. Primary water stress corrosion cracking has occurred in many tubes in the plant, and they were repaired using sleeves or plugs. In order to develop proper repair criteria, it is necessary to understand the leak behavior of the tubes containing stress corrosion cracks. Cracked specimens were prepared using a room temperature cracking technique, and the leak rates and burst pressures of the degraded tubes were determined both at room temperature and at a high temperature. Some tubes with 100% through wall cracks did not show a leakage at 10.8 MPa, which is the typical pressure difference of the pressurized water reactors (PWRs) during a normal operation. In some tests, the leak rates of the tubes increased with time at a constant pressure. In a high temperature pressure test at 282 °C one specimen showed a very small leakage at 18.6 MPa, which stopped after a small increase in the test pressure. Because stress corrosion cracks can develop at relatively low stresses, even 100% through wall cracks can be so tight that they will not leak at a normal operating pressure.     

Multiscale Analysis of Fracture of Carbon Nanotubes Embedded in Composites

Due to the enormous difference in the scales involved in correlating the macroscopic properties with the micro- and nano-physical mechanisms of carbon nanotube-reinforced composites, multiscale mechanics analysis is of considerable interest. A hybrid atomistic/continuum mechanics method is established in the present paper to study the deformation and fracture behaviors of carbon nanotubes (CNTs) in composites. The unit cell containing a CNT embedded in a matrix is divided in three regions, which are simulated by the atomic-potential method, the continuum method based on the modified Cauchy–Born rule, and the classical continuum mechanics, respectively. The effect of CNT interaction is taken into account via the Mori–Tanaka effective field method of micromechanics. This method not only can predict the formation of Stone–Wales (5-7-7-5) defects, but also simulate the subsequent deformation and fracture process of CNTs. It is found that the critical strain of defect nucleation in a CNT is sensitive to its chiral angle but not to its diameter. The critical strain of Stone–Wales defect formation of zigzag CNTs is nearly twice that of armchair CNTs. Due to the constraint effect of matrix, the CNTs embedded in a composite are easier to fracture in comparison with those not embedded. With the increase in the Young’s modulus of the matrix, the critical breaking strain of CNTs decreases.