亚临界和超临界状态下甲苯-多环芳香烃体系的气液相平衡

The phase behaviors of toluene/polycyclic aromatic hydrocarbon mixture systems were investigated with a continuous-flow type apparatus at 573.2,598.2.623.2 and 648.2K,while the pressure changed from 1 tp 5 MPa,The pseudo-binary phase behaviors were predicted with the Peng-Robinson equation of state with interaction parameters between toluene and pseudo-components considered.The phase diagrams of the system have been classified following the category of phase boundary diagram models.The extraction selectivity and efficiency of toluene as a solvent was discussed by comparing with that of hexane .The prediction model for selectivity was also suggested.     

A Direct Test for Cointegration Between a Pair of Time Series

In this paper we introduce a new test of the null hypothesis of no cointegration between a pair of time series. For a very simple generating model, our test compares favourably with the Engle–Granger/Dickey–Fuller test and the Johansen trace test. Indeed, shortcomings of the former motivated the development of our test. The applicability of our test is extended to series generated by low-order vector autoregressions. Again, we find evidence that this general version of our test is more powerful than the Johansen test. The paper concludes with an empirical example in which the new test finds strong evidence of cointegration, but the Johansen test does not.     

污泥厌氧消化过程中沼气原位提纯扩产技术的研究进展

目前,厌氧消化处是污泥减量化、无害化、资源化处理最有效的手段之一,沼气作为厌氧消化资源化产物,产量和纯度的原位提升技术有着重要的作用。文章从厌氧消化产沼气量影响因素和沼气原位富集技术的角度阐述沼气产量和纯度的提高的研究方法,从而对中国市政污泥处理和沼气能源化利用领域提供有价值的参考。     

Evaluation of microstructure and mechanical properties of Mg-xCe-0.5Zn alloys by nano-indentation

The microstructure and mechanical properties of Mg-xCe-0.5Zn(x=0.5,1.5,2.5,molar fraction,%) alloys were examined using a nano-indentation technique.The alloys were fabricated using a vacuum induction melting method under an argon atmosphere. The microstructures of Mg-xCe-0.5Zn alloys mainly consist ofα-Mg and eutectic Mg12Ce phase.The volume fraction and size of the eutectic Mg12Ce phase increase with increasing Ce contents.Nano-indentation test results show that the indentation hardness and elastic modulus of the eutectic Mg12Ce phase are higher than those of theα-Mg matrix.In addition,the mean indentation hardness and elastic modulus of the Mg-xCe-0.5Zn alloys increase with the Ce addition amount increasing.     

Effect of substrate bias on microstructure and tribological performance of GLC films using hybrid HIPIMS technique

The Cr-doped hydrogen-GLC films were prepared by a hybrid magnetron sputtering system composed of a direct current magnetron sputtering (DC-MS) source of carbon and a high power impulse magnetron sputtering (HIPIMS) source of Cr with reactive gas of C2H2.The hydrogen-free GLC and Cr-doped GLC films were also prepared for comparison.The influence of substrate bias on the Cr-doped hydrogen-GLC films was investigated.With the increase of substrate bias from 100 V to 250 V,the re-sputtering of weak bonding sp2 firstly occurred and induced an increased sp3 bonding.However,the following sp3 to sp2 transformation resulted in a decreased sp3 bonding.The change trends of surface roughness and friction coefficient with the increased bias voltages were the same as those of sp3 bond.The lowest surface roughness and lowest friction coefficient corresponded to the highest sp3 with the Cr-GLC-H films at the bias voltage of-100 V.     

Weldability evaluation and tensile strength estimation model for aluminum alloy lap joint welding using hybrid system with laser and scanner head

Aluminum welding using a hybrid system with a laser and scanner welding head was performed under various welding conditions to verify the feasibility of applying an aluminum alloy to a car body.The experimental material was 5J32 aluminum alloy,and the laser power,welding speed,and laser incidence angle were used as the control variables.The weld bead shape and the tensile shear strength were evaluated in order to understand the aluminum lap joint weld characteristics.Analysis of variance (ANOVA) was conducted to identify the effect of the process variables on the tensile shear strength.Tensile strength estimation models using three different regression models were also suggested.The input variables were the laser power,welding speed,and laser incidence angle,and the output was the tensile shear strength.Among the models,the second-order polynomial estimation model had the best estimation performance,and the average error rate of this model was 0.058.     

Effect of pulse time on surface characteristics and corrosion resistance during pulse electrochemical polishing

Pulse electrochemical polishing (PECP) was used to improve the mechanical properties,such as surface roughness and corrosion resistance,of conductive metallic materials.PECP can provide a smooth,bright,reflective,and deburred surface that exhibits superior corrosion resistance.In this work,stainless steel was used as the anode,and copper was used as the cathode due to their low electrical resistances.The surface roughness of the PECP sample was measured by atomic force microscopy (AFM).A scanning electron microscope (SEM) was used to observe surface characteristics,and an Auger electron spectroscope (AES) was used to analyze the metallurgical composition and thickness of the passive film.The aim of this research was to compare the corrosion resistance rates of the unprocessed and PECP-processed stainless steel.     

Friction stir butt welding of A5052-O aluminum alloy plates

Friction stir butt welding (FSW) between A5052-O aluminum alloy plates with a thickness of 2 mm was performed.The rotation speeds of the welding tool were 2000 and 3000 r/min,respectively.The traverse speed was ranged from 100 mm/min to 900 mm/min.The defect-free welds with the very smooth surface morphology were successfully obtained,except for at the welding condition of 3000 r/min and 100 mm/min.The onion ring structure was observed in the friction-stir-welded zone (SZ) at the condition of 2000 r/min and 100 mm/min.For all the welding conditions,the grain size of the SZ was smaller than that of the base metal,and was decreased with the decrease of the tool rotation speed and with the increase of the tool traverse speed.The stir zone exhibited higher average hardness than the base metal.The decrease of the tool rotation speed and the increase of the tool traverse speed resulted in the increase in the average hardness of the SZ.The tensile strength of the FSWed plates was similar to that of the base metal,except for at the welding condition of 3000 r/min and 100 mm/min.The total elongation of the FSWed plates was lower than that of the base metal.     

Influence of substrate bias on microstructure and morphology of ZrN thin films deposited by arc ion plating

Zirconium nitride thin films were fabricated using arc ion plating under negative substrate biases to investigate the influence of substrate bias on the ZrN films. The phase, composition, and surface morphology of the ZrN ?lms, with respect to substrate bias, were studied by XRD, EPMA, and FE-SEM, respectively. The results show that cubic ZrN and hexagonal Zr phases form in the ZrN films. The competition between surface energy and strain energy makes the preferred orientation change from (111) to (200) and then back to highly (111) preferred orientation as a function of substrate bias. With the increase of bias voltage, the crystallite size of ZrN films reduces from 30 to 15 nm. Meanwhile, the film microstructure evolves from an apparent columnar structure to a highly dense equiaxed structure, indicating that the ion bombardment enhanced by substrate bias can suppress the columnar growth in the ZrN films. Deposition rate and mole ratio of Zr to N increase with the increase of bias voltage and reach the maximum at –50 V, and then show a decline trend when bias voltage further increases.