$$\hbox {NO}_{2}^{-}$$ and $$\hbox {SCN}^{-}$$SCN--intercalated layered double hydroxides: structure and orientation of anions in the interlayer gallery

\(\hbox {NO}_{2}^{-}\) and \(\hbox {SCN}^{-}\) are two common small inorganic anions. The former is a common industrial pollutant. The latter is linear and is a good mimic for the toxic \(\hbox {CN}^{-}\) ion. The structures of these two anions are refined within the gallery of the [Zn–Al]-layered double hydroxide (LDH). Both LDHs crystallize as mixed anion phases. The nitrite is found to co-exist with the nitrate ion. The nitrite ion is intercalated with its molecular plane inclined to the metal hydroxide layer. In the case of the \(\hbox {SCN}^{-}\) intercalated LDH, no other anion was detected by ion chromatography, suggesting that the \(\hbox {SCN}^{-}\) deficiency is compensated by intercalated hydroxyl ions. In this case, the \(\hbox {SCN}^{-}\) ion is found to be intercalated with its molecular axis inclined to the metal hydroxide layer.     

Kiln-fired clay bricks synergizing nickel–chromium plating sludge and fly ash: mechanical characteristics and cradle-to-gate life cycle assessment

Clean Technologies and Environmental Policy - Life cycle assessment (LCA) of novel fired clay bricks with synergistic co-valorization of nickel-chrome plating sludge (NCPS) and fly ash (FA) is...