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61.
Several novel R5T1?x{Sb,Bi}2+x phases having the Yb5Sb3-type structure (space group Pnma) have been synthesized. The cell parameters are: a = 1.20668(9), b = 0.88396(7), c = 0.78745(7) nm for Y5CoSb2; a = 1.19939(7), b = 0.88364(5), c = 0.78283(5) nm for Dy5CoSb2; a = 1.19633(8), b = 0.89231(6), c = 0.78450(6) nm for Ho5RhSb2; a = 1.18650(6), b = 0.90455(4), c = 0.79260(4) nm for Ho5PdSb2; a = 1.2215(3), b = 0.8948(2), c = 0.7977(2) nm for Y5CoBi2; a = 1.1781(8), b = 0.9071(7), c = 0.7936(6) nm for Tm5Co0.5Bi2.5; a = 1.1972(1), b = 0.92096(9), c = 0.80048(9) nm for Ho5RuBi2; a = 1.2082(1), b = 0.90346(9), c = 0.79413(8) nm for Ho5RhBi2 and a = 1.20374(5), b = 0.91076(4), c = 0.80135(4) nm for Ho5PdBi2, respectively. Magnetization measurements indicate ferromagnetic transitions for Dy5CoBi2, Ho5RhSb2, Ho5RhBi2, Ho5PdSb2 and Ho5PdBi2 at TC = 34, 38, 28, 42 and 38 K, respectively. The Ho5RhSb2 and Ho5PdBi2 compounds show additional magnetic transitions at about 18 K, probably associated with a spin reorientation. The magnetocaloric effect of Dy5CoBi2 in terms of the isothermal entropy change, ΔSm, is ?6.2 J/(kg/K) at 38 K and in terms of the adiabatic temperature change, ΔTad, is 2.2 K for a 5 T field change. 相似文献
62.
Vijay K. Tomer Surender Duhan Ritu Malik Satya P. Nehra Sunita Devi 《Journal of the American Ceramic Society》2015,98(12):3719-3725
This work deals with the study of hydrothermally synthesized zinc oxide (ZnO) loaded mesoporous SBA‐15 hybrid nanocomposite for relative humidity sensing (RH) at room temperature. The sensor exhibits an excellent ~5 orders impedance change along with excellent linearity, quick response time (17 s), rapid recovery time (18 s), negligible hysteresis (1.2%), good repeatability, and stability (1.8%) in 11%–98% RH range. In addition, complex impedance spectra of the sensor at different RHs were analyzed to understand the humidity sensing mechanism. Our study can open a new way for realizing ZnO/SBA‐15 hybrid nanocomposite for fabrication of high‐performance RH sensors. 相似文献
63.
N‐halamine‐modified polyglycolide (PGA) multifilament as a potential bactericidal surgical suture: In vitro study
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In this study, new cationic homopolymer and anionic copolymer were synthesized, and deposited onto polyglycolide sutures using a layer‐by‐layer assembly technique. The coated sutures were rendered antibacterial by chlorinating with dilute solution of household bleach solution at pH 7. The chlorination treatment transformed the N? H groups of anionic copolymer into N‐halamine structures. The N‐halamine‐modified sutures were challenged with Staphylococcus aureus and Escherichia coli O157:H7 bacteria at different contact times. The suture with chlorine loading of 0.22% completely inactivated both bacterial strains in 30 min contact time. Fourier transform infrared spectroscopy, scanning electron microscopy, and analytical titration confirmed the successful deposition of the N‐halamine multilayers. The effect of layer‐by‐layer coatings of polyelectrolytes on the chlorine loading and antibacterial efficacy of sutures was evaluated. The straight‐pull and knot‐pull strength tests performed on the sutures reported slight decline in tensile properties after chlorination treatment. The in vitro hemolysis and cytocompatibility tests revealed that the N‐halamines‐based antibacterial sutures were biocompatible. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42483. 相似文献
64.
Malik Ranasinghe 《Construction Management & Economics》2013,31(5):613-623
Many developing countries are now attempting to finance new infrastructure projects through private sector participation. This paper outlines a methodology based on financial and risk analyses that a government or a government utility can use to analyse the viability of private sector participation in new infrastructure projects. The water supply projects in Sri Lanka are used for the case study to outline the methodology. Financial analyses of a bulk water supply project and a water distribution project are carried out to estimate subsidy percentages that are required to make the projects viable, using a model developed for the investment analysis of all types of infrastructure project. This analysis looks at four pricing options for the bulk supply project, and sixteen procurement options for the distribution project, from the view point of the utility, for three cases of non-revenue water (35% as base case, 50% and 25% as extreme cases). The risk analysis takes into account the risk and uncertainty in non-revenue water, cost and demand estimates, rate of debt and forecasts of escalation. These analyses show that the best option for the utility is to obtain both bulk supply and distribution projects through private sector participation using BOT arrangements. 相似文献
65.
Malik Ranasinghe 《Construction Management & Economics》2013,31(6):497-505
A simplified model for total project cost is developed in this paper to meet the numerous requests from decision makers for a model that can be used to estimate the total project cost from the estimated cash flows and, more importantly, to check the accuracy of the project cost estimates in feasibility studies that require prudent decisions. It begins with a base cost estimate in constant dollars and discrete cash flows with discrete inflation rates as practised by the construction industry. The discrete inflation rates are used to estimate the current dollar costs of the project. The effects of inflation are estimated as escalation during construction. Using the future value concept, interest during construction is estimated, in a simplified approach, to estimate the total project cost. Data from an actual feasibility study is used to highlight the strengths and weaknesses of the simplified model. The model is extended to treat discrete cash flows with continuous inflation rates. 相似文献
66.
This paper investigates three major issues regarding the elicitation of expert knowledge for economic risk analysis: (1) recognition of some of the implicit assumptions and beliefs; (2) development of an approach to elicit expert knowledge as accurate, calibrated and coherent subjective probabilities; and (3)a study to explore human ability to predict future events and the validity of the implicit assumptions and beliefs in the context of the expert judgements. The proposed elicitation approach combines the theoretical requirements for valid subjective probabilities with a practical process. The recognition that some of the implicit assumptions and beliefs in engineering risk analysis should be explored when dealing with the human ability to predict future events, and the inherent difficulties in developing experiments and methods to test such beliefs arc some of the benefits of the study. Directions for future work are suggested. 相似文献
67.
68.
Malik Adeel Umer Dongju Lee Owais Ahmed Waseem Ho Jin Ryu Soon Hyung Hong 《Metals and Materials International》2016,22(3):493-500
SiC reinforced tungsten matrix composites were fabricated via the spark plasma sintering process. In order to prevent an interfacial reaction between the SiC and tungsten during sintering, TiOx coated SiC particles were synthesized by a solution-based process. TiOx layer coated SiC particles were treated in high temperature nitriding conditions or annealed in a high temperature vacuum to form TiN or TiC coated SiC particles, respectively. The TiC layers coated on SiC particles successfully prevented tungsten from reacting with SiC; hence the proposed process resulted in successful fabrication of the SiC/W composites. The mechanical properties such as compressive strength and flexural strength of the composites were measured. Additionally, the effect of SiC on the high temperature oxidative ablation of tungsten was also investigated. The addition of SiC resulted in an improved oxidative ablation resistance of the tungsten-based composites. 相似文献
69.
70.
Surya Prakasarao Chodisetti V. K. Malik B. Venkata Manoj Kumar 《International Journal of Applied Ceramic Technology》2022,19(3):1367-1378
Highly dense electrically conductive silicon carbide (SiC)–(0, 10, 20, and 30 vol%) titanium boride (TiB2) composites with 10 vol% of Y2O3–AlN additives were fabricated at a relatively low temperature of 1800°C by spark plasma sintering in nitrogen atmosphere. Phase analysis of sintered composites reveals suppressed β→α phase transformation due to low sintering temperature, nitride additives, and nitrogen sintering atmosphere. With increase in TiB2 content, hardness increased from 20.6 to 23.7 GPa and fracture toughness increased from 3.6 to 5.5 MPa m1/2. The electrical conductivity increased to a remarkable 2.72 × 103 (Ω cm)–1 for SiC–30 vol% TiB2 composites due to large amount of conductive reinforcement, additive composition, and sintering in nitrogen atmosphere. The successful electrical discharge machining illustrates potential of the sintered SiC–TiB2 composites toward extending the application regime of conventional SiC-based ceramics. 相似文献