Non-Cp type titanium precatalysts for ethylene/norbornene copolymerization

Ethylene/norbornene monomers were homo- as well as copolymerized using titanium-based non-Cp precatalysts [2-(2,6-dialkylphenylamino)-1-phenylethoxy TiCl₂] in the presence of methylaluminoxane. The precatalysts polymerized ethylene with moderate activities that increased with increase in temperature reaching a maximum yield of polyethylene at 70 °C. However, these catalysts showed relatively low activity towards norbornene homopolymerization. Precatalysts 1ATiCl₂ and 3ATiCl₂ were used for ethylene/norbornene copolymerization. The microstructural analysis of these copolymers suggests that these are alternating copolymers with meso (major) and racemic (minor) sequences. Higher norbornene incorporation in the copolymer was obtained with precatalyst 3ATiCl₂, which is a more “open” catalyst system. The reactivity ratios for ethylene/norbornene copolymerization suggest that these precatalysts show lesser tendency towards norbornene homopropagation in the copolymerization reactions.     

Programmable SiGe BiCMOS low-pass filter for a multicarrier WCDMA base-station receiver

SiGe BiCMOS low-pass filter for a multicarrier WCDMA base-station receiver is described in this paper. The 4th-order Chebyshev filter with a 0.1-dB passband ripple is designed to drive a high-resolution A/D converter. The −3-dB frequency of the implemented filter can be programmed to four different bandwidths: 2.5, 5, 7.5, and 10 MHz depending on the number of received WCDMA channels. The filter achieves +9.7-dBV in-band IIP3, +20-dBV out-of-band IIP3, and 8.5-nV/√Hz input-referred noise density with 10-MHz bandwidth. The circuit uses a 2.5 V supply and has been fabricated in a 0.25-μm SiGe BiCMOS process.     

Facile Synthesis of 7-Aryl-benzo[h]tetrazolo[5,1-b]quinazoline-5,6-dione Fused Polycyclic Compounds by Using a Novel Magnetic Polyurethane Catalyst

Novel Brönsted acid functionalized magnetic polymeric nanocomposite, Ba_0.5Sr_0.5Fe₁₂O₁₉@PU-SO₃H, has been successfully synthesized and characterized by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA) techniques. The catalytic activity of the nanocomposite was tested in the regioselective synthesis of 7-aryl-benzo[h]tetrazolo [5,1-b] quinazoline-5,6-diones in an eco-friendly and recyclable media, deep eutectic solvent (DES), based on choline chloride and urea. This novel method offers several advantages, such as high yields, short reaction time, environmentally friendly reaction media, easy isolation of the product, and also offers an easy method for the synthesis of nanocatalysts. The catalyst was readily recycled by the use of an external magnetic field and could be reused 6 times without significant loss of activity or mass. DES as one of the most promising environmentally benign and cost-effective alternatives to conventional ionic liquids and volatile organic solvents was recovered from the aqueous filtrate by evaporating the water under vacuum. The recycled DES was used up to 4 runs without any loss in activity.     

Occupants’ acceptability of zero energy housing in Finland

Based on an extensive Finnish data covering 1350 interviews the authors surveyed the end users’ perceptions concerning improved energy efficiency, renewable energy integration and zero energy housing. The data has wide social coverage and it matches well with both age and gender distribution in Finland. The survey indicates that solar photovoltaic panels and heat pumps are among most familiar renewable energy technologies to the interviewed occupants while the panels also enjoy the most positive image among the interviewees. However, the interviewees’ willingness to pay extra for energy efficient improvements was more munificent than that for the renewable energy installations. Zero energy buildings were only known to roughly half of the interviewees while 48.9% of the respondents did not even know whether there is an energy performance certificate for their house or not.     

冲击干燥提高效率和产能

对美卓造纸机械的冲击干燥装置进行了简述。将冲击干燥与传统干燥的蒸发效率进行了比较,对比结果表明了冲击干燥装置的优越性。     

Simplifying the role of signals in tile self-assembly

Natural Computing - Sending signals through DNA-based structures is one of the methods used to enhance the capabilities of DNA self-assembly systems. Signal Tile Assembly Models at temperature one,...     

Quantitative analysis of sperm rheotaxis using a microfluidic device

Quite puzzling issue in biology is how sperm cells are selected naturally where human sperm has to maintain a correct swimming behavior during the various stages of reproduction process. In nature, sperm has to compete a long journey from cervix to oocyte to stand a chance for fertilization. Although various guidance mechanisms such as chemical and thermal gradients are proposed previously, these mechanisms may only be relevant as sperm reaches very close to the oocyte. Rheotaxis, a phenomenon where sperm cells swim against the flow direction, is possibly the long-range sperm guidance mechanism for successful fertilization. A little is known quantitatively about how flow shear effects may help guide human sperm cells over long distances. Here, we have developed microfluidic devices to quantitatively investigate sperm rheotaxis at various physiological flow conditions. We observed that at certain flow rates sperm actively orient and swim against the flow. Sperm that exhibit positive rheotaxis show better motility and velocity than the control (no-flow condition), however, rheotaxis does not select sperm based on hyaluronic acid (HA) binding potential and morphology. Morphology and HA binding potential may not be a significant factor in sperm transport in natural sperm selection.     

A 0.18$$\upmu$$m CMOS voltage multiplier arrangement for RF energy harvesting

This work presents a two-stage voltage multiplier (VM) useful in RF energy harvesting based applications. The proposed circuit is based on the conventional differential drive rectifier, in which the input RF signal has been level shifted using a simple arrangement. This signal is then used to drive the next stage, which has been formed by using gate cross-coupled transistors. As a result, the load driving capability of the proposed architecture increases. The load in this work has been emulated in terms of a parallel RC circuit. The architecture has been implemented using standard 0.18 \(\mu\)m CMOS technology. The measurements of the two-stage conventional VM (CVM) and proposed VM circuits were performed at ISM frequencies 13.56, 433, 915 MHz and 2.4 GHz for R\(_L\) of values 1, 5, 10, 3 and 100 K\(\Omega\) with a fixed value of C\(_L\) equal to 20 pF. The performance evaluation has been done in terms of the power conversion efficiency (PCE) and average output DC voltage. The measured results show an improvement in PCE of 5% (minimum) for 13.56, 433 and 915 MHz frequencies, and up to 2% improvement for a frequency value of 2.4 GHz at the targeted load condition of 5 K\(\Omega ||\)20 pF, when compared with the measured results of the CVM circuit.