Glass-fibre-reinforced composites with enhanced mechanical and electrical properties - Benefits and limitations of a nanoparticle modified matrix

Nanoparticles and especially carbon nanotubes (CNTs) provide a high potential for the modification of polymers. They are very effective fillers regarding mechanical properties, especially toughness. Furthermore, they allow the implication of functional properties, which are connected to their electrical conductivity, into polymeric matrices. In the present paper, different nanoparticles, as fumed silica and carbon black, were used to optimise the epoxy matrix system of a glass-fibre-reinforced composite. Their nanometre-size enables their application as particle-reinforcement in FRPs produced by the resin-transfer-moulding method (RTM), without being filtered by the glass-fibre bundles. Additionally, an electrical field was applied during curing, in order to enhance orientation of the nanofillers in z-direction. The interlaminar shear strengths of the nanoparticle modified composites were significantly improved (+16%) by adding only 0.3 wt.% of CNTs. The interlaminar toughness G_Ic and G_IIc was not affected in a comparable manner. The laminates containing carbon nanotubes exhibited a relatively high electrical conductivity at very low filler contents, which allows the implication of functional properties, such as stress-strain monitoring and damage detection.     

Physical attractiveness and health: Comment on Weeden and Sabini (2005).

Evolutionary behavioral biology suggests that certain characteristics of the human face and body are important for mate preferences and are therefore subject to sexual selection. J. Weeden and J. Sabini (see record 2005-11504-001) identify a number of weaknesses in the association between traits' attractiveness and health. In contrast, the authors argue that (a) studies on preferences for physical characteristics that rely on 1 trait permit only limited interpretation, (b) limitations placed on J. Weeden and J. Sabini's review exclude important associations, (c) there are misconceptions in their treatment of some traits, and (d) their selected literature provides an inaccurate picture regarding effect size. The authors suggest that future research in this field should seek conceptual and methodological constancy in trait selection and in the evaluation of attractiveness- and health-related traits. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

On the Precision in Estimating the Location of Edges and Corners

Recently, in Rohr [13], we analyzed the systematiclocalization errors introduced by local operators for detectinggrey-value corners. These errors are inherently due to thedifferential structure of the operators and, in general, areenlarged by discretization and noise effects. Here, we take thestatistical point of view to analyze the localization errorscaused by noisy data. We consider a continuous image model thatrepresents the blur as well as noise introduced by an imagingsystem. In general, the systematic intensity variations arenonlinear functions of the location parameters. For this modelwe derive analytic results stating lower bounds for the locationuncertainty of image features. The lower bounds are evaluatedfor explicit edge and corner models. We show that the precisionof localization in general depends on the noise level, on thesize of the observation window, on the width of the intensitytransitions, as well as on other parameters describing thesystematic intensity variations. We also point out that theuncertainty lower bounds in localizing these image features canin principle be attained by fitting parametric models directlyto the image intensities. To give an impression of theachievable accuracy numerical examples are presented.     

Evaluating Community Sex Offender Treatment Programs: A 12-Year Follow-Up of 724 Offenders.

Although some studies suggest positive effects of treatment for sexual offenders, most studies have been hampered by the unknown influence of selective attrition (e.g., volunteers and drop-outs). In the 1980s, the Correctional Service of Canada began to require weekly community treatment sessions for all sex offenders released in the Pacific Region. This policy change provided a unique opportunity for comparing an unselected cohort of treated sex offenders (n = 403) to an untreated cohort (n = 321) released in earlier years. After an average 12-year follow-up period, no differences were observed in the rates of sexual (21.1% vs 21.8%), violent (42.9% vs. 44.5%) or general (any) recidivism (56.6% vs 60.4%) for treated and untreated groups, respectively. The outcome remained comparable after controlling for length of follow- up, year of release, age, and seven static risk factors coded from official criminal history records. Retrospective ratings of the treatment quality also showed no relationship to observed recidivism rates. The static risk factors coded in the current study accounted for considerable variance in recidivism and could easily be used to improve statistical controls in future evaluations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Overt Anger in Response to Victimization: Attributional Style and Organizational Norms as Moderators.

Prior theory and research suggests a positive relation between perceived victimization and overt anger. The authors proposed and tested a theoretical extension of this link by investigating possible moderating effects of individual and contextual variables. A sample of 158 employees of a municipality was used to test hypotheses that the relationship between perceived victimization and overt anger is moderated by hostile attributional style and perceptions of organizational norms. The results showed that the relation between perceptions of direct victimization and overt anger was stronger when the employee had a more rather than less hostile attributional style and when the employee perceived the organizational norms as more rather than less oppositional. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Differing Conceptions of Moral Exemplarity: Just, Brave, and Caring.

People's conceptions of different types of moral exemplarity were examined in an attempt to augment the current emphasis on moral rationality with a fuller understanding of moral personality. In Study 1 (with 805 adults), a free-listing procedure was used to generate the attributes of 3 types of moral exemplars (just, brave, and caring). In Study 2 (with 401 undergraduates), prototypicality- and personality-rating procedures were used to generate a personality profile for each type of moral exemplar and to examine the relations among them. In Study 3 (with 240 undergraduates), a similarity-sorting procedure was used to identify the typologies implicit in people's understanding of these different types of moral exemplarity. The findings indicate that moral excellence can be exemplified in rather divergent ways and that understanding of moral functioning would be enhanced by attention to this wider range of moral virtues. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Microscopy under pressure--an optical chamber system for fluorescence microscopic analysis of living cells under high hydrostatic pressure

High hydrostatic pressure (HHP) becomes more and more interesting for life science research, since it can be employed to inactivate various cells. To directly monitor "cells under pressure," the development of an optical high-pressure chamber is required. Therefore, an optical pressure chamber that can be used for up to 300 MPa was constructed. This chamber has already been described as a tool for in situ observation of dynamic changes of microscopic structures in bright field as well as phase contrast. In combination with an inverted microscope, we obtained brilliant microscopic color pictures with an optical resolution more than 0.56 microm. Here, we demonstrate the capabilities of the HHP cell, in combination with epifluorescence microscopy. Using a nonadherent human B-cell line (Raji, ATCC CCL 86), stained with the fluorescent dyes propidium iodide, Hoechst 33342, or dihexyloxacarbocyanine iodide, we were able to show that the system is suitable to perform fluorescence microscopic analyses, with pressures up to 300 MPa, with viable mammalian cells.     

Comparison of atmospheric pressure photoionization and atmospheric pressure chemical ionization for normal-phase LC/MS chiral analysis of pharmaceuticals

In this work, we compared APPI and APCI for normal-phase LC/MS chiral analysis of five pharmaceuticals. Performance was compared both by FIA and by on-column analysis using a ChiralPak AD-H column under optimized conditions. By comparison, APPI generated more reproducible signals and was less susceptible to ion suppression than APCI. APPI generated higher peak area and lower baseline noise, and therefore much higher S/N ratios. APPI sensitivity (i.e., S/N ratio) was approximately 2-130 times higher than APCI by FIA and was approximately 2.6-530 times higher than APCI by on-column analysis depending on specific compounds. The better APPI sensitivity as compared to APCI was more dramatic by on-column analysis than by FIA. APCI sensitivity was degraded by ion suppression caused by LC column bleeding components and by elevated APCI baseline noise relative to APPI. On-column APPI LODs (at S/N = 3) were 83, 16, 17, 95, and 7 pg for enantiomer #1, and 104, 23, 19, 122, and 17 pg for enantiomer #2 for benzoin, naringenin, mianserin, mephenesin, and diperodon, respectively, on a Waters ZQ. APPI offers no concern of explosion hazard relative to APCI corona needle discharge or ESI high voltage discharge when flammable solvents (e.g., hexane) are used as mobile phases. Whether APPI dopants are required depends on the IP(s) of mobile-phase solvent(s) and solvent complexes, and photon energies of VUV lamps. Dopant was not necessary for hexane-based mobile phases due to their self-doping effects. Dopants did enhance Kr lamp APPI sensitivity when MeOH was used as the mobile phase. However, dopants became unnecessary for the MeOH mobile phase when the Ar lamp was used.     

Microcavity-integrated graphene photodetector

There is an increasing interest in using graphene (1, 2) for optoelectronic applications. (3-19) However, because graphene is an inherently weak optical absorber (only ≈2.3% absorption), novel concepts need to be developed to increase the absorption and take full advantage of its unique optical properties. We demonstrate that by monolithically integrating graphene with a Fabry-Pérot microcavity, the optical absorption is 26-fold enhanced, reaching values >60%. We present a graphene-based microcavity photodetector with responsivity of 21 mA/W. Our approach can be applied to a variety of other graphene devices, such as electro-absorption modulators, variable optical attenuators, or light emitters, and provides a new route to graphene photonics with the potential for applications in communications, security, sensing and spectroscopy.