Synthesis and characterization of polyelectrolyte hydrogels with controlled swelling behaviour

Copolymerization of sulfopropyl methacrylate potassium salt (K‐SPMA) and 2‐acrylamido‐2‐methyl propane sulfonic acid (AMPS) has been studied in the range 10–90% K‐SPMA in the feedstock. The reactivity ratios have been determined for K‐SPMA/AMPS copolymers. The copolymer compositions, utilized for determining the reactivity ratio, have been determined from nitrogen content. Crosslinked poly(AMPS) and K‐SPMA/AMPS copolymers were prepared in water in the presence of potassium persulfate as initiator and N,N‐methylene bisacrylamide (MBA) as tetrafunctional crosslinker. Irradiation of K‐SPMA and AMPS with an electron‐beam was carried out at 50 wt% aqueous solution with low pH and irradiation dose 40–120 kGy. The swelling behaviour of highly crosslinked K‐SPMA/AMPS copolymer polyelectrolyte gels in aqueous medium was studied in the presence of different types of salts. The crosslink density, the average molecular weight between the crosslinks and the dissociation constant (pK_a) of the crosslinked polymer were determined from stress–strain measurements. © 2001 Society of Chemical Industry     

4Pi spectral self-interference microscopy

Spectral self-interference microscopy (SSM) relies on the balanced collection of light traveling two different paths from the sample to the detector, one direct and the other indirect from a reflecting substrate. The resulting spectral interference effects allow nanometer-scale axial localization of isolated emitters. To produce spectral fringes the difference between the two optical paths must be significant. Consequently, to ensure that both contributions are in focus, a low-numerical-aperture objective lens must be used, giving poor lateral resolution. Here this limitation is overcome using a 4Pi apparatus to produce the requisite two paths to the detector. The resulting instrument generalizes both SSM and 4Pi microscopy and allows a quantification of SSM resolution (rather than localization precision). Specifically, SSM is shown to be subject to the same resolution constraints as 4Pi microscopy.     

Time and temperature dependent piezoresistance of carbon nanofiller/polymer composites under dynamic load

In this study, the behaviour of carbon nanotube/epoxy and carbon black/epoxy composites under dynamic load is studied via dynamic mechanical thermal analysis (DMTA) in combination with DC electrical resistivity measurements. DMTA measurements are carried out at fixed temperature whilst the dynamic loading frequency is varied. With this procedure, a loading frequency-dependence of the phase shift between DC electrical resistance and mechanical elongation (δ _R–ε) is observed, although the force and elongation of the sample are still in phase. Moreover, the magnitude of this phase shift, as well as the amplitude of the DC electrical resistance change shows a clear dependence on the initial electrical conductivity of the samples. In addition, temperature sweeps are carried out to investigate the temperature dependency of the piezoresistance of the samples. An abrupt change in their sensitivity is observed as soon as the glass transition of the polymer is reached. However, the trend of the resistance change beyond the glass transition is substantially different between the nanocomposites containing carbon black and carbon nanotubes, revealing a strong influence of the network characteristics on the piezoresistive behaviour of these novel materials.     

Reactions Between Silicon and Graphite Substrates at High Temperature: In Situ Observations

Graphite as a refractory material has found wide application in many process steps to produce photovoltaic silicon. In the current study, the melting behavior of silicon in contact with different grades of graphite was investigated. The infiltration of silicon into graphite was found to be highly dependent on the internal structure of the graphite substrate. It was confirmed that the heating history of silicon in contact with a graphite substrate strongly influences the melting behavior, which is likely attributed to a gas–solid reaction that forms SiC at less than the liquidus temperature of silicon and alters the surface properties of the graphite. It was also observed that a concentration of CO greater than 5 pct in the inlet gas leads to SiC formation on the surface of the silicon and severely hinders melting.     

Task goals and change in dynamical degrees of freedom with motor learning.

In this article, the authors examined the hypothesis that the direction of the change (increase or decrease) in the dynamical degrees of freedom (dimension) regulated as a function of motor learning is task-dependent. Adult participants learned 1 of 2 isometric force-production tasks (Experiment 1: constant force output; Experiment 2: sinusoidal force output) over 5 days of practice and a 6th day with augmented information withdrawal. The results showed that over practice, the task goal induced either an increase (Experiment 1) or a decrease (Experiment 2) in the dimension of force output as performance error was reduced. These findings support the proposition that the observed increase or decrease in dimension with learning is dependent on both the intrinsic dynamics of the system and the short-term change required to realize the task goal. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Correcting for measurement error in detecting unconscious cognition: Comment on Draine and Greenwald (1998).

A. G. Greenwald, M. R. Klinger, and E. S. Schuh (1995) have proposed a regression method for detecting unconscious cognition in experiments that obtain measures of indirect and direct effects of stimuli with suspected unconscious effects. Their indirect-on-direct-measure regression approach can produce misleading evidence for indirect effects in the absence of direct effects when the direct-effect measure has typical measurement error. This article describes an errors-in-variables variant of the regression method that corrects for error in the direct-effect measure. Applied to the uses of the regression method by S. C. Draine and A. G. Greenwald (see record 1999-10824-004), the errors-in-variables method affirms substantial evidence for indirect effects in the absence of direct effects. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Long-term recidivism of child molesters.

Examined the long-term recidivism rates of 197 child molesters released from prison between 1958 and 1974. Overall, 42% of the total sample were reconvicted for sexual crimes, violent crimes, or both, with 10% of the total sample reconvicted 10–31 yrs after being released. Incest offenders were reconvicted at a slower rate than were offenders who selected only boys, with offenders against girls showing a rate intermediate between these 2 groups. Other factors associated with increased recidivism were (1) never being married and (2) previous sexual offenses. None of the mental health and personality tests used in this study (e.g., the Eysenck Personality Inventory and the MMPI) was significantly associated with recidivism. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Locus of interpretive and inference processes during text comprehension: A comparison of gaze durations and word reading times.

Investigated the locus of interpretive and inference processes during text comprehension. Two positions were contrasted: the buffer-integrate-purge position, which assumes that text-level interpretive and inference processes operate at sentence or clause boundaries, and the immediacy position, which assumes that interpretive and inference processes operate as soon as possible. Two methods of collecting word reading times were contrasted: gaze durations and self-paced word reading times. In simple narrative passages, there was an increase in word reading times for end-of-clause words when self-paced reading times were collected, but there was a decrease when gaze durations were measured with eye tracking equipment. The data indicate that interpretive and inference processes operate immediately and that buffering is to some extent an artifact of the self-paced moving window method. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Peripheral nerve repair in the hand with and without motor sensory differentiation

To investigate the value of motor sensory differentiated nerve repair, we examined a group of 9 patients with motor sensory differentiated nerve repair and a group of 13 patients without motor sensory differentiated nerve repair. The clinical and electroneurographic findings were compared. For the clinical examination, Millesi's scoring system was used. The hand function after motor sensory differentiated median nerve repair was 72% +/- 16% compared with 57% +/- 14% without motor sensory differentiation. The hand function after motor sensory differentiated median and ulnar nerve repair was 53% +/- 12% compared with 43% +/- 24% without motor sensory differentiation. After ulnar nerve repair the achieved values for hand function were high even without motor sensory differentiation. Our results indicate that intraoperative motor sensory differentiation of injured nerves is helpful to reestablish particularly the sensory function in median nerve injuries.