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Elżbieta Chmiel‐Szukiewicz 《应用聚合物科学杂志》2008,109(3):1708-1713
Attempts of obtaining of polyurethane foams using polyetherols with 1,3‐pyrimidine ring (obtained in reactions of 6‐aminouracil with oxiranes) are reported. Properties of the foams are investigated, especially their thermal stability. The foams show an improved thermal stability up to 200°C for a long time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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Teresa Mikołajczyk Grażyna Janowska Mariusz Wójcik Maciej Boguń Andrzej Kurzak 《应用聚合物科学杂志》2008,109(4):2513-2521
The rheological properties of spinning solutions of polyacrylonitrile in dimethyl formamide (DMF) containing various amounts of a ferromagnetic nanoaddition were investigated. The porous structure, the strength and thermal properties of fibers obtained from these solutions were assessed, as well as the uniformity of the nanoaddition distribution on the fiber surface was estimated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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Polymeric oxidants in the bead form that were macroporous styrene/divinylbenzene copolymers containing N‐chlorosulfonamide functional groups (in sodium or hydrogen form) or N‐bromosulfonamide groups (in sodium form) were synthesized and investigated to determine their oxidizing powers. The redox potentials of the N‐chlorosulfonamide/sulfonamide and N‐bromosulfonamide/sulfonamide systems were determined by potentiometric studies at different pH values with aqueous solutions of Na2SO3, KCN, and KSCN as reducers. The formal redox potentials of the N‐chlorosulfonamide copolymers were 0.79, 0.44, and ?0.12 V at pH's of 1.8, 8.45, and 13.6, respectively. The formal redox potential of the N‐bromosulfonamide copolymer was about 100 mV higher in comparable conditions and in solutions over pH = 5 (e.g., 0.56 V at pH = 8.56). The comparatively higher oxidizing power of the N‐bromosulfonamide copolymer was particularly evident in a strong alkaline medium (in which the N‐chlorosulfonamide copolymer was not reactive). In contrast, the N‐chlorosulfonamide copolymer showed strong oxidative properties in acidic media (in which the N‐bromosulfonamide copolymer decomposed itself). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
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初轧机主传动系统扭转自激振动的稳定性 总被引:1,自引:0,他引:1
用变量摄动法对初轧机主传动系统扭转自激振动的稳定性进行了初步研究,讨论了稳定性条件,为初轧机打滑状态的诊断、监测提供了参考依据。 相似文献
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The coincidence of neuronal stress induced by intoxication and an overexpression of amyloid precursor protein (APP) in the brains of children was examined. Brains of ten children accidentally intoxicated by poisonous mushroom were studied by means of immunohistochemical methods using monoclonal antibodies generated against different domains of APP and glial cell markers. Overexpression of APP was found in the brain neurons of all intoxicated children. Neurons were immunopositive with the antibodies generated against the middle (amyloid beta protein) domain of APP. No extracellular deposits were found in the tissue. Our results provided, for the first time, the evidence that overexpression of APP concomitant with the neuronal stress is age-independent phenomenon appearing not only in the brain of adults but in very young individuals as well. 相似文献
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The direct electrooxidation of methanol in acid medium was studied on electrodes made of a perfluorinated membrane with small amounts of metal catalysts incorporated by chemical reduction. Platinum is a good electrocatalyst for this reaction, but needs to be modified by other metals in order to obtain oxidation potentials much more compatible with a working anode in a direct methanol fuel cell. Ruthenium and tin appear to give encouraging results, leading to a negative shift of more than 250 mV as compared to the potential obtained with pure platinum. Other parameters were investigated in this work, such as the working temperature, and the manner of introduction of the methanol into the cell. By gaseous supply, it was possible to carry out measurements at higher temperatures than with methanol in solution, and consequently to greatly improve the performance of the catalytic electrode. 相似文献
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本试验研究了ZrO2与40Cr钢在加入缓冲层前后的钎焊连接,结果表明:插入缓冲层Cu和Ti可以提高接头强度。对每一种缓冲层,存在一最佳厚度,对应的钎焊强度最大。此最佳厚度对Cu为0.4mm左右,对Ti为1mm左右。作者认为这是由缓冲层的力学性能和热膨胀系数对残余应力释放产生的两种相反影响而造成的。钎焊时,缓冲层Cu和Ti向钎料中均有程度不同的溶解,但不影响钎料对ZrO2的浸润和反应结合。ZrO2-40Cr钢连接的所有接头均断在陶瓷的近缝区,其断裂方式有三种。 相似文献