Super environment-friendly electrodeposition paint

Super low VOC due to new composition/reaction mechanism can minimize the environmental risk as it does not contain lead and tin, hazardous air pollutants (HAPs) and endocrine disrupters (EPA/67 items, SPEED’98/JEA/67 items) currently specified as contaminants. New EAD (electrolyzed activate deposition paint) is not the only conventional cure agent or solvent, but also the super low VOC, HAPs materials and endocrine disrupters. The electric energy used by EAD is utilized for the reaction but not for the deposition. EAD consists of two technologies. One is propargyl group change to the allene by using electrodeposition. Propargyl group is stable, but allene group is highly polymerizing. As a result, EAD had high bath stability. The other is sulfonium change to sulfide by using electrodeposition. This sulfonium salt is lost as a result of the electrolytic reduction, and hence can be irreversibly rendered non-conductive. As a result, EAD showed high throwing power.     

A fuzzy model to control the temperature in the cooling of metal molds with a spray robot

In a die-casting operation, the die spray is the key to quality and productivity, but the die-spray operation depends on parameter settings such as the spray volume and the operator's experience, even when a robot sprayer is used. The purpose of this study was to establish an intelligent system to control the surface temperature of a die with a water-based mist spray. A fuzzy model was applied to determine the optimum mist spray volume. The results generated show a good match with the actual measurements of the rate of the temperature drop versus the spray-mist volume. After the fuzzy analysis, the spray parameters calculated were used to control an actual die temperature experiment conducted on a heated plate model. The fuzzy model constructed by using fundamental experiments allowed the die spray operation to maintain a predetermined spray volume. This work was presented in part at the Fourth International Symposium on Artificial Life and Robotics, Oita, Japan, January 19–22, 1999     

Bulk heterojunction organic solar cells utilizing 1,4,8,11,15,18,22,25-octahexylphthalocyanine

Bulk heterojunction solar cells utilizing soluble phthalocyanine derivative, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH₂) have been investigated. The active layer was fabricated by spin-coating the mixed solution of C6PcH₂ and 1-(3-methoxy-carbonyl)-propyl-1-1-phenyl-(6,6)C61 (PCBM). The photovoltaic properties of the solar cell with bulk heterojunction of C6PcH₂ and PCBM demonstrated the strong dependence of active layer thickness, and the optimized active layer thickness was clarified to be 120 nm. By inserting MoO₃ hole transport buffer layer between the positive electrode and active layer, the FF and energy conversion efficiency were improved to be 0.50 and 3.2%, respectively. The tandem organic thin-film solar cell has also been studied by utilizing active layer materials of C6PcH₂ and poly(3-hexylthiophene) and the interlayer of LiF/Al/MoO₃ structure, and a high V_oc of 1.27 V has been achieved.     

Synthesis and antiallergic activity of dimethyl-2-(phenylcarbamoyl)ethylsulfonium p-toluenesulfonate derivatives

The derivatives of dimethyl-2-(phenylcarbamoyl)ethylsulfonium p-toluenesulfonates were synthesized and evaluated for antiallergic activity. The 2,3-dihydroxyethoxy group was introduced to the phenyl ring from the standpoint of lipophilicity and electronic effects of substituent. The IgE-induced rat passive cutaneous anaphylaxis (PCA) was inhibited by oral administration of several substituted 2-[(4-propoxyphenyl)carbamoyl]ethyldimethylsulfonium p-toluenesulfonate derivatives. Among them (+/-)-2-[N-[4-(3-ethoxy-2-hydroxypropoxy)phenyl]carbamoyl]ethyldimeth ylsulfonium p-toluenesulfonate (1a, IPD-1151T) was found to possess considerable activity in the PCA test, and it was launched as Suplatast tosilate in Japan.     

Evaluation of the PyloriTek test for detection of Helicobacter pylori infection in cases with and without eradication therapy

OBJECTIVE: The accuracy of the PyloriTek test (a 1-h rapid urease test) used after eradication therapy of Helicobacter pylori (H. pylori) has not been well clarified. This study was done to evaluate the accuracy of the PyloriTek test results for cases with and without eradication therapy, using culture and histology as gold standard methods, and to establish the suitable timing of the PyloriTek test after eradication treatment. METHODS: One hundred sixty-three patients undergoing upper endoscopy were randomly selected; 100 patients had not received eradication therapy and 63 had. Three biopsy specimens each were obtained from the gastric antrum and the body for examination by PyloriTek, culture, and histology. The absence of H. pylori was established with negative results from both culture and histology. RESULTS: In cases without eradication therapy, PyloriTek, correctly identified 66 of 67 H. pylori-positive cases and 30 of 33 H. pylori-negative cases, yielding 98.5% sensitivity and 90.9% specificity. In cases with eradication therapy, PyloriTek gave correct diagnoses in 10 of 17 H. pylori-positive cases and in 45 of 46 H. pylori-negative cases, for 58.8% sensitivity and 97.8% specificity. However, when PyloriTek was used more than 4 months after the end of eradication therapy, both the sensitivity and the specificity increased to 100%. CONCLUSION: Considering time and cost, the use of PyloriTek alone may be satisfactory for detecting H. pylori infection in cases without eradication therapy. When patients are examined more than 4 months after intervention, the use of PyloriTek alone may be sufficient for correctly diagnosing H. pylori infections.     

Multiobjective control of a vehicle with triple trailers

We consider the backing-up control of a vehicle with triple trailers using a model-based fuzzy-control methodology. First, the vehicle model is represented by a Takagi-Sugeno fuzzy model. Then, we employ the so-called "parallel distributed compensation" design to arrive at a controller that guarantees the stability of the closed-loop system consisted of the fuzzy model and controller. The control-design problem is cast in terms of linear matrix inequalities (LMIs). In addition to stability, the control performance considerations such as decay rate, constraints on input and output, and disturbance rejection are incorporated in the LMI conditions. In application to the vehicle with triple trailers setup, we utilize these LMI conditions to explicitly avoid the saturation of the steering angle and the jackknife phenomenon in the control design. Both simulation and experimental results are presented. Our results demonstrate that the fuzzy controller effectively achieves the backing-up control of the vehicle with triple trailers while avoiding the saturation of the actuator and "jackknife" phenomenon.     

Sharing and Compatibility Study between Fixed Service Using High Altitude Platform Stations (HAPS) and Other Services in the 31/28 GHz Bands

In the World Radiocommunication Conference 2000 (WRC-2000), use of the 31 GHzand 28 GHz bands was permitted for the fixed service (FS) by using highaltitude platform stations (HAPS) in some countries. This paper examines thesharing and compatibility of the HAPS-based FS with the other services usingthe same and adjacent frequency bands and establishes the conditions of thecoexistence with those services. Feasibility of dynamic channel assignment(DCA) scheme among the different communication systems to facilitate thecoexistence is also studied.