Small-chirp 40-Gbps electroabsorption modulator with novel tensile-strained asymmetric quantum-well absorption layer

A small-chirp 40-Gbps electroabsorption modulator (EAM) with a novel tensile-strained asymmetric quantum-well (QW) absorption layer has been demonstrated for the first time. The strain and the band line-up of the asymmetric QW structure were designed in order to obtain a small-chirp operation, a clear eye opening, and a high extinction ratio simultaneously. The chirp measured as /spl alpha/-parameter was reduced without any penalty of extinction ratio and eye opening. The measured /spl alpha/-parameter was smaller than 1.5 at any bias voltage from 0 to -2 V. The measured 3-dB bandwidth of a 75-/spl mu/m-long EAM exceeded 50 GHz at -1 V bias voltage. Under a 40-Gbps modulation, a clear eye opening was obtained, and the eye diagram showed no violation of the standard STM256/OC768 mask. The measured dynamic extinction ratio was over 11 dB.     

Method of noninvasive and continuous hemolysis/thrombogenesis measurement by laser photometry during artificial heart development

The purpose of this research is to propose and develop a method to measure hemolysis and thrombogenesis non invasively and continuously to aid in development of an artificial heart. Generally, the optical absorption rate of hemoglobin is influenced by oxygen saturation except at the isosbestic point, which is not influenced by oxygen saturation. The authors, therefore, used an 805 nm laser diode, an optical spectrum analyzer to obtain greater accuracy. An experimental blood circuit system was constructed using a Bio-Pump, Tygon tubing, a soft shell reservoir, and an optical measurement system. Experimental settings for monitoring hemolysis were as follows; blood volume 200 ml, blood flow 6 L/min, and afterload 200 mmHg. Blood was sampled six times (0, 30, 60, 120, 180, and 240 min), and hemolysis in each sampled was measured using a colorimetric method. Comparing continuous laser measurement data with the sample data, an adequate correlation is obtained, proving that the dynamic trend of hemolysis could be continuously measured. Furthermore, to analyze the process of thrombogenesis, simple experiments were performed using blood neutralized by protamine. As a result, the authors could see the process of thrombogenesis as it occurred and could confirm that this method is able to dynamically detect hemolysis and thrombogenesis.     

Effects of firing temperature on morphology and crystal structure of zirconiumbis(monohydrogen phosphate) and its alkali salts

In zirconiumbis(monohydrogen phosphate)monohydrate, the stability of water of crystallization and of the crystal form was strongly influenced by its crystal size. The water of crystallization of a smaller crystal was completely released on heating to 200° C while a part of this water was held at 300° C in a larger crystal with a diameter of several micrometres. While a smaller crystal was decomposed by heating to 900° C and cubic zirconium pyrophosphate was formed, for a larger crystal,-layered zirconium pyrophosphate was formed instead of cubic zirconium pyrophosphate and a layered structure was held. For the Na₂-, K₂- and Rb₂-forms, good layer structure was retained even by heating to 1000° C. For the Li₂-form, the layer structure was decomposed on heating at or above 900° C. The thermal stability of the layered structure increased with increasing crystal size and ionic radii of the alkali cation.     

Viewer,converter and preprocessor for smart machining process using an industrial robot

In this paper, viewer and converter softwares are presented for smart machining process using an industrial robot. The viewers for NC, CLS, DXF and STL files illustrate their surface representation with normal direction vectors. For example, the DXF is a data format developed by Autodesk to realize data interoperability among different makers’ CAD systems. The STL means Stereolithography which is a file format proposed by 3D Systems and recently is supported by many design tools and CAD/CAM softwares. In addition, the converters for DXF and STL files generate the corresponding CLS files with normal direction vectors for machining. Further, the proposed preprocessor allows the developed machining robot to work based on information included in STL files. The convenience and user-friendliness of the proposed integrated system are confirmed through experiments of viewing, converting and machining.     

A surface silylated single-layer resist based on limited gas permeation

A simple alternative was studied for the tri-layer resist system. One single thick layer of resist polymer was surface silylated to obtain a bilevel structure that functioned similarly to the bilayer resist composed of the Si-containing top imaging and the bottom planalizing layers. A resist or matrix polymer layer containing phenolic – OH groups was silylated by exposing it to hexamethyldisilazane vapor, and Si atoms were effectively incorporated in the surface sublayer by limited gas permeation and reaction with the – OH groups. Oxygen RIE durability of the silylated poly(vinyl phenol) or the positive-working commercial EB resist, RE-5000P, was > 10 times as high as that of PVP or RE-5000P before silylation. The surface silylated single-layer (SSS) resist derived from RE-5000P was flood-exposed through a mesh mask to 11.7°C/cm² of 4 KeV electrons, developed with tetramethylammonium hydroxide in aqueous methanol, and plasma-developed in an O₂ RIE chamber to form a positive-tone relief image.     

Synthesis of Nanowire TiO2 Thin Films by Hydrothermal Treatment and their Photoelectrochemical Properties

Nanowire TiO₂ thin films were successfully prepared on Ti metal substrates by hydrothermal treatment of calcined Ti foils in 10 M NaOH. The nanowire TiO₂ thin films exhibited much larger surface area and higher photoelectrochemical performance than the TiO₂ thin films prepared on Ti metal substrates by the calcination of Ti foil. These nanowire films were shown to act as an efficient photoanodes for the photoelectrochemical water splitting reaction.     

A memory‐in‐pixel reflective‐type LCD using newly designed system and pixel structure

A 7.03‐in. extended graphics array reflective LCD prototype has been developed by using memory‐in‐pixel (MIP) technologies with a newly designed system and pixel structure. The MIP system comprising a MIP backplane and a display driver has been optimized to reduce power consumption. The MIP backplane has specific circuits that allow accessing row drivers randomly, and the display driver manages which row should be accessed. Thus, the system is capable of showing a mixture of still and moving images, resulting in low power consumption. A dithering block embedded in the display driver enables to select an appropriate dithering algorithm according to the types of images and the position on the screen. In addition, the novel pixel structure, “three divided patterns”, has been designed to improve image quality and to provide visibility in dark environments. The latter is based on a novel approach; interpixel area is used for an aperture to transmit light from the backlight, and the fringe field from adjacent pixel electrodes is used to control LC directions. The feature of the pixel structure is also effective for obtaining equivalent gamma between reflective and transmissive images.     

Biodegradable polymers based on renewable resources. VI. Synthesis and biodegradability of poly(ester carbonate)s containing 1,4:3,6‐dianhydro‐D‐glucitol and sebacic acid units

Poly(ester carbonate)s with different compositions were synthesized by bulk polycondensation of 1,4:3,6‐dianhydro‐D ‐glucitol with diphenyl sebacate and diphenyl carbonate in the presence of zinc acetate as a catalyst. Most of the poly(ester carbonate)s as well as the corresponding polycarbonate were amorphous, except the poly(ester carbonate) with a small carbonate content and the corresponding polyester, which are semicrystalline. All these poly(ester carbonate)s are soluble in chloroform, pyridine, dimethylformamide, dimethyl sulfoxide, and N,N‐dimethylacetamide. Soil burial degradation tests, biochemical oxygen demand (BOD) measurements in an activated sludge, and enzymatic degradation tests indicated that these poly(ester carbonate)s are potentially biodegradable. The biodegradability was found to be maximum for the poly(ester carbonate)s with carbonate contents of 10–20 mol % and to decrease markedly for the poly(ester carbonate)s with the carbonate content above 50 mol %. The biodegradability of the poly(ester carbonate)s is discussed in terms of the crystallinity, glass transition temperature, and surface hydrophobicity of the polymer films. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 872–880, 2002     

A discontinuous exponential stabilization law for an underactuated X4-AUV

In this paper, stabilization of a class of second-order nonholonomic systems for an underactuated X4-AUV is investigated. We present a model of the underactuated X4-AUV with six degrees of freedom (DOF) and four control inputs. Then, the system is written in a control-affine form by applying a partial linearization technique, and a dynamic controller based on Astolfi’s discontinuous control is derived to stabilize all states of the system to the desired equilibrium point exponentially. The present approach does not necessitate the conversion of the system model into a “chained form”, and thus does not rely on any special transformation techniques to obtain a canonical form. A simulation is conducted to demonstrate the effectiveness of the proposed controller.     

Charge injection and decay of nanoscale dielectric films resolved via dynamic scanning probe microscopy

To satisfy continual demands for higher performance dielectrics in multi-layer ceramic capacitors and related microelectronic devices, novel characterization methods are necessary for mapping materials properties down to the nanoscale, where enabling materials developments are increasingly relevant. Accordingly, an atomic force microscopy-based approach is implemented for characterizing insulator performance based on the mapping of discharging dynamics. Following surface charging by biasing a conducting tip contacting a dielectric surface, consecutive non-contact Kelvin force surface potential mapping (KPFM) reveals charge dissipation via exponential decay. In barium titanate (BTO) thin films engineered with distinct microstructures but identical thicknesses, discharging rates vary by up to a factor of 2, with smaller grain size correlating to longer dissipation times, providing insight into optimal microstructures for improved capacitor performance. High-resolution potential mapping as a function of time thereby provides a route for directly investigating charge injection and discharging mechanisms in dielectrics, which are increasingly engineered down to the nanoscale and have global implications given the trillions of such devices manufactured each year.