Study on ozone treatment of water-soluble polymers. I. Ozone degradation of polyethylene glycol in water

Polyethylene glycol (molecular weight 8000) was degraded by ozone in 1% aqueous solution of pH 12. Chemical oxygen demand of the solution decreased with increasing ozone consumed. Intrinsic viscosity of the solution lowered exponentially as a result of the ozonization. The number of breaks calculated from the viscosity indicated that two molecules of ozone were consumed for one cleavage of the polymer chain. The molecular weight distribution obtained by gel permeation chromatography was very broadened and molecular weight was lower as well, and the polymer chain was found to be cleaved randomly by ozone. The production of formic ester, ethylene glycol, diethylene glycol, triethylene glycol, and hydrogen peroxide was confirmed by IR, NMR, gas chromatography, and chemical analysis. These observations could be accounted for by electrophilic attack of ozone on the ether bond.     

Residues important for the function of a multihelical DNA binding domain in the new transcription factor family of Cam and Tet repressors

We report that some prokaryotic repressors including CamR andTetR belong to the same family. CamR and TetR bind to DNA usinga multihelical DNA binding domain (DBD) at the N-termini ofthe proteins, while the C-termini are important for regulatingthe DNA binding in a manner dependent on their co-factors (camphorfor CamR, tetracycline for TetR). In all, 11 important aminoacid positions have been identified in the CamR DBD by the systematicsubstitution of residues by Ala. Of the 11 positions, 10 areeither buried in the core, and thus important for creating thehydrophobic environment, or exposed on the surface, and thusimportant for binding to DNA. The eleventh residue, Gly, seemsto be important for a loop structure. The DNA binding mode ofthis type of DBD and a general mechanism of regulating theirDNA binding are discussed in reference to the crystal structureof TetR [Hinrichs et al., (1994) Science, 264, 418–420].     

Effect of Computational Constraints on Zero-Dimensional Computations for the Nanosecond-Order Ignition Process of the CH4/Air Mixture

Combustion, Explosion, and Shock Waves - Zero-dimensional computations of nanosecond-order ignition using a nanosecond discharge are performed with two constraints. The effects of these constraints...     

Electrochemical properties of iron rust

In order to elucidate the electrochemical properties of iron rust, galvanostatic cathodic polarization of rusted steel and rust electrodes, prepared by fixing a piece of rust plate on an acrylic plate with conductive adhesive, was examined. The change in the amount of crystalline substances in the rust layer was observed by X-ray diffraction. The electrochemically active intermediate substances, could not be identified by X-ray diffraction, but their behaviour was distinguished from that of crystalline substances. The rest potential of the rust electrode was controlled by the equilibrium potential of intermediate substances. “An overlapping dual electrode” model is proposed for rusted steel in aqueous solution. Beneficial elements added to weathering steel inhibit the formation of crystalline magnetite in the cathodic reduction process of rust and increase the electrical resistance of the rust layer.     

Influence of chromium on the local structure and morphology of ferric oxyhydroxides

The extended X-ray absorption fine structure (EXAFS) method and transmission electron microscopy (TEM) have been used for characterizing the local structure and morphology of ferric oxyhydroxides, α-FeOOH and γ-FeOOH, with and without chromium. These ferric oxyhydroxide powders were prepared from aqueous solutions containing iron and chromium ions. Radial structural functions for iron obtained by Fe K edge EXAFS spectra showed that the linkage of structural units formed by FeO₆ octahedra in γ-FeOOH is distorted by chromium addition, while such distortion in α-FeOOH is not clearly detected. On the other hand, Cr K edge EXAFS spectra showed that the local structure around chromium does not necessarily correspond to the local structure around of iron, which is observed by Fe K edge EXAFS spectra. This suggests that the structural units containing iron and chromium are heterogeneously distributed in these ferric oxyhydroxides. The local structural information was discussed coupled with morphological features of these ferric oxyhydroxides observed by TEM.     

Difference between mechanical alloying and mechanical disordering in the amorphization reaction of Al50Ta50 in a rod mill

Amorphous Al₅₀Ta₆₀ alloy powders have been synthesized by mechanical alloying (MA) from elemental powders of aluminium and tantalum, and mechanical disordering (MD) from crystalline intermetallic compound powders of AlTa respectively using the rod milling technique. The mechanically alloyed and the mechanically disordered alloy powders were characterized by X-ray diffraction, scanning electron microscopy, electron probe microanalysis, transmission electron microscopy, differential thermal analysis, differential scanning calorimetry and chemical analysis. The results have shown that the crystal-to amorphous transformation in the MD process occurs through one stage, while the crystallineto-amorphous formation in the MA process occurs through three stages. At the early and intermediate stages of the MA time, heating the alloy powders to 700 K leads to the formation of an amorphous phase by a solid-state amorphizing reaction. At the final stage of the MA time, the amorphous phase is crystallized through a single sharp exothermic peak. Contrary to this, amorphous alloy powders produced by MD are crystallized through two broad exothermic peaks.     

Dynamic recrystallization by rapid heating followed by compression for a 17Ni–0.2C martensite steel

A 17Ni–0.2C martensite steel was rapidly heated below the austenite formation temperature and deformed in compression. Continuous dynamic recrystallization was observed. The behavior is similar to that in a ferrite–pearlite steel but the onset strain is much smaller. Sub-micron ferrite grains were obtained through the dynamic recrystallization.     

Embedded blended learning within an Algebra classroom: a multimedia capture experiment

This two‐group, pretest‐posttest, quasi‐experimental study compared secondary students' learning of Algebra II materials over a 4‐week period when identical instruction by the same teacher was delivered through either embedded blended learning (treatment group; n = 32) or a live‐lecture classroom (control group; n = 24). For both groups, instruction was delivered in a normal classroom setting. A math test and a student survey were used to measure students' learning of Algebra II and satisfaction with the instruction. Students in the treatment group showed significantly greater gains in Algebra II test scores and evaluated their learning experiences significantly more positively than did the control group. The great majority (80%) of students in the treatment group preferred the embedded blended learning over traditional live lectures for future learning of math. Students' responses to open‐ended survey questions suggested that students in the treatment group appreciated the: (a) ability to control the pace of instruction; (b) new role of the classroom teacher; (c) lack of distraction in the blended learning environment; and (d) accessibility of the embedded multimedia lessons outside the classroom. This study suggests that screen‐capture instructional technology can be used towards establishing a teacher‐based, embedded blended learning environment within a secondary algebraic classroom.     

Lithography with UV-LED array for curved surface structure

The technology to fabricate high-aspect ratio and micro curved surface structures is needed for optical device fabrication such as micro lens, light guiding device, and so on. In this study, micro curved surface structures were fabricated by using novel lithography technique with UV-LED array and rotary stage (Hanai et al. in Proceedings of the 22nd sensor symposium, pp 516–519, 2005). Smooth surface structures can be fabricated in this technique, because UV-LED which has wide directivity characteristics makes the difference of the UV dose. In addition, the structures can be formed with high uniformity in large area by only one exposure process, because rotation reduces the unevenness of exposure. This technique can control the shapes of structures by changing exposure time and applying gray scale mask method (Waits et al. in Sensors Actuat A 119:245–253, 2005). We fabricated structures of hemisphere, semi-cylinder, and semi-cone by using this technique. High-aspect ratio structures were obtained and they had smooth curved surface. Then, they were used for micro lens fabrication. By using molding technique, micro lenses of the UV curable resin were fabricated on the silicon wafer.     

Quantitative structural analysis of twin boundary in alpha-Zn7Sb2O12 using HAADF STEM method

The structure and composition of the 1/4{110} twin boundary in alpha-Zn7Sb2O12 have been determined by using quantitative high-angle annular dark field scanning transmission electron microscopy (HAADF STEM) analysis. The noise in the experimental HAADF STEM images is reduced by using the maximum entropy method and average processing, and the parameters used in dynamical simulations are experimentally determined. From the analysis, it has been found that octahedral sites in the twin boundary slightly shift parallel to the [110] direction, and a reduction of the Sb concentration at the octahedral sites on the plane adjacent to the twin boundary was detected. The reduction was measured from three regions in the same twin boundary, and the Sb concentrations were 4 +/- 3, 8 +/- 3 and 19 +/-2 at% from 33 at%.