Analysis of deformations and stresses in balanced and unbalanced adhesively bonded single-strap joints

Adhesively bonded joints are increasingly being used in joining various structural components. Adequate understanding of the behaviour of adhesively bonded joints is necessary to ensure efficiency, safety and reliability of such joints. While several joint configurations, such as the single- and double-lap joints have received considerable consideration, the single-strap joint configuration has received little attention, partly because earlier studies have shown it to be the least efficient.

One of the objectives of this paper is to demonstrate that strap joints can be as efficient as lap joints, as long as they are properly designed. This will be done through a detailed analytical investigation into influence of the parameters that govern peak stresses in the adhesive. The next objective is to produce simple equations by which the design of strap joint could be facilitated in an effective manner. For this, the developed analytical expressions are simplified and shown to provide accurate results. The derived solutions provide better insight into understanding the parameters that most influence the edge forces.     

Characteristics of the medical waste generated at the Jordanian hospitals

Recently, Jordan has witnessed increased amounts of medical waste generated at different healthcare facilities. This has resulted in issuance of Medical Waste Regulation that aimed at regulating the management processes of such hazardous waste. To provide information on medical waste generation rates, composition and statistical characteristics, a comprehensive sampling survey was initiated after a regulatory definition of the medical waste was established. Hospitals from Public, private and educational categories were covered by the survey. This paper presents the findings of the survey. The average generation rates ranged from 0.29 to 1.36 kg/bed/day, while in terms of patient numbers it is from 0.36 to 0.87 kg/patient/day. The total daily amount of medical waste generated at the Jordanian hospitals was estimated to be 6 tones/day. The daily amounts of medical waste generated at King Abdullah University Hospital were found to follow a log normal probability distribution. Physical composition analysis of the medical waste, which conducted based on the categories identified by the Jordanian Regulation, indicated that the infectious waste category is the highest, followed by sharps category and finally pathological, cytotoxic and pharmaceutical categories were the lowest. The study concluded that all hospitals covered by the survey are practicing segregation of hazardous medical waste from general medical waste. However, the segregation process in some hospitals is still inefficient and there is a potential for improvements toward minimizing the hazardous medical waste generation.     

Modifications to bicarbonate conductivity: A way to increase phosphate removal during hemodialysis? Proof of concept

Introduction Hyperphosphatemia and cardiovascular mortality are associated particularly with end‐stage renal disease. Available therapeutic strategies (i.e., diet restriction, calcium [or not]‐based phosphate binders, calcimimetics) are associated with extrarenal blood purification. Compartmentalization of phosphate limits its depuration during hemodialysis. Several studies suggest that plasmatic pH is involved in the mobilization of phosphate from intracellular to extracellular compartments. Consequently, the efficiency of modified bicarbonate conductivity to purify blood phosphate was tested. Methods Ten hemodialysis patients with chronic hyperphosphatemia (>2.1 mmol/L) were included in the two three–sessions‐per week periods. Bicarbonate concentration was fixed at 40 mmol/L and 30 mmol/L in the first and second periods, respectively. Phosphate depuration was evaluated by phosphate mobilization clearance (K_M). Findings Although bicarbonatemia was lower during the second period (21.0 ± 2.7 vs. 24.4 ± 3.1 mmol/L, P < 0.01), no difference was observed in phosphatemia (2.4 ± 0.5 vs. 2.3 ± 0.4 mmol/L, P = NS). The in‐session variation of phosphate was lower (?1.45 ± 0.42 vs. ?1.58 ± 0.44 mmol/L, P < 0.05) and K_M was higher during the second period (82.94 ± 38.00 vs. 69.74 ± 24.48 mL/min, P < 0.05). Discussion The decrease of in‐session phosphate and the increase in K_M reflect phosphate refilling during hemodialysis. Thus, modulation of serum bicarbonate may play a role in controlling the phosphate pool. Even though correcting metabolic acidosis during hemodialysis remains important, alkaline excess can impair phosphate mobilization clearance. Clinical trials are needed to test the efficiency and relevance of a strategy where bicarbonatemia is corrected less at the beginning of sessions.     

Direct adaptive neural network controller for a class of nonlinear systems based on fuzzy estimator of the control error

A new approach of direct adaptive control of single input single output nonlinear systems in affine form using single-hidden layer neural network (NN) is introduced. In contrast to the algorithms in the literature, the weights adaptation laws are based on the control error and not on the tracking error or its filtered version. Since the control error is being expressed in terms of the NN controller, hence its weights updating laws are obtained via back-propagation concept. A fuzzy inference system (FIS) with heuristically defined rules is introduced to provide an estimate of this error based on the past history of the system behaviour. The stability of the closed loop is studied using Lyapunov theory. A fixed structure is then proposed for the FIS and the design parameters reduce to the parameters of the NN. The method is reproducible and does not require any pre-training of the network weights.     

Nonlinear generalized equations of motion for multi-link inverted pendulum systems

In this paper, the equations of motion for a general multi-link inverted pendulum system are derived. Assumptions previously employed to simplify such formulation are removed. The pendulum system is more general and includes nonlinear friction terms to suit various engineering applications. The generalized equations are first developed in the absolute coordinate system using Lagrange's technique, then a simple linear transformation is proposed to obtain the set of nonlinear equations in the DevanitHartenberg coordinate system. The equations of motion for double and triple link inverted pendulum systems are given as examples for such dynamics equations.     

Grafting of vinyl acetate onto chitosan and biocidal activity of the graft copolymers

The reaction process of polycarbosilane (PCS) fiber cured by cyclohexene vapor has been studied and compared with that of PCS fiber cured by air. The influence of curing temperature on Si? H bond reaction degree and gel content, the structure and composition of PCS were investigated by FTIR, EA, TGA, NMR, and GC‐MS. The results showed that, Si? H bond in the molecular structure of PCS reacted during cyclohexene curing process and the reaction degree increased when the curing temperature increases. Simultaneously, gel content of PCS fiber rapidly increased till PCS fiber became infusible. Si? H radical and Si? CH₂ radicals formed Si? CH₂? Si crosslinking of PCS molecules through the agency of cyclohexene. Some cyclohexyls linked to principal chain of PCS, which was proven by ¹³C‐CPMAS‐NMR, and broke off, and cyclohexane and some monosilane are generated as byproducts when temperature increased. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Electrochemical and molecular dynamics simulation studies on the corrosion inhibition of aluminum in molar hydrochloric acid using some imidazole derivatives

The corrosion inhibition and adsorption characteristics of three selected imidazole derivatives namely, 2-amino-4,5-imidazoledicarbonitril (AID), 5-amino-4-imidazolecarboxamide (AIC) and imidazole (IM) on aluminum in 1.0 M HCl was investigated at 25 °C. Measurements were carried out under various experimental conditions using chemical (weight loss), and electrochemical (Tafel polarization and impedance) methods. Molecular dynamics (MD) method and density functional theory were also applied here for theoretical study. Results obtained showed that inhibition efficiency of these compounds increases with increase in their concentrations due to the formation of a surface film on the aluminum surface. Adsorption energy as well as hydrogen bond length calculations showed that AID was the best corrosion inhibitor among the tested imidazole derivatives. Polarization measurements reveal that the selected imidazole derivatives function mainly as cathodic-type inhibitors. Physisorption, followed by chemisorption was proposed as the mechanism for the inhibition process. Adsorption via H-bond formation was also considered here. Results obtained from theoretical study were found to confirm experimental findings.     

Kinetic investigation of C38 steel corrosion in concentrated perchloric acid solutions

The corrosion behaviour of steel at various concentrations of perchloric acid was studied by weight loss method in temperature range from 298 to 323 K. Results obtained show that corrosiveness of acid increases with its concentration and temperature. The logarithm of corrosion rate was plotted against the acid concentration and values of Hammett H_o and Strehlow R_o(H) acidity functions. The activation energies, enthalpies and entropies of the corrosion process of steel were also determined and fitted against R_o(H).