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41.
Syed Safdar Ali Khalid Mohammed Khan Hartmut Echner Wolfgang Voelter Mashooda Hasan Atta-ur-Rahman 《Advanced Synthesis \u0026amp; Catalysis》1995,337(1):12-17
Two new synthons, Fmoc-L-Arg(biphenyl-4-sulphonyl)-OH ( 8 ) and Fmoc-Arg(4-methoxy-3-t-butylbenzenesulphonyl)-OH ( 14 ), are prepared for the synthesis of arginine-containing peptides. These groups are cleaved by commonly employed trifluoroacetic acid and methanesulphonic acid. Kinetic studies reveal that extended bicyclic aromatic conjugation, as in biphenyl, slightly improves the acid lability compared to the electron-donating t-butyl group. 相似文献
42.
Sana Ghayas Muhammad Harris Shoaib Faaiza Qazi Rabia Bushra Fatima Ramzan Ali Madiha Maboos Farah Khalid 《Polymer Bulletin》2020,77(3):1281-1306
This work is based on formulating and optimizing controlled release (CR) valsartan (160 mg) tablets using different viscosity grades of the cellulosic polymer. The objective was to develop an effective once-daily drug delivery system of this cardiovascular agent. Central composite design was used for designing the formulations. Polymers used were Methocel® K4M, K15M and K100M. Compatibility of excipients with active was studied through FT-IR. Micromeritic properties were determined and formulations exhibiting appropriate flow characteristics were compressed. Swelling behavior and in vitro buoyancy effect were studied and response surface curves were constructed to optimize the formulation. Multi-point dissolution profiles of valsartan CR tablets at pH 1.2, 4.5 and 6.8 were obtained. Model-dependent and model-independent methods were performed including f2, stability test as per ICH guidelines and ANOVA. FT-IR studies revealed the compatibility of valsartan with all excipients. Formulation K4T9 (containing 25% K4M polymer) was selected to be the best optimized trial, based on physical properties and controlled release profile (23% at 4 h, 82% at 16 h and 100% at 24 h). Results of buoyancy and swelling behavior indicated that HPMC-K4M polymer exhibited excellent floating lag time and swelling indexes. In vitro drug release kinetics showed that formulation K4T9 displayed Korsmeyer–Peppas drug release pattern with r value > 0.99. The manufacturing process of K4T9 was also found to be reproducible with a shelf life period of 41 and 36 months at room temperature and accelerated conditions, respectively. Valsartan CR matrix-based formulation was successfully prepared with Methocel K4M retardant. 相似文献
43.
Khalid Al-Anezi Chris Somerfield David Mee Nick Hankins Nidal Hilal 《Desalination》2008,227(1-3):46-56
The objective of this work is to present experimental data that would show the effect of temperature, salinity, pressure and the presence of anti-scale additives on CO2 solubility in seawater. The paper examines the solubility of CO2 in real seawater and real seawater dosed with two different anti-scale additives. The study has been performed at temperatures between 60ºC and 90ºC and at pressures of 1 and 2 bar. To assess the effect of each anti-scale additive on CO2 gas solubility varying doses, 2–10 ppm of anti-scale additive have been used. For the purpose of the experimentation an experimental rig has been designed to ensure adequate contact between the gas phase and the aqueous phase. The continuous quantitative analysis of CO2 concentration flowing from the experimental rig was measured using a CM-5011 Carbon Coulometer. A mass balance was carried out to calculate the amount of CO2 absorbed into solution; Henry’s law constant was then calculated. 相似文献
44.
Rachid Essehli Brahim El BaliSaid Benmokhtar Khalid BouzianeBouchaib Manoun Mouner Ahmed AbdalslamHelmut Ehrenberg 《Journal of Alloys and Compounds》2011,509(4):1163-1171
Crystal structures from two new phosphates Na4NiFe(PO4)3 (I) and Na2Ni2Fe(PO4)3 (II) have been determined by single crystal X-ray diffraction analysis. Compound (I) crystallizes in a rhombohedral system (S. G: R-3c, Z = 6, a = 8.7350(9) Å, c = 21.643(4) Å, R1 = 0.041, wR2=0.120). Compound (II) crystallizes in a monoclinic system (S. G: C2/c, Z = 4, a = 11.729(7) Å, b = 12.433(5) Å, c = 6.431(2) Å, β = 113.66(4)°, R1 = 0.043, wR2=0.111). The three-dimensional structure of (I) is closely related to the Nasicon structural type, consisting of corner sharing [(Ni/Fe)O6] octahedra and [PO4] tetrahedra forming [NiFe(PO4)3]4+ units which align in chains along the c-axis. The Na+ cations fill up trigonal antiprismatic sites within these chains. The crystal structure of (II) belongs to the alluaudite type. Its open framework results from [Ni2O10] units of edge-sharing [NiO6] octahedra, which alternate with [FeO6] octahedra that form infinite chains. Coordination of these chains yields two distinct tunnels in which site Na+.The magnetization data of compound (I) reveal antiferromagnetic (AFM) interactions by the onset of deviations from a Curie-Weiss behaviour at low temperature as confirmed by Mössbauer measurements performed at 4.2 K. The corresponding temperature dependence of the reciprocal susceptibility χ−1 follows a typical Curie-Weiss behaviour for T > 105 K. A canted AFM state is proposed for compound (II) below 46 K with a field-induced magnetic transition at H ≈ 19 kOe, revealed in the hysteresis loop measured at 5 K. This transition is most probably associated with a spin-flop transition. 相似文献
45.
Synthesis of Novel Series of Benzothieno [2,3-d] Pyrimidine Derivatives, Promising Anticancer Agents
Omer Khalid AI-Duaij Hend Nagah Hafez Abdel-Rhman Barakat Ahmed EI-Gazzar 《化学与化工:英文版》2013,(8):725-742
An extension of the authors' previous discovery of in vitro antitumor activity of substituted thino [2,3-d] prymidine derivatives is reported. The synthesis of some new spirothino [2,3-d] prymidine (4a-f), imidazolidin, substituted prymidinyl and substituted thiazolidine thino [2,3-d] prymidine derivatives have been described. Thirteen of the obtained compounds were selected by the NCI and evaluated for their in vitro anticancer activity. Seven of the investigated compounds, 4a, 8a, 9a, (12a, b), 14a and 15a, displayed high anticancer activity in the primary assay. These compounds have been selected for a full anticancer screening against a 60-cell panel assay where they showed non-selective broad spectrum and promising activity against all cancer cell lines. Compounds 12a and 12b proved to be the active members in this study compared to 5-fluorouracil and cyclophosphamide as reference drugs, respectively. Compounds 12a and 12b were identified as promising lead compounds, evaluated for their in-vitro antitumor activity. 相似文献
46.
Khalid M. Saqr Hossam S. Aly Hassan I. Kassem Mohsin M. Sies Mazlan A. Wahid 《International Communications in Heat and Mass Transfer》2010
In this paper, a new variant of the k-ε turbulence model (Saqr et al., CFD Letters, 1(2) pp. 87–94) is used to compute the shear driven vortex flow in an open cylindrical cavity. The results are compared with published LDA measurements for such flow configuration. The modified turbulence model demonstrated good agreement with experimental results, which further supports its validity in computing vortex dominated flows. 相似文献
47.
Enas Taha Sayed Hussain Alawadhi A.G. Olabi Aisha Jamal Menna Salah Almahdi Juiaria Khalid Mohammad Ali Abdelkareem 《International Journal of Hydrogen Energy》2021,46(8):5975-5983
Microbial fuel cell (MFC) is a promising technology for simultaneous wastewater treatment and energy harvesting. The properties of the anode material play a critical role in the performance of the MFC. In this study, graphene oxide was prepared by a modified hummer's method. A thin layer of graphene oxide was incorporated on the carbon brush using an electrophoretic technique. The deoxygenated graphene oxide formed on the surface of the carbon brush (RGO-CB) was investigated as a bio-anode in MFC operated with real wastewater. The performance of the MFC using the RGO-CB was compared with that using plain carbon brush anode (PCB). Results showed that electrophoretic deposition of graphene oxide on the surface of carbon brush significantly enhanced the performance of the MFC, where the power density increased more than 10 times (from 33 mWm?2 to 381 mWm?2). Although the COD removal was nearly similar for the two MFCs, i.e., with PCB and RGO-CB; the columbic efficiency significantly increased in the case of RGO-CB anode. The improved performance in the case of the modified electrode was related to the role of the graphene in improving the electron transfer from the microorganism to the anode surface, as confirmed from the electrochemical impedance spectroscopy measurements. 相似文献
48.
This paper introduces a novel dynamic semiempirical model for the proton exchange membrane fuel cell (PEMFC). The proposed model not only considers the stack output voltage but also provides valid waveforms of component voltages, such as the no‐load, activation, ohmic, and concentration voltages of the PEMFC stack system. Experiments under no‐load, ramping load, and dynamic load conditions are performed to obtain various voltage components. According to experimental results, model parameters are optimised using the lightning search algorithm by providing valid theoretical ranges of parameters to the lightning search algorithm code. In addition, the correlation between the vapour and water pressures of the PEMFC is obtained to model the component voltages. Finally, all component voltages and the stack output voltage are validated by using the experimental/theoretical waveforms mentioned in previous research. The proposed model is also compared with a recently developed semiempirical model of PEMFC through particle swarm optimisation. The proposed dynamic model may be used in future in‐depth studies on PEMFC behaviour and in dynamic applications for health monitoring and fault diagnosis. 相似文献
49.
50.
Khalid Tauqeer Khan Abdul Nasir Ali Mazhar Adeel Adil ur Rehman Khan Atta Shuja Junaid 《Multimedia Tools and Applications》2019,78(17):24595-24615
Multimedia Tools and Applications - The world is facing many problems including that of traffic congestion. To highlight the issue of traffic congestion worldwide specially in urban areas and to... 相似文献