Metal Single-Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species

Single-atom (SA) catalysts exhibit high activity in various reactions because there are no inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields regarding photocatalytic hydrogen (H₂) evolution which can be generated by abundant water and sunlight. Herein, it is investigated whether 10 transition metal elements can work as an SA on graphitic carbon nitride (g-C₃N₄; i.e., gCN), a promising visible-light-driven photocatalyst. A method is established to prepare SA-loaded gCN at high loadings (weight of ≈3 wt.% for Cu, Ni, Pd, Pt, Rh, and Ru) by modulating the photoreduction power. Regarding Au and Ag, SAs are formed with difficulty without aggregation because of the low binding energy between gCN and the SA. An evaluation of the photocatalytic H₂-evolution activity of the prepared metal SA-loaded gCN reveals that Pd, Pt, and Rh SA-loaded gCN exhibits relatively high H₂-evolution efficiency per SA. Transient absorption spectroscopy and electrochemical measurements reveal the following: i) Pd SA-loaded gCN exhibits a particularly suitable electronic structure for proton adsorption and ii) therefore they exhibit the highest H₂-evolution efficiency per SA than other metal SA-loaded gCN. Finally, the 8.6 times higher H₂-evolution rate per active site of Pd SA is achieved than that of Pd-nanoparticles cocatalyst.     

Built-in folded monopole antenna for handsets

A built-in folded monopole antenna for handsets (BFMA) is introduced and investigated. The characteristics of the BFMA are compared with those of a planar inverted-F antenna (PIFA), which is one of the conventional handset antennas. As a result, it has been confirmed that the BFMA has smaller size and wider bandwidth compared with the PIFA.     

Millimeter and submillimeter-wave quasi-optical oscillator withmulti-elements

Multielement oscillators with a quasi-optical resonator are reported. The resonator consists of a Fabry-Perot cavity with a grooved mirror (grating) and a concave mirror. It is possible to mount solid-state devices (Gunn diode, GaAs MESFET, etc.) in the grooved mirror. The oscillator has the capability for power-combining of solid-state sources in the millimeter- and submillimeter-wave regions     

Transverse-junction-stripe GaAs-AlGaAs lasers for squeezed lightgeneration

We fabricated 850-nm GaAs transverse-junction-stripe (TJS) lasers by an improved metal-organic chemical vapor deposition (MOCVD) and double Zn diffusion process. The high V/III ratio used during the MOCVD growth significantly reduced the intermixing of GaAs active layer and AlGaAs cladding layers. The modified process realized good confinement for both carriers and photons and smaller saturable loss. We measured squeezing of -2.8 dB (-4.5 dB after correction for detection efficiency) at a pumping rate of I/I_th≈20 from these lasers, which is in close agreement with the theoretical limit. This squeezing remained unchanged under injection locking, indicating almost perfect conservation of the intensity noise correlation among the longitudinal modes. These TJS lasers had very small low-frequency 1/f noise     

Multiobjective control of a vehicle with triple trailers

We consider the backing-up control of a vehicle with triple trailers using a model-based fuzzy-control methodology. First, the vehicle model is represented by a Takagi-Sugeno fuzzy model. Then, we employ the so-called "parallel distributed compensation" design to arrive at a controller that guarantees the stability of the closed-loop system consisted of the fuzzy model and controller. The control-design problem is cast in terms of linear matrix inequalities (LMIs). In addition to stability, the control performance considerations such as decay rate, constraints on input and output, and disturbance rejection are incorporated in the LMI conditions. In application to the vehicle with triple trailers setup, we utilize these LMI conditions to explicitly avoid the saturation of the steering angle and the jackknife phenomenon in the control design. Both simulation and experimental results are presented. Our results demonstrate that the fuzzy controller effectively achieves the backing-up control of the vehicle with triple trailers while avoiding the saturation of the actuator and "jackknife" phenomenon.     

Electron microscopy at a sub-50 pm resolution

An aberration-corrected electron microscope developed in CREST project has been applied for imaging atoms and clusters buried inside crystals. The resolution of the microscope in scanning transmission electron microscopy (STEM) has experimentally proved to be better than 47 pm by use of a cold-field emission gun at 300 kV. The high resolution has given an advantage for imaging light elements such as lithium atoms discriminating one by one. Moreover, a three-dimensional structure imaging has been demonstrated for dopant clusters by a sub-50 pm STEM, using its high depth resolution.     

Role of Cooper pairs for the generation of entangled photon pairs from single quantum dots

Generation of entangled photon pairs from semiconductor quantum dots (QDs) is highly desirable for realizing practical solid-state photon sources for quantum information processing and quantum cryptography. However, the energy splitting of exciton states in QDs almost prevent the generation of entangled photon pairs. This paper discusses the new possibility with the injection of electron as well as hole Cooper pairs into QDs.     

Arginine infusion stimulates prolactin, growth hormone, insulin, and subsequent lactation in pregnant dairy cows

L-Arginine or saline was administered intravenously by rapid infusion into 16 late-pregnant Holstein cows to study changes of prolactin, growth hormone, insulin, total protein, urea nitrogen, and subsequent lactation. Arginine was infused daily at .1 g/kg body weight starting about 7 days prior to predicted calving until calving. Blood was sampled via a jugular cannula at 0700, 0715, 0730 (infusion immediately followed 0730 h sample), 0745, 0815, 0845, 1100, 1300, 1500, 1700, and 1900 h. Arginine infusion evoked dramatic but transient increase of concentrations of blood serum prolactin, growth hormone, and insulin. Urea nitrogen also was elevated in blood serum but not total protein. The secretory response of prolactin, growth hormone, and insulin to daily arginine infusion during the entire prepartum period was not diminished. Milk production for the first 22 wk of lactation tended to be higher (by about 10%) for cows infused with arginine as compared to cows infused with saline. Therefore, repeated arginine infusion in late-pregnant cows dramatically increased prolactin, growth hormone, and insulin and tended to increase subsequent milk yield.     

Variable Frequency Microwave Curing of Amide-Epoxy Based Polymers

Irradiation of a dielectric material with microwave irradiation results in energy transfer due to rotational-vibrational transitions within the molecule. The energy transfer results in a local rise in temperature within the material. Microwave-induced reactions can occur at a lower average temperature than convective heating resulting in faster thermal curing of polymer dielectrics because the energy absorption is localized at particular sites. In this study, variable frequency microwave (VFM) curing of epoxy-based dielectric films was investigated. The microwave energy was swept through a range of frequencies to dissipate standing waves so that metallic conductors could be present with the dielectric films. The rate of reaction and film properties of polyamideimide (PAI) and bisphenol A epoxy resin (BPAEp) were studied. Benzanilide and BPAEp were used as model compounds for the reaction between the amide and epoxy. Compared to convective heating, the microwave reaction rates were higher at each isothermal cure temperature. The resulting mechanical properties of the films cured by microwave heated were superior to thermally cured materials. The elastic modulus of VFM cured PAI/BPAEp films was less than that of thermally cured films and the elongation to break was twice as high. Further, the adhesion to copper was improved with microwave processing. The chemical structure of the VFM cured polymer was different from the thermally cured polymer, based on Fourier transform infrared analysis, and is likely the origin of the improved properties.     

FIR system identification based on a nonparametric Bayesian model using the Indian buffet process

In this paper, we propose a nonparametric Bayesian model combined with the Indian buffet process (IBP) for a finite impulse response (FIR) system. We develop an FIR system identification method that can simultaneously estimate the number of FIR taps and coefficients. In the proposed model, each FIR tap consists of a coefficient and a gain, and the gain is a binary value. An infinite-dimensional binary vector is composed of binary values, and we assume that this binary vector is generated by the IBP. To identify the FIR system, we specify the likelihood function and prior distributions of the parameters and derive their posterior distributions. We can simultaneously estimate the number of FIR taps and coefficients by sampling from posterior distributions using the Gibbs sampler. Our simulations demonstrate that although the number of FIR taps is unknown, the identification performance of the proposed method in a high signal-to-noise ratio environment is similar to or better than that of the conventional least square solution.