Impacts of Scarification and Degermination on the Expansion Characteristics of Select Quinoa Varieties during Extrusion Processing

Extrusion of 2 quinoa varieties, Cherry Vanilla and Black (scarified and unscarified) and a mixed quinoa variety, Bolivian Royal (scarified and degermed) were studied for their extrusion characteristics. A corotating twin‐screw extruder with a 3 mm round die was used. Feed moisture contents of 15%, 20%, and 25% (wet basis) were studied. The extruder barrel temperature was kept constant at 140 °C and screw speeds were varied from 100, 150, and 200 revolutions per minutes. Process responses (specific mechanical energy, back pressure, and torque) and product responses (expansion ratio, unit density, and water absorption index/water solubility index) were evaluated. The degermed Bolivian Royal showed the highest expansion in comparison to all other varieties, attributed to its significantly low levels of fat, fiber, and protein. The scarified Cherry Vanilla resulted in the lowest expansion ratio. This was attributed to the increase in the protein content from the removal of the outer layer. The results indicate that all the varieties performed differently in the extrusion process due to their modification processes as well as the individual variety characteristics.     

Aqua-mediated in situ synthesis of highly potent phosphorous functionalized flame retardant for cotton fabric

Flame retardancy in various materials is becoming an increasingly important performance feature. In the textile industries, fire-related problems have become an important concern over the decade. Herein, the polyvinyl alcohol (PVA) and graphene-supported material were functionalized with trimethyl phosphate (TMP) for the synthesis of flame retardant (FR) composite material [graphene polymer functionalized trimethyl phosphate (GPTMP)] in the aqueous medium, which improves the stability of cotton fabric against flame. Graphene and PVA fabricated with phosphorus functional groups make the fabric more comfortable against fire and help to avoid further spreading of fire. The composite-coated fabric sustains for a long time on continuous flame with maintaining its initial shape and size. The GPTMP-coated fabric shows flame retardancy for up to 540 s on constant flame exposure, whereas control samples such as PVA-, graphene oxide-, and TMP-coated fabrics resist for up to 15, 20, and 14 s, respectively. The limiting oxygen index (LOI) and vertical flammability test (VFT) for synthesized composites were performed to confirm and support the flame retardancy property of GPTMP. The GPTMP shows the 35% LOI value and forms the char length of 2.6 cm during VFT. This work provides a simple and eco-friendly method to obtain novel GPTMP, which has a high potential as a FR for different fabrics, including cotton.     

Characterization of Tri-Phasic Edible Films from Chitosan,Guar Gum,and Whey Protein Isolate Loaded with Plant-Based Antimicrobial Compounds

Essential oil containing tri-phasic films of chitosan, guar gum, and whey protein isolate were prepared. Eugenol, carvacrol, and citral were used as the oil phase, either alone or in combination. The addition of essential oils decreased the water vapor transmission rate and tensile strength of the films. CLSM confirmed the presence of essential oil droplets within the biopolymer matrix. XRD analysis indicated that the addition of essential oils altered biopolymer interactions. FTIR analysis suggested alterations within whey protein structure in the presence of essential oils. The essential oil containing films showed good antimicrobial activity, suggesting potential application in food packaging.     

Estimation of ipratropium bromide from aerosols by reversed-phase liquid chromatography

Ipratropium bromide, a derivative of N-isopropyl noratropine, was estimated from the samples of aerosols. An isocratic, reversed-phase liquid chromatographic separation method was developed by using an ODS, 5 μm column with the mobile phase acetonitrile-sodium dihydrogen orthophosphate (0.05M)-diethylamine (50 : 50 : 0.1, v/v) pH adjusted to 4.5 with phosphoric acid. Recoveries obtained were in the range 98% to 102% of ipratropium bromide from aerosol. Fluoxetine hydrochloride was used as an internal standard for quantitation.     

Classification of complex environments using pixel level fusion of satellite data

The present study reports classification and analysis of composite land features using fusion images obtained by fusing two original hyperspectral and multispectral datasets. The high spatial-spectral resolution, multi-instrument and multi-period satellite images were used for fusion. Three pixel level fusion based techniques, Color Normalized Spectral Sharpening (CNSS), Principal Component Spectral Sharpening Transform (PCSST) and Gram-Schmidt Transform (GST), were implemented on the datasets. Performance evaluations of three fusion algorithms were done using classification results. The Support Vector Machine (SVM) and Gaussian Maximum Likelihood Classification (MLC) were used for classification using five types of images, viz. hyperspectral, multispectral and three fused images. Number of classes considered was eight. Sufficient number of ground field data for each class has also been acquired which was needed for supervise based classification. The accuracy was improved from 74.44 to 97.65% when the fused images were considered with SVM classifier. Similarly, the results were improved from 69.25 to 94.61% with original and fused data using MLC classifier. The fusion image technique was found to be superior to the single original image and the SVM is better than the MLC method.

     

Effect of self-assembled monolayers on charge injection and transport in poly(3-hexylthiophene)-based field-effect transistors at different channel length scales

Charge injection and transport in bottom-contact regioregular-poly(3-hexylthiophene) (rr-P3HT) based field-effect transistors (FETs), wherein the Au source and drain contacts are modified by self-assembled monolayers (SAMs), is reported at different channel length scales. Ultraviolet photoelectron spectroscopy is used to measure the change in metal work function upon treatment with four SAMs consisting of thiol-adsorbates of different chemical composition. Treatment of FETs with electron-poor (electron-rich) SAMs resulted in an increase (decrease) in contact metal work function because of the electron-withdrawing (-donating) tendency of the polar molecules. The change in metal work function affects charge injection and is reflected in the form of the modulation of the contact resistance, R(C). For example, R(C) decreased to 0.18 MΩ in the case of the (electron-poor) 3,5-bis-trifluoromethylbenzenethiol treated contacts from the value of 0.61 MΩ measured in the case of clean Au-contacts, whereas it increased to 0.97 MΩ in the case of the (electron-rich) 3-thiomethylthiophene treated contacts. Field-effect mobility values are observed to be affected in short-channel devices (<20 μm) but not in long-channel devices. This channel-length-dependent behavior of mobility is attributed to grain-boundary limited charge transport at longer channel lengths in these devices.     

Aegle marmelos (L.) Correa: An Underutilized Fruit with High Nutraceutical Values: A Review

Aegle marmelos (L.) Correa (Bael) fruit, a member of the Rutaceae family, is a major cultivated fruit plant in tropical and subtropical regions in countries of southeast Asia. Bael fruit has been a major topic for studies in recent years mainly due to its high nutritional (carbohydrates, proteins, minerals, and vitamins) value and presence of various phytochemicals, which attributed to its high medicinal value. These phytochemicals include various compounds, e.g., alkaloids, flavonoids, and phenolic acids (protocatechuic acid, gallic, and ellagic acid). The fruit extract of bael has been also an important study area for its pharmacological activities, including antidiarrheal, antioxidant, antidiabetic, hepatoprotective, radioprotective, anticancer, antiulcer properties. The current review mainly highlighted the nutritional and pharmacological activities of bael fruit. The nutritional profile and phytochemical profile were discussed in the review, along with their concentration in the fruit. Moreover, the experiments carried out in vivo and in vitro of bael fruit extracts with respect to their pharmacological activities were also discussed in the article. The recent literature based on nutritional and pharmacological values of bael fruit showed its high potential as a food and pharmaceutical product. Despite having high nutritional and pharmacological value, research related to molecular mechanisms of bael fruit is still limited, and clinical trials are needed to ensure its safety as a product in the food and pharma industries.