Zur Nitratreaktion bei Milchprodukten

Zusammenfassung Wir haben die für die Abfüllung von Milchprodukten benützten Kartonpapiersorten auf ihren Nitratgehalt untersucht. Die untersuchten Kartonsorten zeigten schwankenden, aber unbedeutenden Nitratgehalt, der in erster Linie von den verschieden hohen Nitratgehalten der Fabrikationswässer abhängig ist. In den untersuchten Fällen wurde die Aufnahme von Nitraten durch Sauerrahm aus solchen paraffinierten Kartonbechern nachgewiesen. Die Herkunft dieser weit über den ursprünglichen Nitratgehalt der Kartons hinausgehenden Nitratmenge lag in dem zur Herstellung der Becher benützten, stark nitrathaltigen Stärkekleister. In solchen Fällen fallen somit die an die Nitratreaktion geknüpften Folgerungen (Wässerung, Verschmutzung) weg. Daher ist bei der Beurteilung der Milchprodukte auf Grund der Nitratreaktion auf diesen Umstand acht zu geben.Da solche Kartonbehälter auch zur Abfüllung anderer Lebensmittel verwendet werden (Honig, Senf, Marmelade usw.), behalten wir uns vor, unsere Untersuchungen auch auf dieses Gebiet auszudehnen.     

Thin hard coatings fracture propagation during the impact test

One of the most significant applications of the impact test is to investigate thin hard coatings fatigue properties. Herein the test conditions and duration up to the film damage initiation, are considered in order to determine the critical stresses associated with the coating fatigue strength. Moreover, the subsequent film damage propagation is a significant mechanism as well, since it refers to the ability of the coating to withstand loads after its fatigue damage initiation. In order to describe the film fracture propagation the failed area ratio was introduced and an algorithm to determine this magnitude developed, based on the analysis of imprint scanning electron microscopy graphs. The application of the coating failed area ratio will be demonstrated in various impact test film cases, also with superficial thin layers. The top layers do not affect, in general, the failure initiation of the basic coating. However, according to the obtained results, the superficial films influence the basic coating failure propagation rate during the impact test.     

Inhibiting and deactivating effects of water on the selective catalytic reduction of nitric oxide with ammonia over MnOx/Al2O3

The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnO_x-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water.     

集成了网络连接的低成本控制器

按照当前的技术水准，如果设计一个不与网络或互联网连接的控制、调节或数据通信系统显然是落伍了。文中将介绍如何采用Maxim／Dalias创新的八位网络微控制器DS80C400实现低成本的具有WEB连接的工业应用。     

Proteine des Bienenhonigs

Zusammenfassung Die Isolierung der Saccharase (E.C. 3.2.1.20) aus den Proteinkonzentraten von Raps-, Tannen- und Zuckerfütterungshonig wird beschrieben. Die Abtrennung von anderen Enzymen, insbesondere von saurer Phosphatase gelingt durch hydrophobe Wechselwirkungschromatographie, von inerten Proteinen durch Gelfiltration. Im Zusammenhang damit wird das Verhalten des Enzyms bei der Chromatographie an Anionenaustauschern, an Hydroxylapatit und an immobilisiertem Weizenkeimlectin untersucht. Dabei ergab sich am Lectin-Gel eine Trennung in zwei multiple Formen.Die Saccharase aus allen drei Honigsorten verhielt sich einheitlich, woraus zu schließen ist, daß sie ausschließlich von der Biene stammt. Ihre Molekül masse wurde gelchromatographisch zu 57000 ermittelt.

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The proteins of honeyVIII. Honey sucrase, isolation, chromatographic behaviour and properties

Summary The isolation of the honey sucrase (E.C. 3.2.1.20) from rape- and fir-honey as well as from honey obtained after sugar feeding is described. The separation from other honey enzymes especially from acid phosphatase succeded by reversed phase chromatography. Separation of other, non-active proteins was accomplished by gel permeation chromatography. The behaviour of the honey sucrase upon chromatography on anion exchangers, on hydroxylapatite and wheat germ lectin was investigated. No differences were found between the sucrases of the three honeys.The molecular weight was determined at 57 000. By affinity chromatography with wheat germ lectin the enzyme could be separated into two multiple forms.

     

Verf?rbung grau und wei? pigmentierter Beschichtungen auf Acrylharzbasis auf Tropenh?lzern

Ohne Zusammenfassung