Heat Pump Drying of Green Sweet Pepper

Thin-layer drying experiments under controlled conditions were conducted for green sweet pepper in heat pump dryer at 30, 35, and 40°C and hot air dryer at 45°C with relative humidities ranging from 19 to 55%. The moisture content of sweet pepper slices reduced exponentially with drying time. As the temperature increased, the drying curve exhibited a steeper slope, thus exhibiting an increase in drying rate. Drying of green sweet pepper took place mainly under the falling-rate period. The Page equation was found to be better than the Lewis equation to describe the thin-layer drying of green sweet pepper with higher coefficient of determination and lower root mean square error. Drying in heat pump dryer at 40°C took less time with higher drying rate and specific moisture extraction rate as compared to hot air drying at 45°C due to lower relative humidity of the drying air in a heat pump dryer though the drying air temperature was less. The retention of total chlorophyll content and ascorbic acid content was observed to be more in heat pump–dried samples with higher rehydration ratios and sensory scores. The quality parameters showed a declining trend with increase in drying air temperature from 30 to 45°C. Keeping in view the energy consumption and quality attributes of dehydrated products, it is proposed to dry green sweet pepper at 35°C in heat pump dryer.     

Synthesis and Characterization of Poly(acrylic acid)/Poly(vinyl alcohol)-xanthan Gum Interpenetrating Network (IPN) Superabsorbent Polymeric Composites

Initially interpenetrating network (IPN) hydrogel was prepared by dispersing xanthan gum (XG) into poly(vinyl alcohol) (PVA) backbone in an aqueous medium. Polyacrylic acid (PAA)/Poly (vinyl alcohol)-Xanthan gum IPN superabsorbent composite were fabricated well by dispersing the prepared IPN hydrogel in acrylic acid and polymerized in a complete aqueous environment through chemical cross-linking method. These superabsorbent polymeric composites were analytically evaluated by scanning electron microscopy (SEM), Fourier Transform Infrared Spectra (FTIR), Thermal analysis (DSC) and X-ray diffraction (XRD) analysis. Simultaneously water absorbency, swelling kinetics and water retention abilities of this prepared superabsorbent polymeric composites were also investigated systematically.     

Exploring the Bioactive Potentials of C60-AgNPs Nano-Composites against Malignancies and Microbial Infections

At present, the potential role of the AgNPs/endo-fullerene molecule metal nano-composite has been evaluated over the biosystems in-vitro. The intra-atomic configuration of the fullerene molecule (C₆₀) has been studied in-vitro for the anti-proliferative activity of human breast adenocarcinoma (MDA-MB-231) cell lines and antimicrobial activity against a few human pathogens that have been augmented with the pristine surface plasmonic electrons and antibiotic activity of AgNPs. Furthermore, FTIR revealed the basic vibrational signatures at ~3300 cm⁻¹, 1023 cm⁻¹, 1400 cm⁻¹ for O-H, C-O, and C-H groups, respectively, for the carbon and oxygen atoms of the C₆₀ molecule. NMR studies exhibited the different footprints and magnetic moments at ~7.285 ppm, explaining the unique underlying electrochemical attributes of the fullerene molecule. Such unique electronic and physico-chemical properties of the caged carbon structure raise hope for applications into the drug delivery domain. The in-vitro dose-dependent application of C₆₀ elicits a toxic response against both the breast adenocarcinoma cell lines and pathogenic microbes. That enables the use of AgNPs decorated C₆₀ endo fullerene molecules to design an effective anti-cancerous drug delivery and antimicrobial agent in the future, bringing a revolutionary change in the perspective of a treatment regime.     

Optimization of the Length of Silicon Nanowires Prepared from MACE Method Using Gene Expression Programming and Genetic Algorithm

Silicon - Metal-assisted chemical etching (MACE) of silicon is used in this study to fabricate silicon nanowire arrays (SiNWs) of different length. This method was modeled using gene expression...     

Kinetic study of liquid lipase-catalyzed glycerolysis of olive oil using Lipozyme TL 100L

Monoacylglycerol (MAG) and diacylglycerol (DAG) are two natural components found in most edible oils and fats. Conventional synthesis of MAG and DAG is usually conducted by glycerolysis of triacylglycerol (TAG) at high temperatures (above 200°C) in the presence of an alkaline catalyst. In this work, the synthesis of MAG and DAG using enzymatic glycerolysis of olive oil was investigated using Tween 80 as surfactant, n-butanol as co-surfactant and the novel lipase in free/liquid formulation Lipozyme TL 100L as catalyst. Experimental design was used to evaluate the effect of enzyme load and reaction temperature on the feedstock conversion. Enzyme load and system temperature were significant variables in the statistical design and the best condition was found at 35°C, 7.5 vol% of Lipozyme TL 100L and glycerol to oil volumetric ratio of 2:1 with conversion of TAG at approximately 98% after 2 h of process. A mathematical model based on the Ping-Pong Bi-Bi mechanism was used to describe the reaction kinetics. The model adequately described the behavior of the system and can be a useful tool for the design of reactors in larger scales.     

Host-Assisted Delivery of a Model Drug to Genomic DNA: Key Information from Ultrafast Spectroscopy and in silico Study

Drug delivery to a target without adverse effects is one of the major criteria for clinical use. Herein, we have made an attempt to explore the delivery efficacy of SDS surfactant in a monomer and micellar stage during the delivery of the model drug, Toluidine Blue (TB) from the micellar cavity to DNA. Molecular recognition of pre-micellar SDS encapsulated TB with DNA occurs at a rate constant of k₁ ∼652 s⁻¹. However, no significant release of encapsulated TB at micellar concentration was observed within the experimental time frame. This originated from the higher binding affinity of TB towards the nano-cavity of SDS at micellar concentration which does not allow the delivery of TB from the nano-cavity of SDS micelles to DNA. Thus, molecular recognition controls the extent of DNA recognition by TB which in turn modulates the rate of delivery of TB from SDS in a concentration-dependent manner.     

Architectural View of Flexible Aliphatic –OH Group Coordinated Hemi-Directed Pb(II)-Salen Coordination Polymer: Synthesis,Crystal Structure,Spectroscopic Insights,Supramolecular Topographies,and DFT Perspective

Journal of Inorganic and Organometallic Polymers and Materials - We serendipitously designed one novel 1D hetero-binuclear Zn(II)-Pb(II) coordination polymer, namely...     

Visible Light Photocatalysis on Magnetically Recyclable Fe3O4/Cu2O Nanostructures

Catalysis Letters - Magnetically recyclable visible light photocatalysts for the degradation of critical organic pollutants are an urgent industrial requirement. Nonetheless, one component...     

Lamotrigine‐loaded polyacrylate nanoparticles synthesized through emulsion polymerization

A series of copolymeric nanoparticles of the partially water‐soluble monomer ethyl methacrylate and the water‐soluble monomer 2‐hydroxyl ethyl methacrylate were synthesized from emulsions containing sodium dodecyl sulfate via free‐radical polymerization. Lamotrigine, as a model drug, was loaded in nanoparticles during in situ polymerization. A stable and transparent poly(ethyl methacrylate‐co‐hydroxyl ethyl methacrylate) nanolatex was produced for all compositions and characterized for particle size by dynamic light scattering and transmission electron microscopy. Particles were found to be smaller than 50 nm in size. Structural characterization of copolymers was done by infrared spectrometry, gel permeation chromatography, and NMR spectroscopy. Drug encapsulation efficiency was determined by ultraviolet (UV)–visible spectrometry and was found to be 26–62% for copolymers with different compositions. UV data suggest molecular‐level dispersion of the drug in the nanoparticles. In vitro drug‐release studies showed the controlled release of lamotrigine. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Hydrogen generation and separation using Gd0.2Ce0.8O1.9−δ–Gd0.08Sr0.88Ti0.95Al0.05O3±δ mixed ionic and electronic conducting membranes

Decomposition of steam under a chemical driving force at moderate temperatures offers a simple and economical way to generate hydrogen. A significant amount of hydrogen can be generated and separated by splitting steam and removing the oxygen using Gd_0.2Ce_0.8O_1.9−δ (GDC)–Gd_0.08Sr_0.88Ti_0.95Al_0.05O_3±δ (GSTA) mixed oxygen ionic and electronic conducting membranes. Hydrogen generation experiments for the self-supported thick membranes and porous supported thin membranes were conducted at different oxygen partial pressure gradients across the membrane established using H₂–H₂O mixture gas. Experimental results indicate that the hydrogen generation from steam using GDC–GSTA MIEC membranes at elevated temperatures is mainly controlled by the bulk diffusion of oxygen for the self-supported thick membranes, while the permeation process for the porous supported thin membranes is mixed controlled, i.e. the hydrogen generation/oxygen permeation process is controlled by the surface exchange reactions and bulk diffusion of oxygen through the MIEC membrane. A mathematical model for the calculation of the area specific hydrogen generation rate is proposed in this paper based on the measured oxygen partial pressures, gas compositions, and gas flow rates of the inlet and outlet gases on feed side of the membrane, as well as the permeation area of the membrane.