Phi zeolite synthesized by template-free method for selective catalytic reduction of NO

Nitrogen oxide (NO_x) is one of the major air pollutants. Using a copper-based zeolite with a chabazite structure (CHA) as a catalyst, the selective catalytic reduction (SCR) technology can effectively remove NO_x. This work introduces a low silica CHA type zeolite with structural defects (zeolite Phi, with Si/Al of 4.7). The zeolite Phi is synthesized through a hydrothermal method without adding any template, which is low-cost and environment-friendly. The Cu-exchanged Phi is abundant of surface acidity and isolated Cu²⁺, showing a superior low-temperature activity, a wide work temperature window and a good hydrothermal stability. The presence of Na or Mg decreases the surface acidity and isolated Cu²⁺. The hydrothermally aged Na,Cu/Phi and Mg,Cu/Phi present different levels of framework collapse, which correspondingly induces catalyst deactivation.     

酚醛树脂/氯丁橡胶胶粘剂的制备及其对45#钢与天然橡胶粘接性能的影响

通过正交试验研究酚醛树脂/氯丁橡胶(CR)胶粘剂主要成分对45~#钢与天然橡胶(NR)粘接性能的影响,通过极差分析确定因子与水平优化组合,并进行试验验证。结果表明,酚醛树脂/CR胶粘剂中白炭黑用量、偶联剂种类和酚醛树脂用量是影响45~#钢与NR粘接性能的主要因素,胶粘剂主要成分优化组合为4份白炭黑、80份酚醛树脂、20份氯化天然橡胶和8份偶联剂KH550,该优化组合下制得的胶粘剂的耐热性能与胶膜耐水性能良好,45~#钢与NR粘接的单向拉伸剪切强度可达4.57 MPa。     

运用均衡凝固模数法设计液压试验平台铸铁件压边浇冒口系统

液压试验平台,材质HT200,铸件重2 800 kg,轮廓尺寸2 400 mm×1 000 mm×275 mm,平板壁厚95 mm,肋条壁厚40 mm,周边框壁厚50 mm,粘土砂,干型。选用直浇道-横浇道-压边冒口系统,运用均衡凝固收缩模数法设计压边冒口体和冒口颈尺寸,运用大孔出流理论计算压边冒口金属液充满高度。计算结果:直浇道φ75 mm,横浇道45/65 mm×70 mm,压边冒口体φ104 mm,高度200 mm,冒口颈尺寸104 mm×8 mm,冒口体浇注过程充满高度80 mm,具有挡渣能力。生产结果表明,铸件无缩孔、气孔、夹渣缺陷,铸件工艺出品率95%。实践证明采用均衡凝固收缩模数法设计液压试验平台浇冒口系统是可行的。     

EB-PVD制备钛合金薄板渗铝相结构转变研究

对电子束物理气相沉积(EB-PVD)技术制备的钛合金薄板进行粉末包埋法渗铝,研究不同温度渗铝后的相结构转变规律.结果表明:制备态合金薄板相结构为Ti和Ti3Al,材料组织致密均匀,X射线衍射峰发生宽化,具有不对称性.在较低温度(600℃和620℃)渗铝后薄板两边的相结构变为Al3Ti相,但薄板的中心部位仍然为制备态的Ti3Al相,两边的Al3Ti组织和中心部位的Ti3Al组织都很均匀致密.在两相之间,存在清晰、平整的界面.在较高温度(700℃)渗铝后薄板的相结构为Al3Ti,此时整个板材都被渗穿,组织均匀致密,并在局部小区域内出现铝元素的富集.     

Surface morphology and photoluminescence properties of ZnO thin films obtained by PLD

ZnO thin films on Si(111) substrate were deposited by laser ablation of Zn target in oxygen reactive atmosphere, Nd-YAG laser with wavelength of 1 064 nm was used as laser source. XRD and FESEM microscopy were applied to characterize the structure and surface morphology of the deposited ZnO films. The optical properties of the ZnO thin films were characterized by photoluminescence. The UV and deep level (yellow-green) light were observed from the films. The UV light is the intrinsic property and deep level light is attributed to the existence of antisite defects (Ozn). The intensity of UV and deep level light depends strongly on the surface morphology and is explained by the surface roughness of ZnO film. A strongly UV emission can be obtained from ZnO film with surface roughness in nanometer range.     

旋转交变磁场和静磁场对Al-18%Si合金变质处理的影响

分别研究了旋转磁场和静磁场对过共晶Al-18％Si合金变质处理的影响。结果表明：变质处理后．不施加磁场的条件下，块状初晶Si偏聚在试样边缘处，试样中心处为共晶Si；施加旋转交变磁场的条件下，粗大的板条状初晶Si偏聚在试样边缘处，试样中心处为共晶Si；施加静磁场的条件下，在试样整个横断面上初晶Si都是细小的块状，且大小和分布均匀。     

YJ231接装机后墙板铸铁件浇注系统当冒口的补缩和溢流排渣设计

YJ231接装机后墙板铸铁件,材质HT200,轮廓尺寸1102mm×962mm×34mm,重200kg,干砂型,表面质量要求高,6个面均需机加工。为获得无夹渣、夹砂、缩松、气孔等缺陷铸件,采用均衡凝固浇注系统当冒口,浇注和补缩一体化设计方法:1只直浇道φ40mm,双向横浇道截面梯形32mm×44mm×50mm,4只内浇道80mm×7mm搭接在铸件顶面,设2只溢流排渣冒口φ50mm×60mm,8只出气冒口φ20mm。墙板实际浇注时间28s,与计算值吻合。生产实践证明,运用均衡凝固浇注系统当冒口浇注、补缩和溢流排渣工艺稳定可靠。     

A SIMPLIFIED EXPRESSION OF m-n-δ RELATIONS FOR MATERIALS WITH PLASTICITY OR SUPERPLASTICITY

以Hart的微分型本构关系为基础,本文推导出了一个既包含应变硬化效应(n)又包含应变速率敏感效应(m)的m-n-δ关系式δ=[1/(1-(1-α(0))~(1/m))]~m×e~n-1当n=0时,它吻合于Ghosh和Ayres的现代分析,当m=0时,吻合于Considère的经典分析.该公式的计算结果和实验结果一致.     

铸件热节变化与冒口位置的分析

热节是铸件凝固慢的节点或区域,可分为几何热节、物理热节、接触热节和流动热节.热节的位置、大小受铸件结构、铸型材质和浇冒口系统的开设位置所影响.冒口的开设应使接触热节、流动热节与几何热节分离.     

稳恒磁场在金属相变过程中的应用

稳恒磁场在材料科学中的应用越来越受到关注。本文从稳恒磁场作用下生成的磁化力和洛伦兹力两个角度归纳了稳恒磁场对金属材料的固态相变和液态相变的影响。其中磁化力可以影响固态相变过程，形成取向．引起磁对流，进行磁性分离。而洛伦兹力可以抑制熔体的流动和波动，提高溶质离子在基体中的固溶度，另外，利用洛伦兹力还可以在电磁离心铸造中获得均匀的凝固组织。