Time dependent crystal-smectic transformation in perylene-containing polyimides

The crystalline conformations of perylene polyimides (PPIs), with alkyl spacers varying in length from C₃ to C₁₂ are discussed. Although modeling of single chains would suggest the possibility that those with odd number of CH₂ groups adopt a flat helical shape, X-ray diffraction suggests that the chains with odd and even spacers have the same conformation, due to the necessity to pack the perylene units. Upon annealing, the UV-vis absorption maximum red-shifts by about 10 nm, indicating enhanced π-stacking between the perylenes. Several changes in the spectra are seen with an increase in annealing time, at a given temperature. With an increase in annealing time, X-ray diffraction patterns show changes in the number of reflections, indicative of a crystal to mesogenic transition. The time required for this transition increases with a decrease in the spacer length, and annealing temperature, suggesting that the dynamics of this transition is very slow.     

基于多随机变量风险约束的水电站长期优化调度

针对市场环境下水电站如何综合考虑电价和来水等不确定性因素下的优化调度是当前研究的热点和难点,建立了考虑电价和来水等不确定性因素的风险约束水电站长期优化调度模型。根据此模型发电商可方便地在预期的目标收益和风险之间进行权衡,达到以较小的风险获得较大的收益的目的。以二滩电厂实算为例,表明了该模型的有效性。     

Synthesis of TiO<Subscript>2</Subscript> Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent

TiO₂ hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as testified by UV spectrometric method. KH570 modified TiO₂ nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive adsorption capacity were achieved, which made it promising in chemical sensor applications.     

Behaviors of concrete-filled steel tubular members subjected to combined loading

The present study is an investigation on the behaviors of concrete-filled thin-walled steel tubular members subjected to combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. ABAQUS software is used in this paper for the finite element analysis (FEA). A comparison of results calculated using this modeling shows generally good agreement with test results. The FEA modeling is then used to investigate the influence of important parameters that determine the ultimate strength of the composite members under combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. The parametric studies provide information for the development of formulae for calculating the ultimate strength of the composite members subjected to combined loading.     

基于随机分析和概率预测的固定式海洋平台结构风险评估研究

对极端海况进行了环境荷载的联合概率分析。引入了整体不确定性和敏感性分析理论,利用非正态过程、具有不同相关性的多变量随机模拟技术,求解结构的失效概率。提出结构失效分析的新方法,并利用DNV提供的历史数据,对结构失效的后果做了适当分析。以埕北12-C井组平台为实例,对平台甲板高程(Air Gap)失效分析进行了实例计算。结果表明,使用多维联合极值分布理论及相应的求解方法,是离岸工程结构物风险评估的重要手段。     

碳酸盐岩气藏加砂压裂重复改造试验效果分析

针对碳酸盐岩气藏部分气井生产效能低的状况，决定在长庆气田下古生界尝试开展加砂压裂重复改造试验，以期提高低产、低效气井的产量，延长气田稳产期。通过潜心研究、精细设计及现场质检监控，优选了4口老井进行加砂压裂重复改造现场试验。从试验结果来看，虽然只有1口井取得明显的改造效果，但4口井加砂压裂施工都是成功的，说明对碳酸盐岩气藏实施加砂压裂是可以实现的，但在选井思路和压裂工艺方面还有待探索和研究。     

海底管道系统失效故障树的建立及定性分析

受自然环境、管道腐蚀、第三方破坏及管理不善等因素的影响,海底管道系统在铺设及运行过程中常常会失效。文中以海底管道穿孔、凝管、断裂和设备故障等主要失效形式为顶事件建立了海底管道系统失效故障树,通过系统的定性分析得到了海底管道系统失效故障树的37个一阶最小割集,进而确定了影响海底管道系统失效的4项主要因素,并针对这些主要因素提出了相应的解决问题的措施。     

一种考虑分布电容的模糊故障测距算法

提出了一种考虑分布电容的故障测距新算法。该算法基于微分方程描述的线路数学模型，利用单端信息对高压输电线路进行故障测距，保留了解微分方程算法的简单可靠、现实可行、不必考虑衰减直流分量和谐波及电网频率波动影响的特点，同时考虑过渡电阻和分布电容的影响，克服了传统解微分方程法中在经高阻接地故障时测距误差过大和忽略分布电容引起的故障定位不准确的缺点。为了检验算法的精度，进行了大量的动模实验。结果表明，算法原理正确并具有较高的测距精度。     

PURIFICATION AND PROPERTIES OF TRANSGLUTAMINASE FROM STREPTOVERTICILLIUM MOBARAENSE

Transglutaminase (TGase) was separated from the culture broth of an isolated strain of Streptoverticillium mobaraense. The crude enzyme was prepared by centrifugation, ultrafiltration, precipitation by alcohol, centrifugation and freeze‐drying. The yield after these processes was 65–70%. Then the enzyme was purified to homogeneity by chromatography on CM‐cellulose and Sephadex G‐75 on which the yields were about 70% and 80%, respectively; the purified folds reached 2.5–4.7 and 1.08–2.06, respectively. The molecular weight of this TGase was 39,500–40,100 Da by gel filtration chromatography. Optimum enzyme activity was observed in the pH range of 5.0–7.0, and it was maintained stable at 20–40C. The optimal temperature and pH was 52C and 6.0, respectively. At 1 mM and 5 mM metal ion or inhibitors concentration, TGase activity was strongly inhibited by Zn²⁺ and NEM, and not affected obviously by Ba²⁺, Ca²⁺, Co²⁺, Cu²⁺, Fe²⁺, Fe³⁺, Mg²⁺, Mn²⁺, Na⁺ as well as PMSF and EDTA. The effects of these additions on this TGase were compared with those of other microbial TGases.