Nido-Hydroborate-Based Electrolytes for All-Solid-State Lithium Batteries

Hydroborate-based solid electrolytes have recently been successfully employed in high voltage, room temperature all-solid-state sodium batteries. The transfer to analogous lithium systems has failed up to now due to the lower conductivity of the corresponding lithium compounds and their high cost. Here LiB₁₁H₁₄ nido-hydroborate as a cost-effective building block and its high-purity synthesis is introduced. The crystal structures of anhydrous LiB₁₁H₁₄ as well as of LiB₁₁H₁₄-based mixed-anion solid electrolytes are solved and high ionic conductivities of 1.1 × 10⁻⁴ S cm⁻¹ for Li₂(B₁₁H₁₄)(CB₁₁H₁₂) and 1.1 × 10⁻³ S cm⁻¹ for Li₃(B₁₁H₁₄)(CB₉H₁₀)₂ are obtained, respectively. LiB₁₁H₁₄ exhibits an oxidative stability limit of 2.6 V versus Li⁺/Li and the proposed decomposition products are discussed based on density functional theory calculations. Strategies are discussed to improve the stability of these compounds by modifying the chemical structure of the nido-hydroborate cage. Galvanostatic cycling in symmetric cells with two lithium metal electrodes shows a small overpotential increase from 22.5 to 30 mV after 620 h (up to 0.5 mAh cm⁻²), demonstrating that the electrolyte is compatible with metallic anodes. Finally, the Li₂(B₁₁H₁₄)(CB₁₁H₁₂)  electrolyte is employed in a proof-of-concept half cell with a TiS₂ cathode with a capacity retention of 82% after 150 cycles at C/5.     

Architecture of a Memory Manager for an MPEG-2 Video Decoding Circuit

A study of the MPEG-2 video decoding standard in Main Profile @ Main Level has been performed, comparing the different solutions existing for the VLSI implementation of the basic functions (Huffman decoding, IDCT...) included in the standard. Afterwards, a new dynamically configurable architecture is proposed for the memory manager, which is necessary to deal with the large data flow inside the decoder. It is aimed at interfacing the external memory, arbitrating the access requests coming from the different decoding units and allowing generic memory requests through the definition of virtual addresses. It is shown that, by means of a particular data organization, the circuit requires an external memory, which is a 2-MB DRAM in fast page or EDO mode, accessible via a 64-bit bus. The memory manager works at 27 MHz and allows a real-time decoding for MP @ ML bitstreams. It has been synthesized in a 0.8-m two-metal CMOS technology and presents a total area of 5.4 mm2 for 6500 gates.     

A physical optics approach to near field RCS computations

The scattered field of a perfectly conducting body treated using a physical optics approach is obtained in near field in either the monostatic or bistatic case. This approach opens new prospects for a broad range of applications in the areas of radar cross section (rcs) and antennas. Numerical examples for simple shapes (circular and rectangular plates) are given. Remarkable phenomena are found and discussed.     

高温氦气环境中石墨的水蒸气氧化特性模拟研究

在正常运行工况下高温气冷堆内石墨材料的氧化对石墨结构材料的服役时间有重要影响.主要介绍高温气冷堆燃料元件氦气孔道内石墨材料与水蒸气发生氧化反应的模拟.该模型使用COMSOL软件进行建模,采用k-ε模型模拟冷却剂的流动,使用Langmuir-Hinshelwood方程描述石墨与水蒸气的化学反应.使用该模型计算了冷却剂管道温度分布为线性、水蒸气压力低于1 Pa的氧化情况.计算结果表明,在堆芯底部氧化主要发生在表面,石墨材料转化率高于8%的厚度约1 mm.     

Selfishness in secure internet of things networks: 6TiSCH case study

Wireless Networks - Performance and communication security in the Internet of Things (IoT) area draw a major concern for both academic and industrial communities. Indeed, an emerging number of IoT...     

A closed-loop electrical stimulation system for cardiac cell cultures

An integrated electrical stimulation and recording system was designed for closed-loop control and analysis of cardiac cultures on planar microelectrode arrays. Stimulated action potentials from HL-1 clonal myocyte cultures were digitized, stimulation artifacts were removed using nulling and filtering methods, and analysis was performed to determine stimulation efficacy in real time. Results of this analysis were used to determine future stimulation waveform parameters such as polarity, amplitude, pulse duration, and rate or pattern. Algorithms were designed utilizing real-time analysis and control to maintain a desired electrophysiological response of the culture, such as an arbitrary capture fraction value. This paper presents the hardware and software design of the stimulus pulse circuitry, artifact extraction, analysis, and control components of the system. Applications of this technology include the study of cardiac cell physiology, improving the speed and accuracy of traditional open-loop stimulation protocols, pharmacological screening, and improving the performance of biosensors based on sensing electrical activity in cardiac cultures.     

Macroscopic and Microscopic Structures of Cesium Lead Iodide Perovskite from Atomistic Simulations

A first‐principles‐based effective Hamiltonian is developed and employed to investigate finite‐temperature structural properties of a prototype of perovskite halides, that is CsPbI₃. Such simulations, when using first‐principles‐extracted coefficients, successfully reproduce the existence of an orthorhombic Pnma state and its iodine octahedral tilting angles around room temperature. However, they also yield a direct transformation from Pnma to cubic $Pm\overline{3}m$ upon heating, unlike measurements that reported the occurrence of an intermediate long‐range‐tilted tetragonal P4/mbm phase in‐between the orthorhombic and cubic phases. Such disagreement, which may cast some doubts about the extent to which first‐principle methods can be trusted to mimic hybrid perovskites, can be resolved by “only” changing one short‐range tilting parameter in the whole set of effective Hamiltonian coefficients. In such a case, some reasonable values of this specific parameter result in the predictions that i) the intermediate P4/mbm state originates from fluctuations over many different tilted states; and ii) the cubic $Pm\overline{3}m$ phase is highly locally distorted and develops strong transverse antiphase correlation between first‐nearest neighbor iodine octahedral tiltings, before undergoing a phase transition to P4/mbm under cooling.     

Performance Optimization of Vertical Nanowire‐based Piezoelectric Nanogenerators

The integrated nanogenerator (NG) based on vertical nanowire (NW) arrays is one of the dominant designs developed to harvest mechanical energy using piezoelectric nanostructures. Finite element method (FEM) simulations of such a NG are developed using ZnO NWs in compression mode to evaluate its performances in term of piezoelectric potential generated, capacitance, induced mechanical energy, output electrical energy, and efficiency. This evaluation is essential to correctly understand NG operation. Three main issues are highlighted. The mechanical and electrical structures of the NG as an integrated system are optimized, and strategies for concentrating the mechanical strain field in the NWs and increasing the force sensitivity are developed. In addition, the influence of NWs length and diameter on NG performances is investigated. The optimization results in a piezoelectric nano composite material where global performances are improved by mean of long and thin NWs.     

Inter‐annual variability,risk and confidence intervals associated with propagation statistics. Part II: parameterization and applications

This set of two companion papers aims at providing a model for the inter‐annual variability of earth‐space propagation statistics and for the inherent risk and CIs. In part I, it was proposed to model the yearly variance σ² of empirical complementary CDFs so that where is the variance of estimation, the inter‐annual climatic variance and p the long‐term probability. Particularly, an analytical formulation of was derived and parameterized from synthetic rain attenuation data. Considering the statistical framework developed in part I, this part II is specifically devoted to the parameterization of the variance of estimation from experimental data of rain attenuation and rainfall rate. Then, a methodology to model and parameterize worldwide the inter‐annual climatic variance is presented. The model of yearly variance of the empirical complementary CDFs is finally compared against yearly experimental variances derived from data collected worldwide. The knowledge of this variability is very useful for system design as it allows the risk on a required availability and associated with a given propagation margin to be quantified. Copyright © 2013 John Wiley & Sons, Ltd.